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·1300· 精细化工 FINE CHEMICALS 第 36 卷

能良好，有望在水性树脂、涂料和胶粘剂等功能材
料领域得到应用。

参考文献：
[1] Li Peitao (李培涛). Analysis and prediction of the gum rosin market
trend in 2014-2015[J]. Biomass Chemical Engineering (生物质化学
工程), 2015, 49(3): 39-48.
[2] Liu Xiongmin (刘雄民), Qin Rongxiu (秦荣秀), Huang Pinxian(黄
品鲜),et al. Oxidation reaction kinetics of abietic acid and rosin
under ultraviolet light irradiation[J]. Acta Phys-chim Sin(物理化学
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[3] Li Dongmei (李冬梅), Li Qian (李前), Zhao Zhendong (赵振东), et
图 8 超支化聚酯胶体溶液的粒径分布图 al. Study on preparation of bio-fuel oil from rosin residue in industria
Fig. 8 Particle size distribution of hyperbranched polyester ldeep processes[J]. Biomass Chemical Engineering (生物质化学工
colloid solution 程), 2010, 44(4): 13-16.
[4] Chen Yuxiang (陈玉湘), Zhao Zhendong (赵振东), Gu Yan (古研),
如图 8 所示，该超支化聚酯的胶体粒径主要有 et al. Study on composition variation relationships of pimaric-type
两个峰，第一个峰平均粒径为 5.53 nm，占比为 resin acids in rosin at acidic conditions[J]. Fine Chemicals (精细化
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37.0%；第二个峰平均粒径为 53.73 nm，占比为 [5] Gulacti T, Ramazan E, Osman C, et al. Diterpenes from the berries of
46.3%。整个体系的平均粒径为 22.14 nm，远小于 Juniperus excelsa[J]. Phytochemistry, 1999, 50(7): 1195-1199.
100 nm，说明该聚酯在水中乳化分散性能很好，可 [6] Smith E, Williamson E, Zloh M, et al. Isop imaric acid from pinus
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形成胶体溶液，可用于水性树脂的制备。 Staphylococcus aureus[J]. Phytotherapy Research, 2005, 19(6): 538-
2.3 水性大豆油-松香基超支化聚酯固化膜的性能 542.
[7] Wang Chunping (王春平), Lei Fuhou (雷福厚), Li Hao (李浩), et al.
测试
Synthesis and structural characterization of the plasticizer tri-lauryl
取 1.3 节制备的大豆油-松香基超支化聚酯胶体 maleopimarate[J]. Chemistry and Industry of Forest Products (林产
溶液，用湿法涂膜器将胶体溶液均匀涂布于 120 mm 化学与工业), 2011, 31(4): 46-52.
[8] Liu He (刘鹤), Xu Xu (徐徐), Gao Hong (高宏), et al. Synthesis and
50 mm 的马口铁片上，置于真空干燥箱中在 120 ℃
properties of maleopimaric acid polyester polyol[J]. Paint & Coatings
进行热固化反应 2 h。所得固化膜表面光滑、透明； Industry (涂料工业), 2013, 43(1): 53-55.
附着力为 1 级；铅笔硬度 3H；抗冲击强度>50 cm； [9] Ge C, Greenland B W, Lampard C, et al. Hyperbranched polymers
containing oxazoline monomers and succinic anhydride: Applications
柔韧性曲率半径为（0.5 0.1） mm。测试结果表明， in fast drying, low solven coating formulationss[J]. Progress in
所得固化产物有良好的柔韧性、硬度、耐冲击强度 Organic Coatings, 2014,77(10): 1516-1522.
及附着力，预期其可应用于水性树脂、涂料和胶粘 [10] Asif A, Wen F S. Synthesis and properties of UV curable waterborn
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3 结论 hyperbranched polyesters with vinylic end groups of different length
as modifiers of epoxy/anhydride thermosets[J]. Reactive &
（1）水性大豆油-松香基超支化聚酯较佳的制 Functional Polymers, 2012, 72(1): 556-563.
[12] Atta A M, Nassar I F, Bedawy H M. Unsaturated polyester resins
备工艺条件如下：大豆油投料量为松香质量的 50%， based on rosin maleic anhydride adduct as corrosion protections of
顺丁烯二酸酐投料量为松香质量的 20%，加入丙三 steel[J]. Reactive & Functional Polymers, 2007, 67(7): 617-626.
[13] Sun Liting (孙丽婷), Chen Yuxiang (陈玉湘), Xu Jian (徐建), et al.
醇使物料羟羧比为 0.86，恒温酯化反应温度 250 ℃，
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恒温反应时间为 3 h。 polyester[J]. Chemistry and Industry of Forest Products (林产化学与
（2）FTIR 分析表明，该超支化聚酯末端基团 工业), 2013, 33(3): 1-6.
[14] Zhang Haibo (张海波), Min Denghao (闵邓昊), Chen Yuxiang (陈玉
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相对分子质量为 1475~1798，相对分子质量分布系 acid (MPA) and PEG-400 and its UV curing[J]. Thermosetting Resin
数为 1.90~3.67。热重分析表明，该超支化聚酯具有 (热固性树脂), 2015, 30(5): 20-23.
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较高的热稳定性能。 biocomposites based on plant oil precursors[J]. European Polymer
（3）该水性大豆油-松香基超支化聚酯可制备 Journal, 2013, 49 (6): 1243-1256.
成黄色透明胶体溶液，体系平均粒径为 22.14 nm， [16] Tang Bingtao (唐炳涛), Zhao Jie (赵杰), Zhang Shufen (张淑芬).
Synthesis of styrene-maleic anhydride alternating copolymers by
粒径分布表明该聚酯在水中分散性良好。 solution polymerization[J]. Fine Chemicals (精细化工), 2010, 27(3):
（4）该水性大豆油-松香基超支化聚酯成膜性 217-221.