Page 113 - 201811

第 11 期 王明远，等: 磷化镍的制备及其催化糠醛加氢制备环戊酮 ·1899·

表 2 Ni-P 催化剂使用前、后的结构特性 Green Chemistry, 2015, 17(8): 4183-4188.
Table 2 Properties of the fresh and reused Ni-P catalyst [11] Guo J, Xu G, Han Z, et al. Selective conversion of furfural to
cyclopentanone with CuZnAl catalysts[J]. Acs Sustainable Chem
2
3
催化剂 比表面积/(m /g) 孔容/(m /g) 孔径/nm Eng, 2014, 2(10): 2259-2266.
[12] Li Mengjie (李孟杰), Zhao Huiji (赵会吉), Ding Ning (丁宁), et
使用前 20.542 0.1403 16.05
al. Selective hydrogenation of furfural to synthesize cyclopentanone
使用 5 次后 11.566 0.0564 19.50 and cyclopentanol over raney copper catalyst [J]. Fine Chemicals (精
细化工), 2015, 32(1): 116-120.
[13] Li Yuna (李玉娜), Liu Zili (刘自力), Zuo Jianliang (左建良), et al.
3 结论 Preparation of Ni-Cu-B amorphous alloy catalysts and their catalytic
hydrogenation of furfural to cyclopentanone [J]. Journal of Chemical
Engineering of Chinese Universities (高校化学工程学报), 2017,
采用溶剂热法制备得到的 Ni-P 催化剂对糠醛 31(1): 74-82.
[14] Ma Jie (马杰). Study on preparation and hydrogenation of novel
加氢制备环戊酮具有良好的催化活性，通过 XRD、 nickel phosphide catalyst[D]. Zhengzhou: Zhengzhou University (郑
SEM、TEM、H 2 -TPR、H 2 -TPD、N 2 吸附-脱附、XPS 州大学), 2016.
[15] Guan Q, Li W, Zhang M, et al. Alternative synthesis of bulk and
对催化剂进行了表征，Ni-P 催化剂颗粒直径为 supported nickel phosphide from the thermal decomposition of
80~90 nm，为介孔结构，有明显的堆积孔；催化剂 hypophosphites[J]. Journal of Catalysis, 2009, 263(1): 1-3.
[16] Krishnan K H, John S, Srinivasan K N, et al. An overall aspect of
的活化温度为 350 ℃，远低于传统程序升温还原法 electroless Ni-P depositions-A review article[J]. Metallurgical &
制备 Ni-P 催化剂的活化温度。 Materials Transactions A, 2006, 37(6): 1917-1926.
[17] Li Zhenyu (李振雨). Study on the preparation characterization and
糠醛加氢制备环戊酮的最优工艺条件为：以水 hydrodeoxygenation performance of supported nickel phophide
(Ni 2P) catalysts[D]. Qingdao: Qingdao University of Science &
作为溶剂，原料与催化剂质量比为 12，在反应温度 Technology (青岛科技大学), 2016.
150 ℃、反应压力 2.0 MPa、转速 600 r/min 的条件 [18] Sawhill S J, Layman K A, Wyk D R V, et al. Thiophene
hydrodesulfurization over nickel phosphide catalysts: effect of the
下反应 4 h，糠醛转化率为 98.87%，环戊酮收率为 precursor composition and support[J]. Journal of Catalysis, 2005,
68.65%。对催化剂进行稳定性测试，4 次重复使用 231(2): 300-313.
[19] Xu Yanli (许燕丽), Wang Xitao (王希涛). Dehydrogenation of
之后环戊酮收率仍能达到 65.40%。虽然本体 Ni-P isobutane to isobutene over nickel phosphide catalyst in the presence
of hydrogen[J]. Chemical Industry and Engineering (化学工业与工
催化剂具有较高的活性，但其表面结构以及孔道不
程), 2016, 33(2):17-22.
够稳定影响其重复使用能力，可以通过负载（载体 [20] Liu Jun(刘俊), Wang Liangliang (王亮亮), Fei Zhaoyang (费兆阳),
et al. Structure and properties of amorphous CeO 2 @ TiO 2 catalyst
为二氧化钛，分子筛等）对催化剂进行优化和改进。 and its performance in the selective catalytic reduction of NO with
NH 3[J]. Journal of Fuel Chemistry and Technology (燃料化学学报),
参考文献： 2016, 44(8): 954-960.
