Page 144 - 《精细化工）》2023年第10期

第 40 卷第 10 期 精 细 化 工 Vol.40, No.10
2 023 年 10 月 FINE CHEMICALS Oct. 2023

功能材料
纳米杂化耐磨超疏水环氧树脂涂层的构筑及性能

许志坚 1,2 ，安秋凤 1,2* ，杨博文 1,2 ，焦岚姣 1,2

（1. 陕西科技大学 化学与化工学院，陕西 西安 710021；2. 陕西省轻化工助剂重点实验室，陕西 西安
710021）

摘要：采用十八烷基胺（C 18 -NH 2 ）对由正硅酸乙酯和 γ-甲基丙烯酰氧基丙基三甲氧基硅烷（KH-570）合成的
纳米粒子进行改性，制得了长链烷基改性纳米粒子（C 18 -NH 2 /570@SiO 2 ）。采用层层组装法将 C 18 -NH 2 /570@SiO 2
引入有机硅改性环氧树脂，制备了超疏水环氧树脂涂层 C 18 -NH 2 /570@SiO 2 /DE51。采用 FTIR、XRD、XPS、TEM、
AFM 对纳米粒子的结构以及涂层的形貌进行了表征。对 C 18 -NH 2 /570@SiO 2 /DE51 的接触角、透光率、自清洁、
耐酸碱和耐摩擦性能进行了测试。结果表明， C 18 -NH 2 /570@SiO 2 成功引入到聚合物链段中， 且
C 18 -NH 2 /570@SiO 2 /DE51 的表面粗糙度明显提高。当喷涂质量分数为 0.8%的 C 18 -NH 2 /570@SiO 2 丙酮分散液时，
制备的 C 18 -NH 2 /570@SiO 2 /DE51-0.8 接触角可达到 150.6°±0.6°，滚动角为 7.8°±0.4°，透光率为 91.98%，具有良
好的自清洁、耐酸碱和耐摩擦性能，摩擦次数可达到 1500 次以上。
关键词：纳米粒子；十八烷基胺；改性环氧树脂；超疏水性；自清洁；耐磨擦；功能材料
中图分类号：TB34 文献标识码：A
文章编号：1003-5214 (2023) 10-2222-09 开放科学 (资源服务) 标识码 (OSID)：

Construction and properties of nano-hybrid wear-resistant
superhydrophobic epoxy resin coatings

1,2
1,2
1,2
XU Zhijian , AN Qiufeng 1,2* , YANG Bowen , JIAO Lanjiao
（1. College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021,
Shaanxi, China; 2. Shaanxi Key Laboratory of Light Chemical Auxiliaries, Xi'an 710021, Shaanxi, China）
Abstract: Long-chain alkyl-modified nanoparticles (octadecylamine C 18-NH 2/570@SiO 2) were synthesized
by C 18-NH 2 modification of the nanoparticles obtained from ethyl orthosilicate (TEOS) and
γ-methacryloyloxypropyltrimethoxysilane (KH-570), and then introduced into silicone-modified epoxy
resin via layer-by-layer assembly to obtain a superhydrophobic epoxy resin coating C 18 -NH 2 /570@SiO 2 /DE51
with excellent friction resistance. The structure of nanoparticles and the morphology of coatings were
characterized by FTIR, XRD, XPS, TEM, AFM. The coating C 18-NH 2/570@SiO 2/DE51 was further tested
for analyses on contact angle, light transmittance, self-cleaning performance, acid and alkaline resistance as
well as friction resistance. The results showed that C 18-NH 2/570@SiO 2 were successfully introduced into
polymer chain with the surface roughness of the coating C 18-NH 2/570@SiO 2/DE51 significantly improved.
When the mass fraction of C 18-NH 2/570@SiO 2 acetone dispersion added was 0.8%, the contact angle and
rolling angle of the coating C 18-NH 2/570@SiO 2/DE51-0.8 obtained could reach 150.6°±0.6° and 7.8°±0.4°,
and the light transmittance was 91.98%. Meanwhile, the coating C 18-NH 2/570@SiO 2/DE51-0.8 exhibited
good self-cleaning performance, acid and alkali resistance and friction resistance, with friction number over
1500 times.
Key words: nanoparticles; octadecylamine; modified epoxy resin; superhydrophobicity; self-cleaning;
friction resistance; functional materials

收稿日期：2022-12-04; 定用日期：2023-03-28; DOI: 10.13550/j.jxhg.20221109
基金项目：陕西省重点研发计划项目（2020ZDLGY13-11）
作者简介：许志坚（1999—），男，硕士生，E-mail：2993247218@qq.com。联系人：安秋凤（1965—），女，教授，E-mail：
1114593350@qq.com。