Page 55 - 201812
P. 55

第 12 期               张   敏,等: PBS-co-Glu 共聚酯与磷酸酯淀粉共混制得复合材料性能                            ·2023·


                                                               Glun%/PPS 生物基复合材料。
                                                                   (2)Glu 的引入提高了 PBS-co-Glun%共聚酯
                                                               的亲水性,未改变 PBS 的晶型,使得 PBS-co-Glun%
                                                               共聚酯与 PPS 共混相容性提高,从复合材料的
                                                               FTIR、XRD 和 SEM 结果可进一步验证此结论。
                                                                   (3)随 Glu 含量的增加,PBS-co-Glun%/PPS
                                                               复合材料的断裂伸长率、酶降解率和光透过率均有
                                                               所增加;当 Glu 含量为 4%时,PBS-co-Glu4%/PPS
                                                               复合材料断裂伸长率达到最大值 98%;与 PBS/PPS

                                                               复合材料相比,PBS-co-Glu5%/PPS 复合材料酶降解
            a — PBS/PPS; b — PBS-co-Glu1%/PPS; c — PBS-co-Glu2%/PPS;
            d—PBS-co-Glu3%/PPS; e—PBS-co-Glu4%/PPS; f—PBS-co-Glu5%/PPS   率从 PBS/PPS 复合材料的 36.80%提高到 42.79%;
            图 10  PBS/PPS 和 PBS-co-Glun%/PPS 复合材料的透光率          PBS-co-Glu2%/PPS 复合材料的光透过率最大。
                  曲线
            Fig. 10    Transmittance of PBS/PPS and  PBS-co-Glun%/   参考文献:
                    PPS composites                             [1]   Sheikholeslami S  N, Rafizadeh M,  Taromi F A,  et al. Material
                                                                   properties of degradable poly(butylene succinate-co-fumarate) copolymer
                                                                   networks synthesized by polycondensation of pre- homopolyesters
                                                                   [J]. Polymer, 2016, 98: 70-79.
                                                               [2]   Siracusa V, Lotti N, Munari A, et al. Poly(butylene succinate) and
                                                                   poly(butylene succinate-co-adipate) for food packaging applications:
                                                                   Gas barrier properties after stressed treatments[J]. Polymer
                                                                   Degradation & Stability, 2015, 119: 35-45.
                                                               [3]  Gu  Ting  (辜婷), Zhu Dayong (朱大勇), Zheng Qiang (郑强), et al.
                                                                   Effects of dopamine modified talcum powder on the crystallization
                                                                   behavior and rheological properties of polylactide/polybutylene
                                                                   succinate blends[J]. Polymer Material Science and Engineering (高
                                                                   分子材料科学与工程), 2017, 33(9): 65-71.
                                                               [4]   Threepopnatkul P, Wongnarat C, Intolo W, et al. Effect of TiO 2, and
                                                                   ZnO on thin film properties of PET/PBS blend for food packaging
                                                                   applications [J]. Energy Procedia, 2014, 56: 102-111.
                                                               [5]   Yang J, Cui S, Da F, et al. Test for L-glutamate inhibition of growth
                                                                   of alternaria, by inducing resistance in tomato fruit[J]. Food
            图 11  PBS-co-Glun%/PPS 复合材料的酶降解率与 Glu 含                Chemistry, 2017, 230: 145-153.
                  量的关系                                         [6]   Mizuno S, Maeda  T, Kanemura  C,  et al. Biodegradability,
                                                                   reprocessability, and mechanical properties of polybutylene succinate
            Fig.  11    Relationship between degradation rate of   (PBS) photografted by hydrophilic or hydrophobic membranes[J].
                      composites and Glu content in PBS-co-Glun%   Polymer Degradation & Stability, 2015, 117: 58-65.