[21] Yu Qi (于祺), Song Hua (宋华), Song Hualin (宋华林), et al. Effect
[1] Liu S J(刘世娟), Wang Y(王玉). The exploration of the synthesis of of reduction temperature on the performance of Ni 2P /Ti-MCM-41
cyclopentanone under microwave[J]. Jilin Normal University Journal catalyst in hydrodesulfurization[J]. Journal of Fuel Chemistry and
( Natural Science Edition) (吉林师范大学学报:自然科学版), 2016, Technology (燃料化学学报), 2016, 44(8): 970-976.
37(2): 97-99. [22] Cecilia J A, Jiménez-Morales I, Infantes-Molina A, et al. Influence of
[2] Sui C, Lu G, Li X Y. Selective oxidation of cyclopentene catalyzed the silica support on the activity of Ni and Ni 2P based catalysts in the
by Pd(CH 3COO) 2-NPMoV under oxygen atmosphere[J]. Reaction hydrodechlorination of chlorobenzene. Study of factors governing
Kinetics & Catalysis Letters, 2008, 94(2): 191-198. catalyst deactivation[J]. Journal of Molecular Catalysis A Chemical,
[3] Duan Y, Song J, Yin B, et al. Oxidation of cyclopentene to 2013, 368/369(1): 78-87.
cyclopentanone catalyzed by PdCl 2-CuCl 2 system[J]. Petrochemical [23] Song H, Dai M, Guo Y T, et al. Preparation of composite
Technology, 2011, 40(3): 289-294.
[4] Chen Kang (陈康), Zhao Dongjiang (赵东江), Yang Bin (杨彬), TiO 2-Al 2O 3, supported nickel phosphide hydrotreating catalysts and
et al .Study on the synthesis of new acaricidal myzus mites[J]. Fine catalytic activity for hydrodesulfurization of dibenzothiophene[J].
Fuel Processing Technology, 2012, 96(3): 228-236.
Chemical Intermediates (精细化工中间体), 2010, 40(3): 18-20.
[5] Hronec M, Fulajtarová K. Selective transformation of furfural to [24] Wang Y, Sang S, Zhu W, et al. CuNi@C catalysts with high activity
derived from metal–organic frameworks precursor for conversion of
cyclopentanone[J]. Catalysis Communications, 2012, 24(26): 100-104.
[6] Diao Chunxia (刁春霞), Xu Zehui (徐泽辉). Study on production furfural to cyclopentanone[J]. Chemical Engineering Journal, 2016,
process of cyclopentanone[J]. Petrochemical Technology & 299: 104-111.
Economy (石油化工技术与经济), 2011, 27(5): 52-56. [25] Liu L, Lou H, Chen M. Selective hydrogenation of furfural to
[7] Lin N, Santoro F, Zhao X, et al. Vibronically resolved electronic tetrahydrofurfuryl alcohol over Ni/CNTs and bimetallic Cu, Ni/CNTs
circular dichroism spectra of (R)-(+)-3-methylcyclopentanone: a catalysts [J]. International Journal of Hydrogen Energy, 2016, 41(33):
theoretical study[J]. Journal of Physical Chemistry A, 2008, 112(48): 14721-14731.
12401-12411. [26] Nadgeri J M, Biradar N S, Patil P B, et al. Control of competing
[8] Zhang Zhennan (张振男). Study on the hydrogenation rearrangement hydrogenation of phenylhydroxylamine to aniline in a single-step
of furfural and furfuryl alcohol to synthesize cyclopentanone[D]. hydrogenation of nitrobenzene to p-aminophenol[J]. Industrial &
Dalian: Dalian Maritime University (大连海事大学), 2016. Engineering Chemistry Research, 2011, 50(9): 5478-5484.
[9] Hronec M, Fulajtárová K, Vávra I, et al. Carbon supported Pd-Cu [27] Zhou M, Zhu H, Lei N, et al. Catalytic hydroprocessing of furfural to
catalysts for highly selective rearrangement of furfural to cyclopentanol over Ni/CNTs catalysts: model reaction for upgrading
cyclopentanone[J]. Applied Catalysis B Environmental, 2016, 181: of bio-oil[J]. Catalysis Letters, 2014, 144(2): 235-241.
210-219. [28] Cueto J, Faba L, Díaz E, et al. Cyclopentanone as an alternative
[10] Fang R, Liu H, Luque R, et al. Efficient and selective hydrogenation linking reactant for heterogeneously catalyzed furfural aldol
of biomass-derived furfural to cyclopentanone using Ru catalysts[J]. condensation[J]. Chemcatchem, 2017, 9(10): 1765-1770.