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·370· 精细化工 FINE CHEMICALS 第 40 卷

Pd-Co 复合催化剂具有更低的活性衰减比例 [26-27] 。 Energy, 2020, 45(56): 32022-32038.
[11] ALCAIDE F, ÁLVAREZ G, CABOT P L, et al. Supporting PtRh
这可以用双功能机理来解释：Co 氧化物/水合氧化 alloy nanoparticle catalysts by electrodeposition on carbon paper for
物在较高电位下可以提供—OH 基团，使 Pd 表面积 the ethanol electrooxidation in acidic medium[J]. Journal of
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剂 Pd-Co/CNT，将其用于甲醇电氧化反应。结果表 [14] DING L X, WANG A L, OU Y N, et al. Hierarchical Pd-Sn alloy
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度约为 Pd/CNT 的 2.7 倍。这归因于 Pd 和 Co 之间 carbon nanotubes for methanol oxidation in alkaline media[J]. ACS
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现出最佳的催化性能，表明适量 Co 的存在有助于 1974-1979.
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