Page 205 - 《精细化工》2022年第9期

第 39 卷第 9 期 精 细 化 工 Vol.39, No.9
2022 年 9 月 FINE CHEMICALS Sept. 2022

丙烯酸系列化学品
基于蒽醌染料水性聚氨酯-丙烯酸酯

共聚乳液的合成及性能

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胡继广，杨建军 ，吴庆云，吴明元，张建安，刘久逸
（安徽大学 化学化工学院 安徽省水基高分子材料高性能化工程实验室，安徽 合肥 230601）

摘要：以异佛尔酮二异氰酸酯（IPDI）、聚四氢呋喃醚二醇（PTMG）、二羟甲基丁酸（DMBA）、1,4-丁二
醇（BDO）和自制红色蒽醌染料（DYE-R）为原料合成聚氨酯（PU），以甲基丙烯酸羟乙酯（HEMA）为封端
剂制得了双键封端的水性聚氨酯，再采用无皂乳液聚合法与甲基丙烯酸甲酯（MMA）和丙烯酸丁酯（BA）单
体共聚制备了玫红色水性聚氨酯-丙烯酸酯乳液，采用 FTIR、纳米粒度仪、TEM、UV-Vis、TG 对乳液及胶膜进
行了表征。结果表明，随着丙烯酸酯单体用量的增加，乳液粒径增加，当 m(PU)∶m(MMA 与 BA)为 10∶2 时，
乳液的综合性能最好，粒径为 81 nm，稳定性好且有一定耐碱性。该乳液着色效果明显，热迁移率为 3.54%，耐
干、湿摩色牢度为 4~5 级。当该乳液胶膜质量保留率为 50%时，所对应温度为 396.1 ℃。
关键词：蒽醌染料；水性聚氨酯；丙烯酸单体；共聚；显色；丙烯酸系列化学品
中图分类号：TQ610.1；O648.23 文献标识码：A 文章编号：1003-5214 (2022) 09-1923-07

Synthesis and properties of waterborne polyurethane-acrylate
copolymer emulsion based on anthraquinone dye

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HU Jiguang, YANG Jianjun , WU Qingyun, WU Mingyuan, ZHANG Jian'an, LIU Jiuyi
（Anhui High Performance Engineering Laboratory of Water-based Polymer Materials, School of Chemistry and
Chemical Engineering, Anhui University, Hefei 230601, Anhui, China）

Abstract: Polyurethane (PU) was synthesized with isophorone diisocyanate (IPDI), polytetrahydrofuran
ether glycol (PTMG), dimethylol butyric acid (DMBA), 1,4-butanediol (BDO) and self-made red
anthraquinone dye (DYE-R), and 2-hydroxyethyl methacrylate (HEMA) was used as end-capping agent to
prepare double-bond terminated waterborne polyurethane. Then rose red waterborne polyurethane-acrylate
emulsion was prepared by soap-free emulsion polymerization with methyl methacrylate (MMA) and butyl
acrylate (BA) monomers. The emulsion was tested and characterized by FTIR, nano-particle size analyzer,
TEM, UV-Vis and TG. The results showed that the particle size of the emulsion increases with the increase
of the amount of acrylate monomer, and when m(PU)∶m(MMA and BA)=10∶2, the emulsion with a
particle size of 81 nm, good stability and certain alkali resistance, exhibited the best overall performance.
Furthermore, the emulsion had obvious coloring effect with a thermal mobility 3.54% and color fastness to
dry and wet rubbing 4~5 grades. When the mass retention rate of the emulsion film was 50%, the
corresponding temperature was 396.1 ℃.
Key words: anthraquinone dye; waterborne polyurethane; acrylic monomer; copolymerization; color;
acrylic series chemicals

低分子染料使用时存在与被染材料结合力弱、 易迁移、利用率低、对人体和环境有害等问题 [1-3] 。

收稿日期：2022-03-17; 定用日期：2022-06-01; DOI: 10.13550/j.jxhg.20220236
基金项目：国家自然科学基金项目（51973001）；安徽省科技计划重点项目（1704a0902018）
作者简介：胡继广（1996—），男，硕士生，E-mail：2417642755@qq.com。联系人：杨建军（1960—），男，教授，博士生导师，E-mail：
andayjj@163.com。