Page 114 - 《精细化工》2023年第5期
P. 114
·1034· 精细化工 FINE CHEMICALS 第 40 卷
荧光探针用于爽肤水中性激素含量的测定具有较好 参考文献:
的准确度。 [1] NOPPE H, LE BIZEC B, VERHEYDEN K, et al. Novel analytical
methods for the determination of steroid hormones in edible
matrices[J]. Analytica Chimica Acta, 2008, 611(1): 1-16.
[2] DISH A, NAYAK M K, KUMARI P, et al. Functional nanomaterials
based opto-electrochemical sensors for the detection of gonadal
steroid hormones[J]. TRAC-Trends in Analytical Chemistry, 2022:
116571.
[3] WANG Y F (汪元符), LIU Z B (刘志斌), XIONG Z Q (熊震球), et al.
Monitoring on thirteen kinds of sexual hormones illegally added in
skin care cosmetics by QuEChERS-UPLC-MS/MS[J]. China Licensed
Pharmacist (中国合理用药探索), 2017, 14(3): 37-45.
[4] HU B (胡贝), LI L X (李丽霞), LIU H (刘红), et al. Research progress
on detection of sex hormones in cosmetics[J]. China Surfactant
Detergent & Cosmetics (日用化学工业), 2020, 50(9): 629-637.
[5] WANG S (王珊), LI Q (李琼), WU X J (武晓剑), et al. HPLC
determination of 5 sexual hormones in cosmetic[J]. Physical Testing
and Chemical Analysis (Part B:Chemical Analysis) (理化检验: 化学
分册), 2014, 50(3): 333-337.
[6] WANG L F (王丽芳), LI Q (李琼), JIANG P H (姜佩华), et al.
Simultaneous determination of five sexual hormones in cosmetics by
high performance liquid chromatography[J]. Fine Chemicals (精细化
工), 2008, 25(5): 479-482.
[7] LIU H L (刘洪亮), DU J F (杜金凤), GUO H H (郭航红), et al.
High-efficiency liquid chromatography to determine 8 hormones in
whitening plaque cosmetics at the same time[J]. Adhesion (粘接),
图 7 不同物质对 β-CD@AuNPs-RB 荧光探针的荧光恢 2019, 40(6): 139-142.
复率影响 [8] YUE L (岳磊), LI X J (李晓静). Simultaneous determination of five
Fig. 7 Effect of different substances on fluorescence banned sex hormones in cosmetics with UPLC-MS/MS[J]. China
Surfactant Detergent & Cosmetics (日用化学工业), 2017, 48(8):
intensity of β-CD@AuNPs-RB fluorescent probe 476-480.
[9] HU B (胡贝), LI L X (李丽霞), LIU H (刘红), et al. Simultaneous
表 1 爽肤水中性激素的测定 determination of 35 sex hormones in cosmetics by ultra-performance
Table 1 Determination of sex hormones in toners liquid chromatography-tandem mass spectrometry[J]. Journal of
Instrumental Analysis (分析测试学报), 2020, 39(8): 986-992.
添加量/ 测定值/ [10] WU W Q (吴维群), SHEN C Y (沈朝烨), YANG Y L (杨玉林),
样品 回收率/% RSD(n=3)/% et al. Determination of sex hormones in liquid cosmetics by gas
(μg/g) (μg/g)
chromatography-mass spectrometry[J]. Occupational and Environmental
1.2 1.14 95.00 4.2 Medicine (环境与职业医学), 2004, 21(4): 307-309.
孕酮 2.4 2.42 100.80 1.8 [11] LIU G Y, HUANG X D, ZHENG S N, et al. Novel triadimenol
detection assay based on fluorescence resonance energy transfer
3.6 3.67 101.94 2.7 between gold nanoparticles and cadmium telluride quantum dots[J].
3.0 2.89 96.33 3.7 Dyes and Pigments, 2018, 149(1): 229-235.
雌二醇 6.0 6.14 102.33 1.2 [12] WU J S, WANG H, YANG H, et al. A novel arginine bioprobe based
on up-conversion fluorescence resonance energy transfer[J]. Analytica
9.0 8.77 97.44 1.8 Chimica Acta, 2019, 1079: 200-206.
3.0 3.14 104.67 2.6 [13] DUAN L, DU X Y, ZHAO H J, et al. Sensitive and selective sensing
system of metallothioneins based on carbon quantum dots and gold
睾酮 6.0 5.89 98.17 1.5
nanoparticles[J]. Analytica Chimica Acta, 2020, 1125:177-186.
9.0 9.17 101.89 4.7 [14] MARIA R A, ALCARAZ C, REY M, et al. Cyclodextrin polymers as
passive sampling materials for lipophilic marine toxins in
注:RSD 为相对标准偏差。 prorocentrum lima cultures and a dinophysis sacculus bloom in the
NW mediterranean sea[J]. Chemosphere, 2021, 285:1-8.
[15] AMMAR S S, MOUHAMAD K, IBRAHIM T, et al. Cyclodextrin
3 结论 diethyldithiocarbamate copper Ⅱ inclusion complexes: A promising
chemotherapeutic delivery system against chemoresistant triple negative
breast cancer cell lines[J]. Pharmaceutics, 2021, 13(1): 84-95.
采用一步水热法制备了 β-CD@AuNPs,并将其 [16] THIENPONT L M, DE BRABANDERD V I, STOCKL D, et al. Use
与 RB 结合用于检测性激素(孕酮、雌二醇、睾酮) of cyclodextrins for prepurification of progesterone and testosterone
from human serum prior to determination with isotope dilution gas
含量。基于性激素含量与 β-CD@AuNPs-RB 荧光恢 chromatography/mass spectrometry[J]. Analytical Chemistry, 1994,
66 (22): 4116-4119.
复率之间的线性关系,构建了 β-CD@AuNPs-RB 荧 [17] ZHAO Y, HUANG Y C, ZHU H, et al. Three-in-one: Sensing,
光 探针, 用于 快速定 量分 析性激 素含 量。 将 self-assembly, and cascade catalysis of cyclodextrin modified gold
nanoparticles[J]. Journal of the American Chemical Society, 2016,
β-CD@AuNPs-RB 荧光探针用于检测爽肤水中的性 138 (51): 16645-16654.
[18] ZHANG N, LIU Y Y, TONG L L, et al. A novel assembly of Au
激素含量,性激素的回收率为 95.00%~104.67%,相 NPs-β-CDs-FL for the fluorescent probing of cholesterol and its
对标准偏差(RSD)≤4.7%,证明此法用于实际样 application in blood serum[J].The Analyst, 2008, 133(9): 1176-1181.
[19] BONENFANT D, NIQUETTE P, MIMEAULT M, et al. UV-Vis and
品中性激素的测定是可靠的。此法有望在众多化妆 FTIR spectroscopic analyses of inclusion complexes of nonylphenol
品样品中快速筛选出可能存在违法添加性激素的违 and nonylphenol ethoxylate with β-cyclodextrin[J]. Water Research,
2009, 43 (14): 3575-3581.
禁化妆品,为化妆品中性激素的快速检测提供了一 [20] HAISS W, THANH N T K, AVEYARD J, et al. Determination of
size and concentration of gold nanoparticles from UV-Vis spectra[J].
种新方法。 Analytical Chemistry, 2007, 79 (11): 4215-4221.