Page 97 - 《精细化工》2023年第3期

第 40 卷第 3 期 精 细 化 工 Vol.40, No.3
20 23 年 3 月 FINE CHEMICALS Mar. 2023

综论
基于 MOFs 材料光催化分解水制氢的研究进展

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李亮荣 ，梁 娇 ，彭 建 ，艾 盛 ，齐海霞
（1. 南昌大学 抚州医学院，江西 抚州 344000；2. 南昌大学 化学化工学院，江西 南昌 330031）
摘要：“双碳”目标的提出让氢能热度持续攀升，制氢技术突破是氢能连接能源消费终端的关键桥梁，光催化分
解水制氢技术是实现太阳能低碳转化的有效途径。其中，利用具有比表面积和孔隙率高、结构可调、活性位点
丰富等优势的金属有机框架（MOFs）材料光催化分解水制氢是近年来的研究热点。该文综述了国内外基于 MOFs
材料光催化分解水制氢体系中半导体复合、金属离子掺杂、敏化剂修饰和贵金属负载等方法的改性原理、技术
难点和制氢效果等，重点阐述比较了上述 MOFs 改性方法在抑制光生电子空穴对复合、优化 MOFs 禁带宽度和
增加 MOFs 活性位点等方面的作用，提出了未来 MOFs 光催化分解水制氢可深入新型 MOFs 材料开发、敏化剂
修饰工艺优化、拓展先进表征手段的研究方向。
关键词：金属有机框架；光催化剂；分解水制氢；太阳能
中图分类号：TQ116.2；O643.36 文献标识码：A 文章编号：1003-5214 (2023)03-0553-12

Research progress of photocatalytic water splitting for hydrogen

production using MOF based catalysts

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LI Liangrong , LIANG Jiao , PENG Jian , AI Sheng , QI Haixia
（1. Fuzhou Medical College, Nanchang University, Fuzhou 344000, Jiangxi, China; 2. School of Chemistry and Chemical
Engineering, Nanchang University, Nanchang 330031, Jiangxi, China）
Abstract: The hydrogen energy continues to draw extensive attention under the “double carbon” goal, of
which the breakthrough of hydrogen production technology is the key. Photocatalytic water splitting for
hydrogen production is an effective way to realize the low-carbon transformation of solar energy. The
hydrogen production via photocatalytic water splitting catalyzed by metal-organic frameworks (MOFs)
materials with high specific surface area, high porosity, adjustable structure and abundant active sites is a
research hotspot in recent years. Herein, the modification principles, technical difficulties and catalytic
performances of semiconductor composite, metal ion doping, sensitizer modification and noble metal
deposition methods in photocatalytic water splitting based on MOFs materials at home and abroad were
reviewed, with emphasis on the roles of above MOFs modification methods in inhibiting photogenerated
electron hole pair recombination, optimizing the band gap of MOFs and increasing the active sites of MOFs.
Finally, the future research directions of photocatalytic water splitting catalyzed by MOFs for hydrogen
production were also discussed, which could promote the development of new MOFs materials, optimize
the sensitizer modification process and expand the advanced characterization methods.
Key words: metal-organic frameworks; photocatalyst; hydrogen production by water splitting; solar
energy

受新冠肺炎疫情和俄乌冲突等影响，全球传统 能源，在交通、储能、建筑和分布式发电等领域都
化石能源供应日趋紧张，绿色清洁新型能源的转型 有着广阔的应用前景，是助力中国“双碳”目标和全
发展也越来越紧迫，氢能作为目前最具潜力的清洁 球能源生产消费革命、构建低碳高效能源体系的重

收稿日期：2022-06-29; 定用日期：2022-09-05; DOI: 10.13550/j.jxhg.20220605
基金项目：南昌大学抚州医学院重点科技项目（FYKJ202203）
作者简介： 李亮荣（1986—），男，副教授，E-mail：ncurong@163.com。联系人：齐海霞（1977—），女，副教授，E-mail：fylilr@163.com。