Page 71 - 《精细化工》2023年第9期

第 40 卷第 9 期 精 细 化 工 Vol.40, No.9
20 23 年 9 月 FINE CHEMICALS Sept. 2023

功能材料
聚苯胺尼龙导电织物的制备及其传感性能

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韩玮屹，彭 军，宋理阳，殷允杰，王潮霞
（江南大学 纺织科学与工程学院 生态纺织教育部重点实验室，江苏 无锡 214122）

摘要：采用低温原位聚合法在尼龙织物表面形成一层聚苯胺导电材料，并用场发射扫描电子显微镜和显微拉曼
成像光谱仪对其形貌及化学组成进行了表征，用数显万用表和电化学工作站测试了其导电性能。结果表明，聚
苯胺聚合在尼龙织物的表面，赋予尼龙织物较好的导电性，聚苯胺尼龙导电织物电导率为 31.62 S/m。聚苯胺尼
龙导电织物的电阻随应变的增大而增大，当应变回复到初始状态时，电阻逐渐恢复并接近初始值，在 3500 次拉
伸-回复循环后仍有 96.2%的高循环稳定性。聚苯胺尼龙导电织物具有良好的传感性能，在 0~15%应变范围内可
以准确监测人体的关节运动。同时，聚苯胺尼龙导电织物也具有热电性能，其塞贝克系数为 8.406 μV/K，有望
作为温差传感器。
关键词：织物传感器；热电织物；应变传感；聚苯胺；运动监测；功能材料
中图分类号：TS106；TP212 文献标识码：A
文章编号：1003-5214 (2023) 09-1919-06 开放科学 (资源服务) 标识码 (OSID)：

Preparation and sensing properties of polyaniline nylon conductive fabric

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HAN Weiyi, PENG Jun, SONG Liyang, YIN Yunjie, WANG Chaoxia
（Key Laboratory of Eco-Textile, Ministry of Education, College of Textile Science and Engineering, Jiangnan
University, Wuxi 214122, Jiangsu, China）

Abstract: A layer of polyaniline conductive material was developed on the surface of nylon fabric by low
temperature in situ polymerization, and characterized by field emission scanning electron microscopy and
microscopic Raman imaging spectrometer for morphology and chemical composition analyses. The
conductivity of polyaniline nylon fabric was then measured by digital multimeter and electrochemical
workstation. The results showed that polyaniline polymerized on the surface led to the improvement of
electrical conductivity, 31.62 S/m, of polyaniline nylon conductive fabric. The resistance of polyaniline
nylon conductive fabric increased with the increase of strain, but gradually recovered back to the initial
value when the strain returned to the initial state. The polyaniline nylon conductive fabric still maintained a
high recycle stability of 96.2% after 3500 stretching-releasing cycles. Furthermore, the polyaniline nylon
conductive fabric exhibited good sensing performance and could accurately monitor the joint movement of
human body within strain ranging from 0 to 15%. Meanwhile, the polyaniline nylon conductive fabric
displayed thermoelectric properties. With a Seebeck coefficient of 8.406 μV/K, the fabric showed good
potential in temperature sensing.
Key words: fabric sensors; thermoelectric fabrics; strain sensing; polyaniline; motion monitoring; functional
materials

织物基柔性传感器因其轻薄、灵敏度高，且具 是将导电材料与柔性基底相结合，根据导电材料的
有可穿戴功能，在军事、医疗、健康检测、娱乐等 不同，柔性织物传感器主要分为金属基柔性织物传
方面极具发展潜力 [1-3] 。开发织物基柔性传感器通常 感器 [4-5] 、聚合物基柔性织物传感器 [6-7] 以及碳基柔

收稿日期：2022-11-24; 定用日期：2023-02-25; DOI: 10.13550/j.jxhg.20221073
基金项目：国家自然科学基金（21975107）
作者简介：韩玮屹（1998—），男，硕士生，E-mail：jnuhanweiyi@163.com。联系人：王潮霞（1969—），女，教授，E-mail：
wchaoxia@sohu.com。