Page 57 - 《精细化工）》2023年第10期

第 10 期 张风帆，等: 磁性纳米片的制备及功能化应用研究进展 ·2135·

究中，着重研究操作简单、条件温和、低成本、高 magnetic nanoparticles[J]. Colloids and Surfaces A Physicochemical
质量、可以规模化应用于工业生产的制备方法，这 and Engineering Aspects, 2020, 606: 125462.
[7] HAJDU V, MURANSZKY G, PREKOB A, et al. Palladium decorated
是磁性纳米片在各个应用领域进一步发展的基础； nickel and zinc ferrite spinel nanoparticles applied in aniline
（2）制约磁性纳米片可控制备的一个最主要原因就 synthesis-development of magnetic catalysts[J]. Journal of Materials
Research and Technology, 2022, 19: 3624-3633.
是反应过程机理认识不清，尽管部分学者提出了一些 [8] JAHANI G, MALMIR M, HERAVI M M. Catalytic oxidation of
反应机理，解释了成片的机制。但磁性纳米片形貌调 alcohols over a nitrogen-and sulfur-doped graphitic carbon dot-
控的深层机理仍不明了，在后续的研究中应着重研究 modified magnetic nanocomposite[J]. Industrial & Engineering
Chemistry Research, 2022, 61(5): 2010-2022.
形貌调控深层机理，明确反应条件与其形貌调控的构 [9] LIU L H (柳利花), ZHANG P B (张萍波), FAN M M (范明明),
效关系，为规模化可控制备奠定理论基础；（3）磁 et al. Catalytic performance of magnetic (CaO-MgO)@Fe 3O 4/C solid
base catalyst for preparation of glycerol carbonate from glycerol[J].
性纳米片具有理论容量大、电子电导率高、成本低
Fine Chemicals (精细化工), 2017, 34(3): 307-312.
和安全性好等特点，使其在电极材料等新能源行业 [10] ALGAMDI M, ALSHAHRANI A, ALSUHYBANI M. Chitosan
具有巨大前景。但作为负极材料使用时，结构不稳 grafted tetracarboxylic functionalized magnetic nanoparticles for
removal of Pb(Ⅱ) from an aqueous environment[J]. International
定等问题制约了磁性纳米片的开发和应用。表面包 Journal of Biological Macromolecules, 2023, 225: 1517-1528.
覆和结构设计是提升磁性纳米片应用性能的重要 [11] SARAVANAN A, KUMAR P, GOVARTHANAN M, et al.
研究方向，特别是双碳背景下，多种材料的掺杂与 Adsorption characteristics of magnetic nanoparticles coated mixed
fungal biomass for toxic Cr(Ⅵ) ions in aquatic environment[J].
复合对提升电池循环稳定性能是十分必要的；（4） Chemosphere, 2021, 267: 129226.
磁性纳米片高各向异性场的高渗透性、高磁共振频 [12] REN K K (任凯文), WANG Y X (王雨昕), MA J C (马建超).
Fe 3O 4@SPC as catalyst for Fenton-like oxidative degradation of
率等特性使其具有优异的微波吸收性能。但是，吸
phenol[J]. Fine Chemicals (精细化工), 2022, 39(6): 1242-1249.
波性能受微观结构和材料体系的影响较大，通过对 [13] ZHANG W D, XIAO H M, ZHU L P, et al. Template-free solvothermal
磁性纳米片尺寸和结构的设计以获得更好的吸波性 synthesis and magnetic properties of novel single-crystalline
magnetite nanoplates[J]. Journal of Alloys and Compounds, 2009,
能，是未来发展的一个重要方向。同时，进一步提
477: 736-738.
高其抗氧化、抗酸解能力，也是一个需要继续深入 [14] LI C H, WEI R X, XU Y M, et al. Synthesis of hexagonal and
研究的课题；（5）由于磁性纳米片优异的磁性能、 triangular Fe 3O 4 nanosheets via seed-mediated solvothermal growth[J].
Nano Research, 2015, 7(4): 536-543.
低毒性、良好的生物相容性等特点，其广泛用作 MRI [15] ZHANG Q, CHEN R, GONG J Y, et al. Single-crystalline Fe 3O 4
的多功能造影剂，同时该技术也相对成熟。基于其 nanosheets: Facile sonochemical synthesis, evaluation and magnetic
优异的性能，进一步探究其在靶向治疗、肿瘤免疫和 properties[J]. Journal of Alloys and Compounds, 2013, 577: 528-532.
