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·2320·                            精细化工   FINE CHEMICALS                                 第 40 卷

            3   结论                                             [11]  WANG B, ZHOU Y, XU N, et al. Palladium (Ⅱ)-catalyzed remote
                                                                   meta-C—H functionalization of aromatic tertiary amines[J]. Organic
                                                                   Letters, 2019, 21(6): 1885-1889.
                 本文在硅铝凝胶体系中加入高分子聚合物,成
                                                               [12]  ZHANG  Z, TANAKA K,  YU J Q.  Remote site-selective C—H
                                            2
            功合成了具有较高外表面积(110 m /g)的丝光沸石                            activation  directed by a catalytic bifunctional template[J]. Nature,
            纳米片,其负载的 Pd 催化剂在 2-苯基吡啶 C—H 键                          2017, 543: 538-542.
                                                               [13]  SHI H, HERRON  A N, SHAO  Y,  et al. Enantioselective remote
            活化的双酰基化反应中具有优异的催化活性(转化
                                                                   meta-C—H arylation and alkylation via a chiral transient mediator[J].
            率 90%~100% )和双 酰基化产 物的选择 性                             Nature, 2018, 558: 581-585.
            (79%~92%),这归因于 NS-MOR 沸石表面含有高                      [14]  QIN Y, ZHU  L H, LUO S Z. Organocatalysis in inert C—H bond
                                                                   functionalization[J]. Chemical Reviews, 2017, 117(13): 9433-9520.
                                0
                                      2+
            度分散的小粒径的 Pd 和 Pd 物种以及沸石的空间                         [15]  SHARMA  R, SHARMA  U. Remote C — H bond activation/
            位阻作用。作为对比,均相 Pd 盐催化体系中只能实                              transformations: A continuous growing synthetic tool;  Part  Ⅱ[J].
            现 2-苯基吡啶分子中 C2—H 键的活化,得到单一的                            Catalysis Reviews Science and Engineering, 2018, 60: 1-69.
                                                               [16]  GOLDING W A, PHIPPS R J. Electrostatically-directed Pd-catalysis
            单酰基化产物。而且,Pd/NS-MOR 催化剂具有良好                            in combination with C—H activation: Site-selective coupling of
            的官能团容忍度,重复使用 5 次后仍保持较高的催                               remote  chlorides with fluoroarenes and fluoroheteroarenes[J].
            化活性(转化率 95%)和目标产物的选择性(85%)。                            Chemical Science, 2020, 11: 3022-3027.
                                                               [17]  HUANG Y J (黄瑛婕), ZHU C J (朱超杰), TANG T D (唐天地).
            参考文献:                                                  Acidic zeolite HBeta catalysis for hydration of aryl alkynes to aryl
                                                                   ketones[J]. Fine Chemicals (精细化工), 2022, 39(7): 1495-1512.
            [1]   ALTAF A A, SHAHZAD A, GUL Z, et al. A review on the medicinal   [18]  TAO T Y (陶庭雨), FU W Q (傅雯倩). Preparation of a Ni 2P/HZSM-
                 importance of pyridine derivatives[J]. Journal  of Drug  Design and   5 catalyst and its catalytic performance for phenylacetylene selective
                 Medicinal Chemistry, 2015, 1(1): 1-11.            hydrogenation[J]. Fine Chemicals (精细化工), 2019, 36(5): 1-6.
            [2]   AFZAL O, KUMAR S, HAIDER M R, et al. A review on anticancer   [19] GUO  L  (郭亮), ZHANG  L (张磊), ZHANG W (张伟),  et al.
                 potential of bioactive heterocycle quinolone[J]. European Journal of   Hydroisomerization performance of acid-treated nanosized ZSM-22
                 Medicinal Chemistry, 2015, 97: 871-910.           zeolite supported Pt catalyst on n-dodecane[J]. Acta Petrolei Sinica:
            [3]   CORMA A, NAVAS J, SABATER M. Advances in one-pot synthesis   Petroleum Processing Section (石油学报:  石油加工), 2021, 37(6):
                 through borrowing hydrogen catalysis[J]. Chemical Reviews, 2018,   1321-1328.
                 118(4): 1410-1459.                            [20]  FU W, YIN C, FENG Y, et al. Synergistic catalysis of the Brönsted
            [4]   LOUILLAT M L,  PATUREAU F W. Oxidative C—H amination   acid and highly dispersed Cu on the mesoporous beta zeolite in the
                 reactions[J]. Chemical Society Reviews, 2014, 43: 901-910.   intermolecular aminoazidation of styrene[J]. Applied Catalysis A:
            [5]   CHEN  Z, WANG  B, ZHANG J,  et al. Transition metal-catalyzed       General, 2021, 609: 117907-117918.
                 C—H bond functionalizations by the use of diverse directing   [21]  DING  Y L, KE Q P, LIU  T T,  et al. An ultra-low-cost route to
                 groups[J]. Organic Chemistry Frontiers, 2015, 2: 1107-1295.   mesostructured TS-1 zeolite for effcient catalytic conversion of bulk
            [6]   HUMMEL J R, BOERTH J A, ELLMAN J A. Transition-metal-   molecules[J]. Industry Engineering Chemistry Research,  2014, 53:
                 catalyzed C—H bond addition to carbonyls, imines, and related   13903-13909.
                 polarized π bonds[J]. Chemical Reviews, 2017, 117(13): 9163-9227.   [22]  ZHANG  L, BAI  X R, FU W Q,  et al. Superior activity and
            [7]   LIANG  Y F, WANG X, TANG  C,  et al. NHPI and palladium   isomerization selectivity in n-dodecane hydroisomerization over Ni
                 cocatalyzed aerobic oxidative acylation of arenes through a radical   clusters  on ZSM-22 zeolite with  structural defects[J]. Fuel, 2023,
                 process[J]. Chemical Communications, 2016, 52: 1416-1419.   332: 126204-126216.
            [8]   DAVIES D L, DONALD S M A, MACGREGOR S A. Computational   [23]  FU W Q, FENG Y, FANG Z X, et al. Zeolite Y nanosheet assembled
                 study of the mechanism of cyclometalation by palladium acetate[J]. Journal   palladium catalysts with high catalytic activity and selectivity in the
                 of the American Chemical Society, 2005, 127(40): 13754-13755.   vinylation of thiophenes[J]. Chemical Communication, 2016, 52:
            [9]   BALCELLS D, CLOT E, EISENSTEIN O. C—H bond activation in   3115-3118.
                 transition metal species from a computational perspective[J].   [24]  YUAN G, KEANE M A.  Liquid phase hydrodechlorination of
                 Chemical Reviews, 2010, 110(2): 749-823.          chlorophenols over Pd/C and Pd/Al 2O 3: A  consideration of HCl/
            [10]  TANG R Y, LI G, YU J Q. Conformation-induced remote meta-C—H   catalyst interactions and solution pH effects[J]. Applied Catalysis B:
                 activation of amines[J]. Nature, 2015, 507: 215-220.   Environmental, 2004, 52: 301-314.
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