Page 165 - 201808
P. 165
第 8 期 何 柏,等: 减四线馏分油的酯化脱酸反应 ·1413·
表 2 酯化脱酸前后的主要理化指标对比 [9] Wang Y Z, Liu Y P, Liu C G. Removal of naphthenic acids of a
Table 2 Comparison of main physicochemical indexes second vacuum fraction by catalytic esterification[J]. Petroleum
Science and Technology, 2008, 26: 1424-1432.
before and after the deacidification [10] Li X H, Zhu J, Liu Q, et al. The removal of naphthenic acids from
dewaxed VGO via esterification catalyzed by Mg–Al hydrotalcite[J].
指标 原料油 脱酸后
Fuel Processing Technology, 2013, 111: 68-77.
酸值/(mgKOH/g) 2.51 0.19 [11] He Bai (何柏), Wang Jiankang (汪建康), You Xiaolan (游晓兰), et
al. Deacidification of vacuum gas oil by catalytic esterification[J].
3
密度/(g/cm ) 0.96 0.88 Petrochemical Technology (石油化工), 2013, 42 (11): 1282-2285.
2
运动黏度(50 ℃)/(mm /s) 628.6 604.6 [12] Li Zifeng (李子峰), Tian Songbai (田松柏), Wang Zijun (王子军).
Study on esterification for reducing total acid number of high acid
闪点/℃ 252 263 crude oil by Mg/Al oxides[J]. Petroleum Process and Petrochemicals
(石油炼制与化工), 2009, (8): 50-53.
[13] Jia Xiaolin (贾晓林), Zhang Haijun (张海军), Tan Wei (谭伟), et al.
3 结论 Synthesis of nano-ZnO powder by homogeneous precipitation
method[J]. Rare Metal Materials and Engineering (稀有金属材料与
工程), 2004, 33(9): 992-995.
(1)采用饱和浸渍法制备了 ZnO/Al 2 O 3 催化剂 [14] Zhang Yongqiang (张永强), Li Yong (李永). Analysis about zinc
oxide with XRD and TG –DTA[J]. Journal of Henan Institute of
并对减四线馏分油进行了酯化脱酸反应。结果表明, Education (NaturalScience) (河南教育学院学报:自然科学版).
在减四线馏分油用量为 40 g、催化剂用量为馏分油 2009, 18(4): 25-27.
[15] Gu Guishan (顾桂山), Zhang Yuanyuan (张园园), Huang Chi (黄
质量的 2.5%、脱酸剂乙二醇用量为馏分油质量的 驰), et al. Synthesis of ZnO nanometer powders doped with Ce~(4+)
ions and the photocatalytic degradation of dying wastewater[J].
4%、反应温度 250 ℃、反应时间为 1.0 h 的条件下, Journal of Changshu Institute Technolog (Natural Sciences) (常熟理
减四线馏分油的脱酸率达到 92.43%。优选的脱酸体 工学院学报(自然科学)), 2014, 28(4): 55-60.
[16] Deng Fang (邓芳), Li Yuexiang (李越湘), Luo Xubiao (罗旭彪), et
系对减二线馏分油也有不错的脱酸效果。 al. The effect of calcination temperature, calcination time and
3+
Fe -doped amount on the photocatalytic activity of TiO 2[J].
(2)制备的催化剂重复使用 5 次以上依然具有 Materials Review (材料导报), 2010, 24(10): 83-86.
较高的催化活性,催化酯化脱酸率仍近 92%。 [17] Yan Xiangyun (闫翔云), Ma Bo (马波), Ji Honghai (季洪海), et al.
Effect of calcination temperature on physical and chemical properties
(3)减四线馏分油脱酸前后的 FTIR 表征结果 and microstructure of alumina[J]. Contemporary Chemical Industry
(当代化工), 2011, 40(3): 248-251.
显示,精制油中没有羧酸特征吸收峰,新增了酯基 [18] Wang XiaoLei (王晓蕾), Pan Xiangmin (潘相敏), Lin Rui (林瑞), et
特征吸收峰,表明减压馏分油中的乙二醇和环烷酸 al. Dimethyl ether steam reforming for hydrogen production over
Cu-Ni/γ-Al 2O 3 bi-functional catalyst[J]. Acta Phys-Chim Sin (物理化
13
反应转化为酯类,实现了脱酸目的,这也为 CNMR 学学报), 2010, 26(5): 1296-1304.
[19] Wang Xiaolei (王晓蕾), Ren Kewei (任克威), Pan Xiangmin (潘相
所证实。 敏), et al. Influence of solid acid catalysts on steam reforming of
(4)与原料油相比,酯化脱酸后馏分油的酸值 dimethyl ether for hydrogen production[J]. Chinese Journal of
Catalysis (催化学报), 2009, 30(4): 297-304.
