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第 5 期 张婉萍,等: 水相介质中 CO 2 的水合转化效应及皮肤护理应用 ·1089·
的水合转化的影响基本遵循流变调节剂质量分数越 112:10386-10398.
高 CO 2 溶解量越少的规律,但流变调剂的制备工艺 [11] GALIB M, HANNA G. Mechanistic insights into the dissociation and
decomposition of carbonic acid in water via the hydroxide route: An
及分子结构同时会对 CO 2 的水合转化效应产生影 ab initio metadynamics study[J]. Journal of Physical Chemistry B,
响;(2)无机盐使得水分子钝化,降低了 CO 2 的水 2011, 115: 15024-15035.
[12] BLOMBACH B, TAKORS R. CO 2-intrinsic product, essential substrate,
合转化且基本遵循盐析效应和 HOFMEISTER 理论; and regulatory trigger of microbial and mammalian production
(3)极性较强的乙醇对 CO 2 具有增溶作用,但在较 processes[J]. Front Bioeng Biotechnol, 2015, 3: 1-11.
低质量分数下对 CO 2 的增溶作用未表现出来,丙二 [13] BUSS E. Gravimetric measurement of binary gas adsorption equilibria
of methane-carbon dioxide mixtures on activated carbon[J]. Gas
醇、1,3-丁二醇、丙三醇其本身具有一定黏度,当质 Separation & Purification, 1995, 9: 189-197.
量分数较高时对 CO 2 的溶解量有抑制作用;(4)乳化 [14] THEERAWATTANAWIT C, PROMVARANON T, RERKNIMITR
P, et al. Snail soothing and repairing cream improves skin hydration
剂对 CO 2 的水合转化要考虑到 pH 和黏度的影响,
after ablative fractional CO 2 laser: A split-face randomized double-
较为复杂,需要具体分析。 blinded placebo-controlled trial[J]. Skin Pharmacol Physiol, 2021,
此外,含 CO 2 水合转化体系对 HaCaT 细胞展现 34: 262-270.
[15] ARFIN N, BOHIDAR H B. Concentration selective hydration and
出良好的细胞相容性,对皮肤温和无刺激;通过人 phase states of hydroxyethyl cellulose (HEC) in aqueous solutions[J].
体功效评价,表明含有 CO 2 的化妆水对皮肤应用后 International Journal of Biological Macromolecules, 2012, 50: 759-767.
呈现出一定时间的保湿效果;并能调节人体皮肤的 pH。 [16] WANG R (王韧),SUN J S (孙金声),SHI X M (史晓梅), et al.
Effects of modified starch, CMC and XC on hydrate formation under
综上所述,通过对 CO 2 在水相介质中的相转化 different driving forces[J]. Journal of China University of Petroleum
效应及人体功效评价研究,为理性发展 CO 2 类化妆 (中国石油大学学报), 2021, 45: 127-136.
[17] HARIFI-MOOD A R. Solubility of carbon dioxide in binary mixtures
品产品技术开发和功效应用提供了理论依据和应用 of dimethyl sulfoxide and ethylene glycol: LFER analysis[J]. Journal
新途径。 of Chemical Thermodynamics, 2020, 141: 1-7.
[18] CHENG C (程程). Catalytic application of Lewis acid-basic sites
参考文献: coexisting MOFs in CO 2 cycloaddition[D]. Jinzhou: Bohai University (渤
海大学), 2015.
[1] VOETD V, VOET J G, PRATT C W. Fundamentals of biochemistry: [19] LI Z Y (李正要). Chemical processing of minerals[M]. Beijing:
Life at the molecular level[J]. Fundamentals of Biochemistry Life at Metallurgical Industry Press (冶金工业出版社), 2015.
the Molecular Level, 2016, 2: 480-484. [20] SERGIO M, MURGIA M, BARRY W N. Hofmeister effects in
[2] SCHWANITZ H J, BOCK M. Protective effects of topically applied cationic microemulsions[J]. Current Opinion in Colloid & Interface
CO 2-impregnated water[J]. Skin Research and Technology, 2010, 4: Science, 2004, 9: 102-106.
