Page 128 - 《精细化工》2023年第4期

g814g ㇫㏳ࡃጒ FINE CHEMICALS す 40 ࢤ

䌜㏬ຯ̸᝭⹧喟 ܧ⣝Ⅱღᓺ◦喍۝Ⅱ͚ܧ⣝⮪㞟☌䰫⣝䆎喎喑䭺⍖㜠
60 Ď喑␡ߍ 27.6 g(0.6 mol)ᬍⅡΆ䚴ࣷ 40 g(0.2
mol)PEG-200 ⮱⌤व䚴⏣⋟喑ࣺᏁ 1.5 h ऻ喑ВιΆ
䚴㘧䄰㞯 pH=8~9喑ᓄݝ䔼ᬻ⒱⌲⋟Ҁ喑ࢠ AMF 䶱

㖇Ҁ喑ڣధक़䛼ͧ 58%~60%ȡڣݣิ䌜㏬ຯ̸᝭⹧ȡ
1.2.2 ᩦᕔჳ㘧ᴾ㘯⮱ݣิ
ᄳ AMA ⌤व➖ݣิ⮱ᴾ㘯ܳݘᴴ䃝ͧ AMF(1.0%)Ƞ
⼝ः AMA ⌤व➖㏓ 126 g(1 mol)Ƞ䉕䛼ܳ᪝ 37%
⮱⩟䛈⏣⋟ 186.5 g(2.3 mol)Ƞ4~5 g יࡃݯιΆ䚴㘧 AMF(4.0%)ȠAMF(7.0%)ȠAMF(10.0%)喠⩕̶㖇⅝
㘧ᰬᢏ AMA ⌤व➖喑ᎣᠶⰥहߍ䛼ࣷₒ俑ݣิ⮱
ߍڒ㷲ᰶᤲ៹கȠ⍖Ꮣ䃎হఋ≮ۤ܊㷲㒛⮱ 500 mL
̶ऐ☔⨣͚喑ࡴ⍖㜠 85 Ď喑ᒲ⌤व➖Ⴙڕ⏣㼐Ꭳ ჳ㘧ᴾ㘯ᴴ䃝ͧ MFȡ

