Page 125 - 《精细化工》2022年第8期
P. 125

第 8 期                     王   超,等:  温敏光子晶体及自适应结构色迷彩器件制备                                 ·1625·

















            图 5   自适应结构色器件的单点测试图以及对应的红外热成像图(a);单点对应的反射光谱图(b);自适应结构色器件
                  多点统一控温在 26.3  ℃的测试图以及对应的红外热成像仪图(c);26.3  ℃时对应的反射光谱图(d);自适应结
                  构色器件多点统一控温在 24.6  ℃的测试图以及对应的红外热成像仪图(e);24.6  ℃时对应的光谱图(f);自适
                  应结构色器件多点不同温度控制的红花绿叶图(g);红花绿叶图对应的红外热成像图(h);红花绿叶图对应的
                  反射光谱图(i、j)
            Fig. 5    Single point test of adaptive structured color devices (a); Reflection spectrum corresponding to a single point (b); Test
                   diagram of multi-point unified temperature control of adaptive structural color device at 26.3  ℃ and corresponding
                   infrared thermal imager diagram (c); Reflection spectrum corresponding to the material at 26.3  ℃  (d); Test diagram
                   of multi-point unified temperature control of adaptive structural color device at 24.6  ℃ and corresponding infrared
                   thermal imager diagram (e); Corresponding spectrum at 24.6  ℃  (f); Red flower green leaf diagram with multi-point
                   different temperature control of adaptive structural color device (g); Infrared thermal image corresponding to
                   safflower green leaf image (h); Reflection spectrum corresponding to safflower green leaf diagram (i, j)

