Page 44 - 《精细化工》2022年第5期

第 39 卷第 5 期 精 细 化 工 Vol.39, No.5
2022 年 5 月 FINE CHEMICALS May 2022

功能材料
浸润性对 GF/PDCPD 复合材料性能的影响

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胡贵宝 ，杨维成 1,2,3* ，郝建淦 ，乔新峰 ，
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郭 松 ，乔拟春 ，罗 勇 1,2,3*
〔1. 上海化工研究院有限公司，上海 200062；2. 上海市聚烯烃催化技术重点实验室，上海 200062；
3. 聚烯烃催化技术与高性能材料国家重点实验室，上海 200062；4. 东风银轮（十堰）非金属部件有限公
司技术中心，湖北 十堰 442000〕

摘要：利用动态接触角考察了双环戊二烯（DCPD）树脂（S-D、3S-D 和 SCB-600）与玻璃纤维（GF）的浸润
性，通过 90°拉伸强度和层间剪切强度测试不同 DCPD 树脂与玻璃纤维之间的黏附力，研究了浸润性对树脂与
GF 结合性的影响。结果表明，动态接触角为 60.35°±0.3°的 SCB-600 与 GF 具有良好的浸润性，由其制备的 PDCPD
基玻璃纤维复合材料〔GF/PDCPD (SCB-600)〕的 90°拉伸强度为（42.3±1.2） MPa，层间剪切强度为（61.3±3.2）
MPa，达到环氧基玻璃纤维复合材料〔GF/1564 环氧树脂〕结合性能。当 SCB-600 质量分数为 30%±2%时，
GF/PDCPD (SCB-600)具有最优的力学性能，拉伸强度为（1180.1±4.1） MPa，弯曲强度为（1060.4±4.6） MPa，
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与 GF/1564 环氧树脂相当，但其悬臂梁缺口冲击强度达到（145.3±4.8） kJ/m ，明显优于 GF/1564 环氧树脂，
说明 GF/PDCPD (SCB-600)在抗冲击方面具有广泛的应用前景。
关键词：双环戊二烯；接触角；纤维复合材料；力学性能；浸润性；功能材料
中图分类号：TB332 文献标识码：A 文章编号：1003-5214 (2022) 05-0898-07

Effect of wettability on properties of GF/PDCPD composites

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HU Guibao , YANG Weicheng 1,2,3* , HAO Jiangan , QIAO Xinfeng ,
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GUO Song , QIAO Nichun , LUO Yong 1,2,3*
[1. Shanghai Research Institute of Chemical Industry Co., Ltd., Shanghai 200062, China; 2. Shanghai Key Laboratory of
Catalysis Technology for Polyolefins, Shanghai 200062, China; 3. State Key Laboratory of Polyolefins and Catalysis,
Shanghai 200062, China; 4. Dongfeng Yinlun (Shiyan) Non-Metallic Parts Co., Ltd., Shiyan 442000, Hubei, China]
Abstract: The impregnation capacity of a series of dicyclopentadiene (DCPD) resins (S-D, 3S-D and
SCB-600) on glass fiber (GF) was studied by dynamic contact angle analysis. The interfacial adhesion
between different DCPD resins and GF was tested by 90° tensile strength and interlaminar shear strength
measurements, and the effect of wettability on the bonding property between GF and resin was investigated.
The results showed that SCB-600 had the lowest dynamic contact angle of 60.35°±0.3° among the resins
tested, which suggested better impregnation behavior with GF. The PDCPD-based GF composite [GF/
PDCPD (SCB-600)] prepared from SCB-600 had a 90° tensile strength of (42.3±1.2) MPa, interlaminar
shear strength of (61.3±3.2) MPa, which achieved the bonding ability of epoxy-based GF composites
GF/1564 epoxy resin. GF/PDCPD (SCB-600) with SCB-600 mass fraction of 30%±2% demonstrated the
best mechanical properties, exhibited in the form of the tensile strength and bending strength with a value of
(1180.1±4.1) MPa and (1060.4±4.6) MPa respectively, which was equivalent to those of GF/1564 epoxy
resin. However, the cantilever notched impact strength of GF/PDCPD (SCB-600) reached (145.3±4.8)
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kJ/m , obviously better than that of GF/1564 epoxy resin, suggesting that GF/PDCPD (SCB-600) could
have promising application prospects in impact resistance.

收稿日期：2021-12-12; 定用日期：2022-02-21; DOI: 10.13550/j.jxhg.20211309
基金项目：上海市科委自然科学基金（21ZR1480700）
作者简介：胡贵宝（1996—），男，硕士生，E-mail：guibao_hu@163.com。联系人：杨维成（1982—），男，高级工程师，E-mail：
ywcjc@163.com；罗 勇（1974—），男，教授级高级工程师，E-mail：real-luoyong@hotmail.com。