1.2.3 AMF 䄂ᵤ⮱ݣิ 2008Ȩᬍᱧ⶙䉕㐊☚ݣ৮䄂侹᫦∂ȩᄦ⶙∎ᱽ᫆䔈
⼝ः 40 g AMF ᝃ MF ᴾ㘯Ƞ0.8 g ᄦ⩟㠜⸧䚥 㵹ᑜᰟᑧᏓ≸䄂喠࣯⚔ GB/T 8813ÿ2020Ȩ⶙䉕∎
⌤व౴࠭喑㒛λ὎ڤ͚᜽ಸధࡃ喍40 Ď, 8 h喎喑ᓄ ⇘ൾ᫆ࢸ㑖ᕔ㘪⮱≸Ⴧȩᄦ⶙∎ᱽ᫆䔈㵹ࢸ㑖ᑧᏓ
ݝ≸䄂⩕ AMF 䄂ᵤȡ ≸䄂ȡ
1.2.4 AMF ⊯ᅯ⮱ݣิ ᠶ⚔ GB/T 14074ÿ2017Ȩ᱕ᱽጒ͇⩕㘣㇅ݯࣷ
⼝ः 10 g AMF ᝃ MF ᴾ㘯Ƞ0.2 g ᄦ⩟㠜⸧䚥 ڣᴾ㘯ᷭ侹᫦∂ȩᄦ AMF 䔈㵹叼ᏓȠధक़䛼Ƞוႅ
⌤व౴࠭喑150 ȝm ㏬᷿䒷⊯λ⣨⦰Წധᱽ喑λ 105 Ď ᱌ぶ≸䄂ȡ
᎟✒ 60 min ऻᓄݝ AMF ⊯ᅯ䔈㵹ᕔ㘪≸䄂ȡ ᠶ⚔ GB/T 30447ÿ2013Ȩ㏠ㆠ㪱㛉ᣒ㼓㻿≸䛼
1.2.5 AMF ⶙∎ᱽ᫆⮱ݣิ ᫦∂ȩᄦ AMA ㆶҀВࣷ AMF 㛉ᅯᣒ㼓㻿䔈㵹≸䄂喠
⼝ः 10 g AMF ᝃ MF ᴾ㘯Ƞ0.5 g OP-10Ƞ0.2 g ᠶ⚔ GB/T 17657ÿ2013Ȩϧ䕍Წࣷ亝䲏ϧ䕍Წ⤳ࡃ
ᄦ⩟㠜⸧䚥⌤व౴࠭喑㒛λᓛ∏喍500 W喑2 min喎 ᕔ㘪䄂侹᫦∂ȩᄦ㛉ᅯ䔈㵹㔽↎ᕔ㘪⮱≸䄂喠ᠶ⚔
͚䔈㵹ࣾ∎ȠధࡃȠ⛌ࡃऻ䔈㵹ᕔ㘪≸䄂ȡ GB/T 9286ÿ1998Ȩ㞟␳হ⌲␳ ␳㛉⮱ܿᵩ䄂侹ȩ
1.3 㶕ᒮ̻≸䄂 ᄦ㛉ᅯ䔈㵹䭱Ɑ߈≸䄂喠ᠶ⚔ GB/T8810ÿ2005Ȩ⶙䉕
1.3.1 㶕ᒮ ∎⇘ൾ᫆॥Ⅱ⢴⮱≸Ⴧȩᄦ⶙∎ᱽ᫆Ҁ⼜॥Ⅱ⢴䔈
⩕㏏ใٶ䅞З≸Ⴧᵤ৮⮱㏏ใٶ䅞喑AMA ㆶ᱘ 㵹≸䄂ȡ
䛴⩕ KBr ࢸ❴∂喑AMF ⋟Ҁ䛴⩕ NaCl ⿄❴∂喠В
2 㐀᳉̻䃕䃧
DMSO-d 6 ͧ⏣ݯ喑⩕ᵥⷮڞᡜ∏䅞З≸Ⴧᵤ৮⮱
NMR 䅞ఫ喠⩕☚䛺ܳᲽЗ≸Ⴧᵤ৮⮱☚⽠Ⴧᕔ喑ࡴ 2.1 AMA ⮱㐀Ჱ㶕ᒮࣷᕔ䉕
⍖䕌⢴ͧ 10 Ď/min喑⅛⅁≮䛼ͧ 50 mL/min喑⍖Ꮣ 2.1.1 AMA ⮱㐀ᲱܳᲽ
㠰డͧ 30~800 Ď喠⩕ SEM 㻯ᄌ㏜ࡃ AMA ⮱㶕䲏 ⶙㘯䚝⅜̶̻㖇⅝㘧͸䬡⮱䚝㘧ࡃࣺᏁͨ㺮ࣺ
ᒏ䆹喠⩕ EDS ᄦ㏜ࡃ AMA 䔈㵹ٰ㉍ܳᲽ喠⩕ᣒ㼓 ᏁѺ◦̶ౕଗ⣜⣜ใ⅕ധ喍ÿNH 2 喎̷喑ౕᒏ᜽䚝
㻿≸䄂Зᄦᵤ৮̻Ⅱ⮱ᣒ㼓㻿䔈㵹≸䄂ȡ 㘧ധఏ喍キ⼝ͧ䚝㘧ࡃ喎⮱हᬣ喑㙞ࣨ⅜ࡃ⅏喑䕇
1.3.2 ᕔ㘪≸䄂 䓴䚝㘧䩛ᄳ䲋Ხᕔ⮱࡮̰ⷠ䨫喍ÿC 17 H 35 喎䔋ᣒ㜠
ᠶ⚔ GB/T 7019ÿ2014Ȩ㏑㐡Ⅱ−ݣ৮䄂侹᫦∂ȩ ̶ଗ⣜ȡ䚝㘧ࡃࣺᏁݺऻ̶㖇⅝㘧⮱ FTIR ̻ NMR
ᄦ䄂ᵤ䔈㵹ោࢸȠោៅᑧᏓ≸䄂喠࣯⚔ GB/T 5486ÿ 䅞ఫຯఫ 1 ᝭⹧ȡ