                      copolyester                              [7]   Khalil F, Galland S, Cottaz A, et al. Polybutylene succinate adipate/
                                                                   starch blends: a morphological study  for  the design of  controlled
                 复合材料的酶降解率受聚酯相对分子质量、结                          [8]   release films[J]. Carbohydrate Polymers, 2014, 108(7): 272-280.
                                                                   Jbilou F, Joly C, Galland S, et al. Biodegradation study of plasticised
            晶度、降解温度及膜表面与降解液之间的接触面积                                 corn flour/poly(butylene succinate-co-butylene adipate) blends[J].
                                                                   Polymer Testing, 2013, 32(8): 1565-1575.
            等因素共同影响。由图 11 可以看出,随着 Glu 含量                       [9]   Kanitporn S I, Koombhongse P, Chirachanchai S. Starch grafted
                                                                   poly(butylene succinate)  via conjugating reaction and its role on
            的增加,PBS-co-Glun%/PPS 复合材料的酶降解率均                        enhancing  the compatibility[J]. Carbohydrate Polymers, 2014, 102:
            增加 , PBS-co-Glu5%/PPS 复合材 料酶降 解率与                      95-103.
                                                               [10]  Luzi F, Fortunati E, Jiménez A, et al. Production and characterization
            PBS/PPS 复合材料相比,酶降解率从 36.80%提高到                         of PLA/PBS biodegradable blends reinforced with cellulose
                                                                   nanocrystals extracted from hemp fibres[J]. Industrial  Crops &
            42.79%。这是由于:首先,Glu 的引入破坏了 PBS                          Products, 2016, 93: 276-289.
            分子链的规整结构,使其规整性和对称性降低,导                             [11]  Hong G, Meng  Y, Yang Z,  et al. Mussel-inspired polydopamine
                                                                   modification of bamboo fiber and its effect on the properties of
            致共聚酯的结晶度减小、非结晶区增加,N435 酶的                              bamboo fiber/polybutylene succinate composites[J]. Bioresources,
                                                                   2017, 12(4): 8419-8442.
            活性分子更容易侵入共聚酯的非结晶区,引发酶解                             [12] Jia  Shuping  (贾淑平), Yan Zihong  (燕子红), PanYanliang (潘言
                                                                   亮 ),  et al.  Preparation and properties of polyphenols-modified
            反应;其次,随着 PBS-co-Glun%共聚酯的降解,复                          chitosan-gelatin composite membrane of walnut  peel[J]. Fine
            合材料的表面出现较多的孔洞有利于水分子进入,                                 Chemicals (精细化工), 2017, 34(8): 919-924.
                                                               [13]  Zhang Min (张敏), Xu Xiaoling (许小玲), Song Jiqing (宋吉青),
            从而促进了淀粉的水解;最后,随着 Glu 含量的增加,                            et al. Interaction between etherified PBS and CMC liquid
                                                                   composites[J]. Chemical Journal of Chinese Universities (高等学校
            PBS-co-Glun%共聚酯的相对分子质量变小(表 1),                         化学学报), 2015, 36(4): 808-814.
            有利于 PBS-co-Glun%共聚酯的降解          [14] 。             [14]  Zhang Min (张敏), Miao Nina (苗妮娜), Xu Xiaoling (许小玲),
                                                                   et al. Study on properties of PBS-co-DEG and thermoplastic starch
                                                                   blend films[J]. Engineering Plastics Applications (工程塑料与应用),
            3   结论                                                 2015, 43(3): 1-6.
                                                               [15]  Xu X, Dees D, Dechesne A, et al. Starch phosphorylation plays an
                                                                   important role in starch biosynthesis[J]. Carbohydrate  Polymers,
                 (1)采用乳液-浇注成型法成功制备了力学性                             2017, 157(10): 1628-1637.
                                                               [16]  Passauer L, Bender H, Fischer S. Synthesis and characterisation of
            能优异、光透过率高、酶降解性良好的 PBS-co-                              starch phosphates[J]. Carbohydrate Polymers, 2010, 82(3): 809-814.
   50   51   52   53   54   55   56   57   58   59   60