得到了大幅度降低,而其他部分主要理化性质变化 [20] Liang Xu (梁旭), Liu Yanxia (刘艳侠), Jiang Yuanli (蒋元力), et al.
Preparation and characterization of silicon modified alumina and
不大。 supported nickel based catalysts[J]. Industrial Catalysis (工业催化),
2015, 23 (1): 41-44.
参考文献: [21] Zhai Dewei (翟德伟), Yue Yinghong (乐英红), Hua Weiming (华伟
明), et al. Esterification and transesterification on Al 2O 3-doped
[1] Mao Jincheng (毛金成), Liu Jiawei (刘佳伟), Li Yongming (李勇 sulfated Tin oxide solid acid catalysts[J]. Acta Phys-Chim Sin (物理
明), et al. Research and development of super heavy oil viscosity 化学学报), 2010, 26(7): 1867-1872.
reducer[J]. Applied Chemical Industry (应用化工), 2016, 45(7): [22] Xie Li (谢丽), Zhang Wei (张伟), Li Zifeng (李子锋), et al. Study on
1367-1370. the application of ultrasonic in the esterification deacidification of
[2] Chen Qingtao (陈清涛), Zhu Yulong (朱玉龙), Qin Yiming (秦一 high acid crude oil[J]. Petroleum Process and Petrochemicals(石油
鸣), et al. Development status of high acid crude oil deacidification 炼制与化工), 2010, 41(1): 6-10.
technologies[J]. Contemporary Chemical Industry (当代化工), 2014, [23] Gong Guanqun (巩冠群), Wang Ruixue (王瑞雪), Hu Yong (胡勇),
43 (6): 1053-1055. et al. Synthesis and application of starch-AM-DAC grafe copolymer
[3] Zhong Dule (钟读乐), Wang Yanzhen (王延臻), Han Xiaotong (韩晓 with reversed phase emulsion polym erization[J]. China Chemicals
nd
彤), et al. A research on deacidification of 2 vacuum distillations by (化工文摘), 2009, (1): 28-30.
catalytic decomposition[J]. Petroleum Process and Petrochemicals [24] Wang Hualin (王华林), Tang Chao (唐超), Shi Tiejun (史铁钧), et
(石油炼制与化工), 2012, 43(5): 10-13. al. Research on polyurethane/SiO 2 organic-Inorganic hybrid
[4] JLA Filho,LGM Moura,ACS Ramos. Liquid-liquid extraction and material[J]. Polymer Materials Science and Engineering(高分子材
adsorption on solid surfaces applied to used lubricant oils 料科学与工程), 2006, 22(4): 250-253.
recovery[J]. Brazilian Journal of Chemical Engineering, 2010, 27(4): [25] Cao Meizhu (曹美珠), Pan Liping (潘丽萍), Zhang Chaolan (张超
687-697. 兰 ), et al. Surface characteristics of four biochars and their
[5] Li Jianghao (李江浩), Dai Yongchuan (戴咏川), Wu Shikui (吴世 adsorption of Cd and atrazine in aqueous solution[J]. Journal of
逵). Study on removing naphthenic acid from naphthenic base Agro-Environment Science (农业环境科学学报), 2014, 33(12):
distillate by amine alcohol method[J]. Contemporary Chemical 2350-2358.
Industry (当代化工), 2015, 44(12): 2759-2762. [26] Zhang Bo (张波), Li Jie (李解), Zhang Xuefeng (张雪峰), et al.
3+
2+
[6] Wu Yan (吴雁), Yan Chenyang (闫琛洋), Wang Hao (王豪). Study Activation and mechanism of Cu and Fe in flotation system of
on the esterification reaction for removing the acids from crude oil fluorite ore[J]. Chinese Journal of Rare Metals (稀有金属), 2016,
using Mg-Al hydrotal-cite as catalyst[J]. Chemical Engineering of 40(9): 963-968.
Oil & Gas (石油与天然气化工), 2009, 38(2): 129-131. [27] Wang J, Gu S S, Pang N, et al. Study of the esterification of caffeic
[7] MK Khan, A Riaz, M Yi, et al. Removal of naphthenic acids from acid with methanol using p-toluenesulfonic acid as a catalyst[J]. J.
high acid crude via esterification with methanol[J]. Fuel Processing Serb. Chem. Soc, 2013, 78 (7): 1023-1034.
Technology, 2017, 165: 123-130. [28] He Leqin, Qin Shenjun, Chang Tao, et al. Biodiesel synthesis from
[8] Ding Jincheng, Xia Zheng, Lu Jie. Esterification and deacidification the esterification of free fatty acids and alcohol catalyzed by
of a waste cooking oil (TAN 68.81 mg KOH/g) for biodiesel long-chain Brønsted acid ionic liquid[J]. Catal Sci Technol, 2013, 3:
production[J]. Energies, 2012, 5(8): 2683-2691. 1102-1107.