Page 217 - 《精细化工》2022年第5期

第 5 期 李亚科，等: 蓖麻油酸二乙醇酰胺硼酸酯合成工艺及摩擦性能 ·1071·

催化剂，采用两步法合成了 RA。酰化反应 n（蓖麻 [7] LI W M (李维民), JIANG C (姜程),WANG X B (王晓波), et al.
油酸）∶n（二乙醇胺）=1∶0.8 时，150 ℃下反应 Preparation and tribological of vegetable oil based lubricating oil
additive[J]. Acta Petrolei Sinica (Petroleum Processing Section)
6 h；胺解反应 n（蓖麻油酸）∶n（二乙醇胺）=1∶ 〔石油学报(石油加工)〕, 2015, 31(2): 468-475.
0.4，NaOH 用量为 1%，95 ℃下反应 3 h，此条件 [8] DING H Y, YANG X H, XU L N, et al. Analysis and comparison of
tribological performance of fatty acid-based lubricant additives with
下 RA 产率达 88.10%。 phosphorus and sulfur[J]. Journal of Bioresources and Bioproducts,
（2）以 RA 和硼酸为原料，对甲苯磺酸为催化 2020, 5(2): 134-142.
剂，在 n（RA）∶n（硼酸）=1.8∶1，催化剂用量 [9] NING P, WANG L, WANG W Y, et al. Tribological studies on two
novel borate esters with nitrogen-containing heterocyclic and
为 1.5%，140 ℃下反应 100 min 时，RAB 产率达 alkanolamide as multifunctional additives in rapeseed oil[J]. Journal
92.78%。 of Dispersion Science and Technology, 2015, 37(5): 699-705.
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（3）对蓖麻油酸、RA 和 RAB 进行红外光谱表
evaluation of its tribological properties as an additive in different
征，在 RA 和 RAB 谱图上均发现酰胺基的 C==O 和 base oils[J]. Lubrication Science, 2016, 28(8): 505-519.
C—N 伸缩振动峰，在 RAB 谱图上发现了 B—O 特 [11] FAN B J (范冰极). The synergistic effect of N-containing borate
ester and phosphate ester on tribological performances[D].
征吸收峰，表明 RA 和 RAB 顺利合成。 Shanghai : Shanghai Jiao Tong University (上海交通大学), 2016.
（4）使用四球摩擦试验机对 RAB 在菜籽油中 [12] ZHU M (朱苗). Synthesis and performance of boric acid ester
的摩擦性能进行了测试，结果表明，RAB 添加量为 containing N，S element[D].Daqing: Northeast Petroleum University
(东北石油大学), 2016.
2%时，P B 达到 805 N，比菜籽油增加了 61%；RAB [13] ZHANG G J (张冠军), YI S Z (衣守志), ZHANG C X (张晨曦),
添加量为 1%时，磨斑直径最小，为 0.580 mm，比 et al. Preparation and tribological properties of phenyl borate ester
菜籽油下降 20.8%，摩擦系数下降 32.4%；SEM 分 containing sulphur andnitrogen[J]. Fine Chemicals (精细化工),
2018, 35(11): 1956-1960.
析表明，含 RAB 的菜籽油润滑时，钢球摩擦表面犁 [14] JIN D Y (靳大耀), HAO Y M (郝聿铭), JIA X Q (贾晓强). Study of
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摩擦表面生成了铁的氧化物（FeO、Fe 2 O 3 和 Fe 3 O 4 ）
[15] LI L M (李伶敏), JIANG W W (蒋文伟), WANG J W (王俊武),
和 Fe—C 化合物、B 2 O 3 和含氮有机物等，这些摩擦 et al. Synthesis of fatty acid alkanolamide and evaluation of its
化学产物与有机分子碎片形成了复杂的润滑保护 properties[J]. Fine Chemical Intermediates (精细化工中间体), 2016,
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