            3   结论                                             [7]   1264-1270.
                                                                   WANG Z H, ZHANG J  H,  TIAN Z C,  et al. Organic-inorganic
                                                                   hybrid photonic hydrogels as a colorful platform for visual detection
                                                                       −
                                                                   of SCN [J]. Chemical Communications, 2010, 46(45): 8636-8638.
                 本文制备了一种基于 C 12 DMAO 的温敏显色材                    [8]   HAQUE M  A, KUROKAWA T, KAMITA G,  et al. Rapid  and
            料与正阵列式集成电路复合构成的温敏响应的光子                                 reversible tuning of structural color  of a hydrogel over  the entire
                                                                   visible spectrum by mechanical stimulation[J]. Chemistry of Materials,
            晶体结构色器件。通过 NIPAM、DMAA、AM 比例                            2011, 23(23): 5200-5207.
                                                               [9]   XIAO F X, PAGLIARO M, XU Y J, et al. Layer-by-layer assembly
            的调整,水凝胶的响应温度可在 4.3~55.0  ℃范围内调                         of versatile nanoarchitectures with  diverse dimensionality: A new
            节。在 NIPAM 为 0.20 g、DMAA 为 0.20 g、AM 为                  perspective for rational construction of multilayer assemblies[J]. Chemical
                                                                   Society Reviews, 2016, 45(11): 3088-3121.
            50 mg、MBAA 50 mg 条件下,制备的自适应结构色                     [10]  KURT P, BANERIEE D, COHEN  R E,  et al. Structural color via
                                                                   layer-by-layer deposition: Layered nanoparticle arrays with near-UV
            器件在 22~30  ℃之间调节温度,结构色器件可以实                            and visible reflectivity bands[J]. Journal of Materials Chemistry,
                                                                   2009, 19(47): 8920-8927.
            现快速的颜色变化。通过调节 AM 用量,可以调整                           [11]  DIERENDONCK  M, DE  K S, DE  R R,  et al. Just spray it-LbL
            显色材料的温度区间,通过调节 NIPAM、DMAA 用                            assembly enters a new age[J]. Soft Matter, 2014, 10(6): 804-807.
                                                               [12]  NOGUEIRA G M, BANERJEE D, NCOHE R E, et al. Spray-layer-
            量,可以调整显色材料当前温度区间的宽窄。通过                                 by-layer assembly can more rapidly produce optical-quality multistack
                                                                   heterostructures[J]. Langmuir, 2011, 27(12): 7860-7867.
            信号调整使正阵列式加热板能稳定输出温度,结合                             [13]  CHO J, CHAR K, HONG J D, et al. Fabrication of highly ordered
            材料温敏变色的特性,通过温度的调节显示出不同                                 multilayer films using a spin self-assembly  method[J].  Advanced
                                                                   Materials, 2001, 13(14): 1076-1078.
            图案,从而达到自适应显色的效果。在可穿戴迷彩                             [14]  ANAMUL H, GEN K, TAKAYUKI K, et al. Unidirectional alignment
                                                                   of lamellar bilayer in hydrogel: One-dimensional swelling, anisotropic
            防伪方面有着广阔的应用前景。                                         modulus, and stress/strain tunable structural color[J]. Advanced Materials,
                                                                   2010, 22: 5110-5114.
            参考文献:                                              [15]  CHEN Z Y, FU F F, YU Y R, et al. Cardiomyocytes-actuated morpho
                                                                   butterfly wings[J]. Advanced Materials, 2019, 31(8): 1805431.
            [1]  BERGER  O, YOSKOVITZ E, ADLER-ABRAMOVICH L,  et al.   [16]  DUMANLI A G, SAVIN T.  Recent advances in the biomimicry of
                 Spectral transition in bio-inspired self-assembled peptide nucleic acid   structural colours[J]. Chemical Society Reviews, 2016, 45(24): 6698-
                 photonic crystals[J]. Advanced Materials, 2016, 28(11): 2195-2200.   6724.
            [2]   LEE G H, CHOI  T M, KIM B,  et al. Chameleon-inspired   [17]  CHIARELLI P A,  JOHAL M S, CASSON J L,  et al. Controlled
                 mechanochromic photonic films composed of non-close-packed   fabrication of polyelectrolyte multilayer thin films using spin-assembly[J].
                 colloidal arrays[J]. ACS Nano, 2017, 11(11): 11350-11357.   Advanced Materials, 2001, 13(13): 1167-1171.
            [3]   SHEN H Z, WANG Z H, WU Y X, et al. One-dimensional photonic   [18]  PARK T H, YU S G, CHO S H,  et al. Block copolymer structural
                 crystals: Fabrication, responsiveness and emerging applications in   color strain sensor[J]. NPG Asia Materials, 2018, 10(4): 328-339.
                 3D construction[J]. RSC Advances, 2016, 6(6): 4505-4520.   [19]  KOSONEN H, VALKAMA S,  RUOKOLAINEN J,  et al. One-
            [4]   MATSUBARA K, WATANABE M, TAKEOKA Y, et al. A thermally   dimensional optical reflectors based on self-organization of polymeric
                 adjustable  multicolor photochromic hydrogel[J]. Angewandte   comb-shaped supramolecules[J]. European Physical Journal E, 2003,
                 Chemie, 2007, 119(10): 1718-1722.                 10(1): 69-75.
            [5]   BOHN J J, BEN-MOSHE M, TIKHONOV A, et al. Charge stabilized   [20]  KIMURA M,  OKAHARA K, MIYAMOTO  T,  et al. Tunable
                 crystalline colloidal arrays as templates for fabrication of non-close-   multilayer-film distributed-bragg-reflector filter[J]. Journal of Applied
                 packed inverted photonic crystals[J]. Journal of Colloid and Interface   Physics, 1979, 50(3): 1222-1225.
                 Science, 2010, 344(2): 298-307.               [21]  WANG Z H, ZHANG  J H, XIE  J,  et al. Bioinspired water-vapor-
            [6]   WANG Z H, ZHANG J H, LI J X, et al. Colorful detection of organic   responsive organic/inorganic hybrid one-dimensional photonic crystals
                 solvents based on responsive organic/inorganic hybrid one-dimensional   with tunable full-color stop band[J]. Advanced Functional Materials,
                 photonic crystals[J]. Journal of Materials Chemistry, 2011, 21(4):   2010, 20(21): 3784-3790.
   120   121   122   123   124   125   126   127   128   129   130