Page 20 - 《精细化工》2022年第9期

·1738· 精细化工 FINE CHEMICALS 第 39 卷

以下问题：（1）对于化学交联改性 PVA，研究大多 based polymer blends, nanocomposites and their biodegradability[J].
Carbohydrate Polymers, 2011, 85(1): 7-16.
停留在 PVA 改性涂料及其薄膜的性能上，对改性
[16] CHEN M, WANG Y, YIN S J. Effects of temperature and humidity
PVA 涂料在聚烯烃膜上的应用适应性的研究还不够 on the barrier properties of biaxially-oriented polypropylene and
polyvinyl alcohol films[J]. Journal of Applied Packaging Research,
深入，尤其是附着牢度研究不够深入；（2）对于 PVA-
2014, 6: 40-46.
纳米层状材料复合涂料，纳米层状材料在高负载下 [17] GRUNLAN J C, GRIGORIAN A, HAMILTON C B, et al. Effect of
的分散性、在聚合物基质中的定向排列以及透明外 clay concentration on the oxygen permeability and optical properties
of a modified poly(vinyl alcohol)[J]. Journal of Applied Polymer,
观是其主要技术难题。此外，繁杂的涂布工序也是 2004, 93: 1102-1109.
导致大多数研究停留在实验室阶段，无法大规模生 [18] LU P C, PITTSFORD N Y. Barrier film structures: US 5776618A[P].
1998-06-07.
产的主要原因。针对以上问题，只有综合考虑工业 [19] JORDAN M P, TAYLOR J. Film coatings and film coatings
化生产，加强对纳米材料及其与水溶性高分子有机 compositions based on poly vinyl alcohol: US6448323B1[P]. 2002-
09-10.
物之间相互作用的机理研究，结合化学交联改性以 [20] GERALD D M, HUMBLE T X. PVOH barrier performance on
及有机/无机杂化技术的纵深研究，才能实现多功能 substrates: US2005/0042443A1[P]. 2005-02-24.
[21] PANG Z P (庞志鹏), GENG J R (耿建荣). Modification of PVA and
PVA 涂布液在高阻隔软包装领域的拓展应用。 the processing method[J]. Packaging Engineering, 2001, 22: 20-23.
[22] HU Y Q (胡焱清), LI Z F (李子繁), SUN H Q (孙红旗). Research
参考文献： on modified PVA coating process[J]. Packaging Engineering, 2009,
30(2): 29-32.
[1] DEY A, NEOGI S. Oxygen scavengers for food packaging applications:
A review[J]. Trends in Food Science & Technology, 2019, 90: 26-32. [23] LIU J L (刘建林). Modified PVA paint and its preparation process:
[2] LANGE J, WYSER Y. Recent innovations in barrier technologies for CN1847334A[P]. 2006-10-18.
plastic packaging—A review[J]. Packaging Technology and Science, [24] HUANG H C (黄宏存), ZHU Q M (朱清梅), YUAN Y X (袁业兴).
2003, 16(4): 149-158. High-oxygen-barrier no-primer polyvinyl alcohol coating and
[3] PIRINGER O G, BANER A L. Plastic packaging: Interactions with manufacturing method thereof: CN104962146A[P]. 2015-10-07.
food and pharmaceuticals, Second Edition [M]. [25] HUANG H C (黄宏存), XING Q T (邢青涛), LI M B (李明彪),
et al. High-solid-content water-resistant polyvinyl alcohol coating for
10.1002/9783527621422. 2008.
[4] MARSH K, BUGUSU B. Food packaging—Roles, materials, and coating and preparation method thereof: CN102676003B[P]. 2012-
09-19.
environmental issues[J]. Journal of Food Science, 2007, 72(3): 39-55. [26] BOLTO B, TRAN T, HOANG M, et al. Crosslinked poly(vinyl
[5] ARORA A, PADUA G W. Review: Nanocomposites in food alcohol) membranes[J]. Progress in Polymer Science, 2009, 34(9):
packaging[J]. Journal of Food Science, 2010, 75(1): 43-49. 969-981.
[6] MURMATSU M, OKURA M, KUBOYAMA K, et al. Oxygen [27] RYNKOWSKA E, FATYEYEVA K, MARAIS S, et al. Chemically
permeability and free volume hole size in ethylene-vinyl alcohol and thermally crosslinked PVA-based membranes: Effect on swelling
copolymer film: Temperature and humidity dependence[J]. Radiation and transport behavior[J]. Polymers, 2019, 11(11): 1799.