28-33. [21] FAN R (樊榕). Solubility and diffusivity of carbon dioxide in polyols
[3] FUKAGAWA S, TAKAHASHI A, SAYAMA K, et al. Carbon [D]. Shanghai: East China University of Science and Technology (华
dioxide ameliorates reduced desquamation in dry scaly skin via 东理工大学), 2013.
protease activation[J]. International Journal of Cosmetic Science, [22] SNEHA A P, GORDON G B. Solution properties of ethanol in
2020, 42: 564-572. water[J]. Food Chemistry, 1999, 67: 241-246.
[4] SCHMIDT J, MONNET P, NORMAND B, et al. Microcirculatory [23] WU Y (吴颖), LIU Q (刘晴), TANG W(唐文), et al. Application of
and clinical effects of serial percutaneous application of carbon complexes of Salvia miltiorrhiza volatile oil and dandelion extract in
dioxide in primary and secondary Raynaud's phenomenon[J]. VASA- cosmetics[J]. Fine Chemicals (精细化工), 2022, 39(3): 562-568.
European Journal of Vascular Medicine, 2005, 34: 93-100. [24] VILLAVERDENF M A. Bacterial cell factories for recombinant
[5] YUKI K, KAWANO S, MORI S, et al. Facial application of protein production; expanding the catalogue[J]. Microbial Cell
high-concentration carbon dioxide prevents epidermal impairment Factories, 2013, 12: 113.
associated with environmental changes[J]. Clinical, Cosmetic and [25] LIU S, HOU X, CHEN L, et al. Enhancing amplification of late-
Investigational Dermatolog, 2019, 12: 63-69. outgrowth endothelial cells by bilobalide[J]. Journal of Cellular and
[6] ALICE H, CRAIG P, JANEL S, et al. On the hydration and Molecular Medicine, 2018, 22: 3340-3352.
hydrolysis of carbon dioxide[J]. Chemical Physics Letters, 2011, [26] ZHOU H, SHI L, REN Y, et al. Applications of human skin
514: 187-195. microbiota in the cutaneous disorders for ecology-based therapy[J].
[7] KERN D M. The hydration of carbon dioxide[J]. Journal of Frontiers in Cellular and Infection Microbiology, 2020, 10: 1-12.
Chemical Education, 1960, 37: 14-23. [27] HSU K, LEE T Y, PERIASAMY A, et al. Adaptable interaction
[8] WANG X G, CONWAY W, BURNS R, et al. Comprehensive study between aquaporin-1 and band 3 reveals a potential role of water
of the hydration and dehydration reactions of carbon dioxide in channel in blood CO 2 transport[J]. The FASEB Journal, 2017, 31:
aqueous solution[J]. Journal of Physical Chemistry A, 2010, 114: 4256-4264.
1734-1740. [28] GRICE E A, SEGRE J A. The skin microbiome[J]. Nature Reviews
[9] ALAN L S, ROBERT H B. CO 2 system hydration and dehydration Microbiology, 2011, 9: 244-253.
kinetics and the equilibrium CO 2/H 2CO 3 ratio in aqueous NaCl [29] ALI S M, YOSIPOVITCH G. Skin pH: From basic science to basic
solution[J]. Marine Chemistry, 2002, 78: 65-73. skin care[J]. Acta Dermato Venereologica, 2013, 93: 261-267.
[10] NGUYEN M T, MATUS M H, JACKSON V E, et al. Mechanism of [30] BOCK M, SCHURER N Y, SCHWANITZ H J. Effects of CO 2-
the hydration of carbon dioxide: Direct participation of H 2O versus enriched water on barrier recovery[J]. Archives of Dermatological
microsolvation[J]. Journal of Physical Chemistry A, 2008, Research, 2004, 296: 163-168.