Page 127 - 《精细化工》2023年第4期
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す 4 ᰦ⿸Ͳ喑ぶ: 㘯䚝⅜ᩦᕔ̶㖇⅝㘧㵺⩌➖ࣷڣᴾ㘯ࡃᏁ⩕ g813g
and the anti-pollution performance was improved.
Key words: stearyl chloride; amidated melamines; amidated melamine resins; coating materials; rigid foam
materials; functional materials
̶㖇⅝㘧-⩟䛈ᴾ㘯ࣵ⼝ჳ㘧ᴾ㘯喑䕇፥⩞̶㖇
1 侹䘕ܳ
⅝㘧̻⩟䛈ٵ䔈㵹ߍࣺᏁᒏ䶱㖇➖喑ں㏼㑖㖇
ࣺᏁᒏڤᰶ̶㐡㑾㐉㐀Ჱ⮱㖇व➖ [1-2] ȡჳ㘧ᴾ㘯
1.1 䄂ݯ̻Зக
ڤᰶхᐯ⮱᱙ᒮ䭨⛰ᕔȠ叼㐀߈Ƞ㔽ܿ⬂ᕔࣷ☚⽠
̶㖇⅝㘧喍䉕䛼ܳō99.5%喎喑⪳⢶䆎㘎Ვ
Ⴧᕔぶ➦ᕔ喑๔䛼⩕λ叼㐀ݯȠ⊯᫆Ƞಸൾ᫆В ࡃጒᰶ䭽ڙथ喠⩟䛈⏣⋟喍䉕䛼ܳ 37%喎喑ܳᲽ㏜喑
ࣷ⩢கݣ৮ぶ䶳ഌ [3-5] ȡहᬣ喑⩞λჳ㘧ᴾ㘯ధࡃڤ
Ꭼ͉Ꭼᐼ䄂ݯឭᰶ䭽ڙथ喠㘯䚝⅜喍SCR喑䉕
ᰶ䒰倅⮱ϑ㖁ჳᏓ喑㜡Ҭࢂ㏜⮱ჳ㘧ᴾ㘯ಸᱽ᫆
䛼ܳō99.5%喎ȠᴍῙ䚥Ƞ⅏⅔ࡃ䧍ȠιΆ䚴㘧喍䉕
ᰶᭀ㘳Ƞ㑧ͼ䴔ᕔȠऄ⒛ᭀ哌㷯ぶ㑧䮤喑ݣ㏓γჳ
䛼ܳō99%喎Ƞₐጞ☤喍䉕䛼ܳō98%喎ȠᬍⅡΆ
㘧ᴾ㘯⮱ᰡᎬ∈Ꮑ⩕ȡ
䚴喍䉕䛼ܳō95%喎Ƞ㖇Άι䚴 200喍PEG-200喑
፥㻮⮱ჳ㘧ᴾ㘯ᩦᕔ∂๔็᭜ౕჳ㘧ᴾ㘯
ᎠⰥᄦܳၽ䉕䛼 200喎Ƞ㖇⅔Ά☜䓈ധ㠜䚇䛇-10
⮱ߍᝃ㑖वࣺᏁ⣜㞯ᑂڒᴁᕔ䨫⃢Ƞ⪼Ⅱ䨫⃢
Ȳキ⼝ OP-10喑㓌թͧ(87±10) mg KOH/gȳȠᄦ⩟㠜
