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第 12 期 张 敏,等: PBS-co-Glu 共聚酯与磷酸酯淀粉共混制得复合材料性能 ·2023·
Glun%/PPS 生物基复合材料。
(2)Glu 的引入提高了 PBS-co-Glun%共聚酯
的亲水性,未改变 PBS 的晶型,使得 PBS-co-Glun%
共聚酯与 PPS 共混相容性提高,从复合材料的
FTIR、XRD 和 SEM 结果可进一步验证此结论。
(3)随 Glu 含量的增加,PBS-co-Glun%/PPS
复合材料的断裂伸长率、酶降解率和光透过率均有
所增加;当 Glu 含量为 4%时,PBS-co-Glu4%/PPS
复合材料断裂伸长率达到最大值 98%;与 PBS/PPS
复合材料相比,PBS-co-Glu5%/PPS 复合材料酶降解
a — PBS/PPS; b — PBS-co-Glu1%/PPS; c — PBS-co-Glu2%/PPS;
d—PBS-co-Glu3%/PPS; e—PBS-co-Glu4%/PPS; f—PBS-co-Glu5%/PPS 率从 PBS/PPS 复合材料的 36.80%提高到 42.79%;
图 10 PBS/PPS 和 PBS-co-Glun%/PPS 复合材料的透光率 PBS-co-Glu2%/PPS 复合材料的光透过率最大。
曲线
Fig. 10 Transmittance of PBS/PPS and PBS-co-Glun%/ 参考文献:
PPS composites [1] Sheikholeslami S N, Rafizadeh M, Taromi F A, et al. Material
properties of degradable poly(butylene succinate-co-fumarate) copolymer
networks synthesized by polycondensation of pre- homopolyesters
[J]. Polymer, 2016, 98: 70-79.
[2] Siracusa V, Lotti N, Munari A, et al. Poly(butylene succinate) and
poly(butylene succinate-co-adipate) for food packaging applications:
Gas barrier properties after stressed treatments[J]. Polymer
Degradation & Stability, 2015, 119: 35-45.
[3] Gu Ting (辜婷), Zhu Dayong (朱大勇), Zheng Qiang (郑强), et al.
Effects of dopamine modified talcum powder on the crystallization
behavior and rheological properties of polylactide/polybutylene
succinate blends[J]. Polymer Material Science and Engineering (高
分子材料科学与工程), 2017, 33(9): 65-71.
[4] Threepopnatkul P, Wongnarat C, Intolo W, et al. Effect of TiO 2, and
ZnO on thin film properties of PET/PBS blend for food packaging
applications [J]. Energy Procedia, 2014, 56: 102-111.
[5] Yang J, Cui S, Da F, et al. Test for L-glutamate inhibition of growth
of alternaria, by inducing resistance in tomato fruit[J]. Food
图 11 PBS-co-Glun%/PPS 复合材料的酶降解率与 Glu 含 Chemistry, 2017, 230: 145-153.
量的关系 [6] Mizuno S, Maeda T, Kanemura C, et al. Biodegradability,
reprocessability, and mechanical properties of polybutylene succinate
Fig. 11 Relationship between degradation rate of (PBS) photografted by hydrophilic or hydrophobic membranes[J].
composites and Glu content in PBS-co-Glun% Polymer Degradation & Stability, 2015, 117: 58-65.
copolyester [7] Khalil F, Galland S, Cottaz A, et al. Polybutylene succinate adipate/
starch blends: a morphological study for the design of controlled
复合材料的酶降解率受聚酯相对分子质量、结 [8] release films[J]. Carbohydrate Polymers, 2014, 108(7): 272-280.
Jbilou F, Joly C, Galland S, et al. Biodegradation study of plasticised
晶度、降解温度及膜表面与降解液之间的接触面积 corn flour/poly(butylene succinate-co-butylene adipate) blends[J].
Polymer Testing, 2013, 32(8): 1565-1575.
等因素共同影响。由图 11 可以看出,随着 Glu 含量 [9] Kanitporn S I, Koombhongse P, Chirachanchai S. Starch grafted
poly(butylene succinate) via conjugating reaction and its role on
的增加,PBS-co-Glun%/PPS 复合材料的酶降解率均 enhancing the compatibility[J]. Carbohydrate Polymers, 2014, 102:
增加 , PBS-co-Glu5%/PPS 复合材 料酶降 解率与 95-103.
[10] Luzi F, Fortunati E, Jiménez A, et al. Production and characterization
PBS/PPS 复合材料相比,酶降解率从 36.80%提高到 of PLA/PBS biodegradable blends reinforced with cellulose
nanocrystals extracted from hemp fibres[J]. Industrial Crops &
42.79%。这是由于:首先,Glu 的引入破坏了 PBS Products, 2016, 93: 276-289.
分子链的规整结构,使其规整性和对称性降低,导 [11] Hong G, Meng Y, Yang Z, et al. Mussel-inspired polydopamine
modification of bamboo fiber and its effect on the properties of
致共聚酯的结晶度减小、非结晶区增加,N435 酶的 bamboo fiber/polybutylene succinate composites[J]. Bioresources,
2017, 12(4): 8419-8442.
活性分子更容易侵入共聚酯的非结晶区,引发酶解 [12] Jia Shuping (贾淑平), Yan Zihong (燕子红), PanYanliang (潘言
亮 ), et al. Preparation and properties of polyphenols-modified
反应;其次,随着 PBS-co-Glun%共聚酯的降解,复 chitosan-gelatin composite membrane of walnut peel[J]. Fine
合材料的表面出现较多的孔洞有利于水分子进入, Chemicals (精细化工), 2017, 34(8): 919-924.
[13] Zhang Min (张敏), Xu Xiaoling (许小玲), Song Jiqing (宋吉青),
从而促进了淀粉的水解;最后,随着 Glu 含量的增加, et al. Interaction between etherified PBS and CMC liquid
composites[J]. Chemical Journal of Chinese Universities (高等学校
PBS-co-Glun%共聚酯的相对分子质量变小(表 1), 化学学报), 2015, 36(4): 808-814.
有利于 PBS-co-Glun%共聚酯的降解 [14] 。 [14] Zhang Min (张敏), Miao Nina (苗妮娜), Xu Xiaoling (许小玲),
et al. Study on properties of PBS-co-DEG and thermoplastic starch
blend films[J]. Engineering Plastics Applications (工程塑料与应用),
3 结论 2015, 43(3): 1-6.
[15] Xu X, Dees D, Dechesne A, et al. Starch phosphorylation plays an
important role in starch biosynthesis[J]. Carbohydrate Polymers,
(1)采用乳液-浇注成型法成功制备了力学性 2017, 157(10): 1628-1637.
[16] Passauer L, Bender H, Fischer S. Synthesis and characterisation of
能优异、光透过率高、酶降解性良好的 PBS-co- starch phosphates[J]. Carbohydrate Polymers, 2010, 82(3): 809-814.