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透过率影响较小,可见光透过率均在 85%以上,而 参考文献:
对近红外屏蔽性能影响较大。400 ℃煅烧 2 h 时,所 [1] Chang Tianhai, Huang Guangzhou, Yu Jirong, et al. Thermal
制粉体晶粒平均粒径小,但结晶性差,晶体中存在 shielding and energy saving performance of ITO film used on
automobile front windshield [J]. Journal of South China University
大量的晶格缺陷,导致近红外屏蔽性能不佳。当煅
of Technology, 2002, 30(7): 74-77.
烧温度提高至 600 ℃时,晶型生长趋于完整,缺陷 [2] Yang Lili, He Xiaodong, He Fei. ITO coated quartz fibers for heat
减少,而且晶粒平均粒径也没增大较多,粉体性能 radiative applications [J]. Materials Letters, 2008, 62(30):
4539-4541.
较好,红外屏蔽性能迅速提高,达到 70%左右。但 [3] Zhou Li (周莉). The preparation and performance research of
是,煅烧温度提高至 800 ℃时,近红外屏蔽效果反 doped-VO 2 superfine powder [D]. Dalian: Dalian Polytechnic
而变差。主要原因是,煅烧温度的提高,不仅促进 University (大连工业大学), 2010.
[4] Fu Qun (傅群), Chu Xiangfeng (储向峰), Lin Chen (林晨). The
了晶型的完整,同时促进了晶体的生长,晶粒平均 preparation and performance characteristics of VO 2 [J]. Journal of
粒径迅速增大,内聚力增大,团聚严重,降低了粉 Inorganic Material (无机材料学报), 2004, 19(4): 767-771.
体在涂料中的分散性,导致近红外屏蔽性能降低。 [5] Li Ning, Meng Qinglin, Zhang Nan. Dispersion stabilization of
antimony-doped tin oxide (ATO) nanoparticles used for energy-
所以,600 ℃煅烧 2 h 所合成 Cs 0.30 WO 3 粉体的光学 efficient glass coating [J]. Particuology, 2014, 17(6): 49-53.
性能较好。 [6] Qu Jian, Song Jianrong, Qin Jie, et al. Transparent thermal insulation
coatings for energy efficient glass windows and curtain walls [J].
Energy and Buildings, 2014, 77(10): 1-10.
[7] Wang kun (王琨). Hydrothemal preparation of tungsten oxides its
application in transparent heat insulation coating [D]. Taiyuan:
Taiyuan University of Technology (太原理工大学), 2014.
[8] Peng Zhanjun (彭战军), Shi Fei (史非), Tang Nailing (唐乃岭), et al.
Hydrothermal synthesis of cesium tungsten bronze (Cs xWO 3) and its
insulation performance research [J].Materials Review (材料导报),
2012, 26(19): 341-343.
[9] Liu J, Xu Q, Shi F, et al. Dispersion of Cs 0.33WO 3 particles for
preparing its coatings with higher near infrared shielding properties
[J]. Applied Surface Science, 2014, 309(4): 175-180.
[10] Xu Qiang (徐强). The preparation of Cs 0.33WO 3 powder and the
study of transparent insulation coating [D]. Dalian: Dalian
图 8 煅烧温度对 Cs 0.30 WO 3 粉体的紫外-可见-近红外透 Polytechnic University (大连工业大学), 2014.
[11] Luo Jiayu (罗嘉宇). The preparation of M xWO 3 tungsten bronze and
射光谱图影响
its performance research [D]. Dalian: Dalian Polytechnic University
Fig. 8 Effect of calcination temperature on UV-Vis-NIR (大连工业大学), 2014.
transmission spectra of Cs 0.30 WO 3 powders [12] Hussain A, Gruehn R, Rüscher C H. Crystal growth of alkali metal
tungsten bronzes M xWO 3 (M = K, Rb, Cs) and their optical properties
[J]. Cheminform, 1997, 28(24): 51-56.
3 结论 [13] Mamak M, Choi S Y, Stadler U, et al. Thermal plasma synthesis of
tungsten bronze nanoparticles for near infra-red absorption applications
采用溶胶-凝胶法,系统考察了铯钨物质的量 [J]. Journal of Materials Chemistry, 2010, 20(44): 9855-9857.
[14] Takeda H, Adachi K. Near infrared absorption of tungsten oxide
比、分散剂种类和煅烧温度对铯钨青铜粉体晶型、 nanoparticle dispersions [J]. Journal of the American Ceramic
形貌、晶粒平均粒径及光学性能的影响。结果表明: Society, 2007, 90(12): 4059-4061.
反应物铯钨物质的量比为 0.33、分散剂为 PEG-600、 [15] Orel B, Krašovec U O, Grošelj N, et al. Gasochromic behavior of
sol-gel derived Pd doped peroxopolytungstic acid (W-PTA)
氩气气氛下 600 ℃煅烧 2 h 时,可制得晶型完整, nano-composite films[J]. Journal of Sol-Gel Science and Technology,
分 散性和 近红 外屏蔽 性能 均较好 的铯 钨青 铜 1999, 14(3): 291-308.
[16] Guo Juan(郭娟), Lu Xifeng(卢喜凤), Gao Chaojun(郜超军), et al.
Cs 0.3 WO 3 粉体,Cs 0.3 WO 3 涂层的可见光透过率在
Effect of element A on crystal structure of tungsten bronze
85%以上,近红外阻隔率在 70%左右。 (A xWO 3)[J]. Journal of Functional Materials(功能材料), 2015,
下一步将系统考察铯钨青铜浆料的分散稳定 46(17):17008-17013.
[17] Bueno-Ferrer C, Parres-Esclapez S, Lozano-Castelló D, et al.
性,并应用于透明隔热涂料中,优化其光学性能和
Relationship between surface area and crystal size of pure and doped
隔热性能。 cerium oxides[J]. Journal of Rare Earths, 2010, 28(5): 647-653.