ぶ喑В⣝ᄦჳ㘧ᴾ㘯㐀Ჱ⮱䴔ࣷ⪼Ⅱᕔ㘪⮱ ⸧䚥喍䉕䛼ܳō95%喎ぶ喑ܳᲽ㏜喑̷⊤叓ٸ᳄
[6]
ᩦ䔈ȡ࢝ぶ В̶㖇⅝㘧ͧͨ㺮ܳݣิγ䬚ႁ
⩌ࡃឭᰶ䭽ڙथ喠㧥亼Ⅱ喑㜗ݣȡ
∎⇘ൾ᫆喑ڣڤᰶхᐯ⮱䭨⛰ᕔহ☚⽠Ⴧᕔ喑ౕ̺
TENSOR27 ಸֲ䛹णअᢏ㏏ใٶ䅞ЗȠAV400
⌨ߍ䭨⛰ݯУ̸喑⅔ᠴō39%Ƞᄩ☚㈨Ō ಸᵥⷮڞᡜ ∏䅞З喑ᓤ ప Bruker ڙथ喠 Sigma
[7]
0.030 W/(m·K)ȠҀ⼜॥Ⅱ⢴Ō1.4%喠倅λ∸ぶ В
SEM300 ౧ࣾᄱម⩢ၽ᭫ᓛ䪉喍FE-SEM喎ȠZeiss
N,N-ι⩟ധΆ䚝㘧ͧ⏣ݯ喑В̶㖇⅝㘧হ็㖇⩟䛈ͧ
Sigma 300 㘪䅞ܳᲽЗ喍EDS喎喑ᓤప Zeiss ڙथ喠
࣌᫆喑ᑂڒ㓌ധᄮ〜⮱㖇ι⩟ധ⅔☤ͧᩦᕔݯ喑ᩦ
TGA/DSC3+TGA ☚䛺ܳᲽЗ喑㒻ప Mettler-Toledo
ᕔऻᴾ㘯㛉ᅯ̻Ⅱ⮱ᣒ㼓㻿䓫ݝ 91.80°喑㶕䲏㜗⩞㘪
ڙथ喠DSA-XROLL ᣒ㼓㻿≸䄂З喑Ꭼጋ䉊᠀႓
䭺㜠 28.1 mN/mȡ㔹䛴⩕㐀Ჱԛ亝䓴⮱̶㖇⅝㘧ͧ࣌ ឭᱜᰶ䭽ڙथ喠CMT4204 ಸ⩢ၽ̴㘪ᱽ᫆䄂侹ᱧ喑
᫆ᄦჳ㘧ᴾ㘯ᕔ㘪䔈㵹ᩦ䔈⮱ⵁ⾣្䖀䒰ᄾȡGO ぶ [8] 㒻➦ጒ͇㈨㐌喍͚ప喎ᰶ䭽ڙथȡ
ᄳ㖇ι⩟ധ⅔☤⅔ࡃ䛈喑ں⩕λჳ㘧ᴾ㘯⮱ 1.2 ₒ俑
व喑ᩦᕔऻჳ㘧ᴾ㘯ౕٶ⏾Ꭰ䲏̷̻Ⅱᣒ㼓㻿ज 1.2.1 AMA ⮱व
䓫 108.5°喑ѳ᭜䄒ࣺᏁₒ俑㍮⤽喑⩕ᕔ䒰ጛȡᬍ ᣔݣࣺᏁ⍖Ꮣͧ 20 Ď喑ᄳ 126 g(1 mol)̶㖇⅝
䃧᭜䦵ᄦჳ㘧䶱㖇➖ϑ㖁䓴⼸⮱ᩦᕔ喍ࢠ䓴⼸ᩦ 㘧ࣷ 300 mL ₐጞ☤ߍڒፓᰶۤࢡఋ≮Ƞᕿࢸ␡⋟
ᕔ喎喑䔅᭜̶㖇⅝㘧㐀Ჱ⮱ԛ亝喍ࢠ㐀Ჱԛ亝喎喑͑ ᫄㷲㒛⮱̶ऐ☔⨣͚喑ᤲ៹ 30 min喍200 r/min喎喠♣