Physics and Chemistry, 2003, 68(3/4): 561-564. [28] MIJIN L, DOVAN K, JONGCHUL S. Enhanced oxygen-barrier and
[7] TOBIN V R, SUTTLE H, ASSENDER H E. Nanodefect-controlled water-resistance properties of poly(vinyl alcohol) blended with
permeation in AlO x/polymer gas barrier films[J]. Thin Solid Films, poly(acrylic acid) for packaging applications[J]. Polymer
2017, 642: 142-150. International, 2016, 65(4): 400-406.
[8] ZHAO Y, HUANG C X, HUANG X Q, et al. Effectiveness of [29] DHIEB F B, TABATABAEI S H, MIGHRI F, et al. Comparison of
PECVD deposited nano-silicon oxide protective layer for polylactic crosslinking efficiency in dip and roll-deposited coatings on their
acid film: Barrier and surface properties[J]. Food Packaging and oxygen barrier[J]. ACS Omega, 2019, 4(14): 15772-15779.
Shelf Life, 2020, 25: 100513. [30] ZHU Q M, WANG X H, CHEN X Q, et al. Fabrication and
[9] GRUNIGER A, ROHR R V. Influence of defects in SiO x thin films evaluation of melamine-formaldehyde resin crosslinked PVA
on their barrier properties[J]. Thin Solid Films, 2004, 459: 308-312. composite coating membranes with enhanced oxygen barrier properties
[10] LIM M, KWON H, KIM D, et al. Highly-enhanced water resistant for food packaging[J]. RSC Advance, 2021, 11: 14295-14305.
and oxygen barrier properties of cross-linked poly(vinyl alcohol) [31] KOROS W J. In barrier polymers and structures[M]. Washington:
hybrid films for packaging applications[J]. Progress in Organic American Chemical Society, 1990.
Coatings, 2015, 85: 68-75. [32] CHEN B Q, EVANS J R G, GREENWELL H C, et al. A critical
[11] SMITHERS P. The future of European food & drink packaging to appraisal of polymer-clay nanocomposites[J]. Chemical Society
2023[N]. Reviews, 2008, 37: 568-594.
https://www.smithers.com/services/market-reports/packaging/europe [33] TSURKO E S, FEICHT P, HABEL C, et al. Can high oxygen and
an-food-and-drink-packaging-to-2023 (2018, 02). water vapor barrier nanocomposite coatings be obtained with a
[12] DING F C, LIU J J, ZENG S S, et al. Biomimetic nanocoatings with waterborne formulation[J]. Journal of Membrane Science, 2017, 540:
exceptional mechanical, barrier, and flame-retardant properties from 212-218.
large-scale one-step coassembly[J]. Science Advances, 2017, 3(7): [34] ROVERA C, GHAANI M, FARRIS S. Nano-inspired oxygen barrier
1701212. coatings for food packaging applications: An overview[J]. Trends in
[13] ABDULLAH Z W, DONG Y, DAVIES I J, et al. PVA, PVA blends Food Science & Technology, 2020, 97: 210-220.
and their nanocomposites for biodegradable packaging application[J]. [35] ARANDA P, RUIZ-HITZKY E. Poly(ethylene oxide)-silicate
Polymer-Plastics Technology and Engineering, 2017, 56(12): 1307- intercalation materials[J]. Chemistry of Materials, 1992, 4(6): 1395-
1344. 1403.
[14] DABBAGHIANAMIRI M, DURAIA E M, BEALL G W. Self- [36] ZABSKA M, JASKIEWICS K, KIERSNOWSKI A, et al.
assembled montmorillonite clay-poly(vinyl alcohol) nanocomposite Spontaneous exfoliation and self-assembly phenomena in polyvinyl
as a safe and efficient gas barrier[J]. Results in Materials, 2020, 7(2): pyrrolidone/synthetic layered silicate nanocomposites[J]. Radiation
100101. Physics and Chemistry, 2011, 80: 1125-1128.
[15] TANG X Z, ALAVI S. Recent advances in starch, polyvinyl alcohol （下转第 1746 页）