[16] REYES-REYES M, ÁVILA-NIÑO J A, LÓPEZ-SANDOVAL R,
热磁疗等医用领域的应用，特别是集上述功能于一体 et al. Thermal stability of magnetite hexagonal nanoflakes coated
的复合制剂，这可能为肿瘤患者治疗提供新策略。 with carbon layers[J]. Journal of Physics D: Applied Physics, 2016,
49(13): 135301.
参考文献： [17] REYES-REYES M, HERNÁNDEZ-ARRIAGA D, LÓPEZ-SANDOVAL
R. Carbon-coated hexagonal magnetite nanoflakes production by
[1] XUE F F, ZHU S T, TIAN Q W, et al. Macrophage-mediated spray CVD of alcohols in mixture with water[J]. Materials Research
delivery of magnetic nanoparticles for enhanced magnetic resonance Express, 2014, 1(4): 045607.
imaging and magnetothermal therapy of solid tumors[J]. Journal of [18] LAKSHMI N V, TAMBE P, PANDA B, et al. Surface modified iron
Colloid and Interface Science, 2023, 629: 554-562. oxide (Fe 3O 4) nanosheets reinforced PVDF nanocomposites: Influence
[2] ZARE M, SARKATI M N. Chitosan-functionalized Fe 3O 4 on morphology, thermal and magnetic properties[J]. Plastics Rubber
nanoparticles as an excellent biocompatible nanocarrier for silymarin and Composites, 2022, 51(4): 205-216.
delivery[J]. Polymers for Advanced Technologies, 2021, 32(10): [19] FAN N, MA X C, LIU X Z, et al. The formation of a layer of Fe 3O 4
4094-4100. nanoplates between two carbon films[J]. Carbon, 2007, 45(9): 1839-
[3] BINAYMOTLAGH R, HAGHIGHI F H, ABOUTALEBI F, et al. 1846.
Selective chemotherapy and imaging of colorectal and breast cancer [20] CHEN L Y, ZHAO C L, ZHOU Y, et al. Controlled synthesis of
cells by a modified MUC-1 aptamer conjugated to a poly(ethylene Fe 3O 4 nanosheets via one-step pyrolysis of EDTA ferric sodium salt
glycol)-dimethacrylate coated Fe 3O 4-AuNCs nanocomposite[J]. New [J]. Journal of Alloys and Compounds, 2010, 504(2): L46-L50.
Journal of Chemistry, 2019, 43(1): 238-248. [21] ZHOU Z J, ZHU X L, WU D J, et al. Anisotropic shaped iron oxide
[4] LIU J, WANG H J, LI X C, et al. Recyclable magnetic graphene nanostructures: Controlled synthesis and proton relaxation shortening
oxide for rapid and efficient demulsification of crude oil-in-water effects[J]. Chemistry of Materials, 2015, 27(9): 3505-3515.
emulsion[J]. Fuel, 2017, 189: 79-87. [22] ZHOU Z J, ZHAO Z H, ZHANG H, et al. Interplay between
[5] JAVADIAN S, KHALILIFARD M, SADRPOOR S M. Functionalized longitudinal and transverse contrasts in Fe 3O 4 nanoplates with (111)
graphene oxide with core-shell of Fe 3O 4@oliec acid nanospheres as a exposed surfaces[J]. ACS Nano, 2014, 8(8): 7976-7985.
recyclable demulsifier for effective removal of emulsified oil from [23] LIU X, CAO K Y, CHEN Y Z, et al. Shape-dependent magnetic and
oily wastewater[J]. Journal of Water Process Engineering, 2019, 32: microwave absorption properties of iron oxide nanocrystals[J].
100961. Materials Chemistry and Physics, 2017, 192: 339-348.
[6] GÁLVEZ-VERGARA A, FRESCO-CALA B, CÁRDENAS S. [24] CHEN L, XU X T, WAN L J, et al. Carbon-incorporated Fe 3O 4
Switchable Pickering emulsions stabilized by polystyrene-modified nanoflakes: High-performance faradaic materials for hybrid capacitive