ᐼ䘪᭜䕇䓴ᩦ䕍ܳၽ㐀Ჱ喑⣝ჳ㘧ᴾ㘯ᕔ㘪 ऻλ 30~90 min ␡ߍႹⰥᄦλ̶㖇⅝㘧䉕䛼 1.0%Ƞ
⮱ᩦ䔈ȡڣ͚喑䦵ᄦ̶㖇⅝㘧ܳၽ㐀Ჱ䔈㵹䃫䃎̻ 4.0%Ƞ7.0%হ 10.0%⮱㘯䚝⅜喑ᕿ⍖ࣺᏁ 60 min
ᩦ䕍喑᭜⣝ϔ➖ᕔ㘪᭫㦄ࡴࣷᩦ⮱ឭᱜڠ䩛喑 ऻ喑ᓄݝक़ AMA ⮱ᗙ⊛⋟ȡᄳᗙ⊛⋟䲆㒛ܳᅯऻ
ᄦλᐭ̶ࣾ㖇⅝㘧⮱͚䬡ҀȠߌ㘪ࡃᱽ᫆Ƞࡴ㏔ ఋᩣₐጞ☤喑↶⋭➖㏼㧥亼Ⅱ็⁎≄⋑䓴␑喑㜠 EDS
ϔ৮ឭᱜҀ㈨Ƞ⣝ϔ͇䨫⮱ࣾᆂ䘪ڤᰶ䛺㺮ᘼ ≸䄂͚↶⋭➖͚ᬍ⅜ٰ㉍ᷭܧ喑ᓄݝक़ AMA ̻᱗
Ͷ喑Ό᭜㼐̶۠㖇⅝㘧ϔ͇䨫ࣾᆂ䬛䷅⮱ധȡ ࣺᏁ̶㖇⅝㘧⮱⌤व➖喍キ⼝ AMA ⌤व➖喎ȡᄳ
᱙᪴᠌䛴⩕㘯䚝⅜ᄦ̶㖇⅝㘧䔈㵹䚝㘧ࡃᩦ AMA ⌤व➖ᩫڒ★マ͚λ 105 Ď✒ 2 h喑ᓄݝ⮪
ᕔ [9-12] 喑䔈㔹̻⩟䛈ࣷ⌤व䚴ࣺᏁ喑Ꭳ䕇䓴ᄦࣺᏁ 㞟ㆶ᱘⟣㇄ϔ➖喑ϔ⢴ō96%ȡڣݣิ䌜㏬ຯ̸ȡ
У⮱䄰ᣔ喑ܳݘݣิज㛉⮱䚝㘧ࡃჳ㘧ᴾ㘯 ऻ㐚AMA ⌤व➖जⰡᣒ⩕λव⊯ᅯᴾ㘯̻∎ᴾ
喍AMF喎̻जࣾ∎⮱ AMFȡ䛴⩕㏏ใٶ䅞Ƞᵥⷮڞ 㘯喠㇄ϔ➖㏼㉏ℼ䔈㵹ܳ⻨㏜喑В m喍ᬍⅡΆ
ᡜ⅏䅞Ƞⷠ䅞ࣷ☚䛺ܳᲽぶᄦ䚝㘧ࡃ̶㖇⅝㘧 䚴喎ńm喍Ⅱ喎=78ń22 ⮱⌤व⏣⋟ͧ⏣ݯ喑ࡴ⍖㜠
喍AMA喎Вࣷ AMF ⮱㐀ᲱȠᒏ䆹Вࣷᕔ㘪䔈㵹ܳ ఋ≮⍖Ꮣ喑䔋㐚 6 h ऻ喑ᓄݝ⮪㞟ㆶ᱘喑ࢠ㏜
Ჽᄦ℁喑Вᬻ㐀Ჱᩦᕔჳ㘧ᴾ㘯⮱㐀Ჱ̻ᕔ㘪➦ ࡃ⮱ AMA喑㞟䅞㏜Ꮣō98%喑⩕λ㐀Ჱ̻ᒏ䆹⮱㶕
ᒮ喑ͧӰ䔈ჳ㘧ᴾ㘯ᩦᕔឭᱜ⮱ࣾᆂࣷڣᏁ⩕䶳ഌ ᒮ̻ܳᲽȡᵦᢛ䚝㘧ࡃ⼸Ꮣ喍ࢠ㘯䚝⅜⌨ߍ䛼喎
⮱᠀ᆂ喑ᅑڣ᭜Ꮑ⩕λ⊯ᅯᱽ̻᫆∎ᱽ᫆䶳ഌ喑 ᄳ㏜ࡃ⮱ AMA ܳݘᴴ䃝ͧ AMA喍1.0%喎ȠAMA
ӈ̭ᰶ⯷⮱ᵵȡ 喍4.0%喎ȠAMA喍7.0%喎ȠAMA喍10.0%喎ȡڣव
