Page 28 - 《精细化工》2020年第6期

·1094· 精细化工 FINE CHEMICALS 第 37 卷

3 总结与展望 [4] HUANG Y (黄昱), LI X M (李小明), YANG Q (杨麒), et al.
Application of advanced oxidation processes to antibiotic wastewater
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过渡金属硫化物在地球上的储量十分丰富，具
13-17.
有良好的导电性、机械稳定性和热稳定性。TMS 可 [5] MALIK S N, KHAN S M, GHOSH P C, et al. Treatment of
作 Fenton/类 Fenton 反应的（助）催化剂，促进 pharmaceutical industrial wastewater by nano-catalyzed ozonation in
a semi-batch reactor for improved biodegradability[J]. Science of the
2+
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Fe /Fe 循环，提高反应速率；与金属化合物复合 Total Environment, 2019, 678: 114-122.
可以提高电导率；与碳基材料复合可原位生成 [6] ZHU Y P, ZHU R L, XI Y F, et al. Strategies for enhancing the
heterogeneous Fenton catalytic reactivity: A review[J]. Applied
H 2 O 2 。TMS 还可直接活化过硫酸盐；通过与金属化
Catalysis B-Environmental, 2019, 255: 117739.
合物或碳基材料复合可提高电导率，增强催化活性。 [7] XIAO R, LUO Z, WEI Z, et al. Activation of peroxymonosulfate/
具有带隙可调特性的 TMS 可作光催化剂；通过元素 persulfate by nanomaterials for sulfate radical-based advanced
oxidation technologies[J]. Current Opinion in Chemical Engineering,
掺杂改性可增加活性位点，降低带隙宽度；通过与 2018, 19: 51-58.
金属化合物或碳基材料复合可降低光生电子-空穴 [8] MATAFONOVA G, BATOEV V. Recent advances in application of
UV light-emitting diodes for degrading organic pollutants in water
对的重组速率，提高光催化性能。今后，TMS 在
through advanced oxidation processes: A review[J]. Water Research,
AOPs 中的研究可从以下 4 个方面进行： 2018, 132: 177-189.
（1）光照、电/磁场、溶解氧等因素的变化可能 [9] GHIME D, GHOSH P. Removal of organic compounds found in the
wastewater through electrochemical advanced oxidation processes: A
会对 TMS 参与的 AOPs 去除有机污染物的性能产生 review[J]. Russian Journal of Electrochemistry, 2019, 55(7): 591-620.
影响。尽管对单个物理因素辅助的 AOPs 进行了研 [10] SUN Y (孙怡), YU L L (于利亮), HUANG H B (黄浩斌), et al.
Research trend and practical development of advanced oxidation
究，但对于不同物理因素组合是否也会促进有机污
process on degradation of recalcitrant organic wastewater[J]. CIESC
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途径上，而对于非均相 TMS 催化剂与水溶性氧化剂 [12] RADISAVLJEVIC B, RADENOVIC A, BRIVIO J, et al.
和污染物间的表面接触以及固液传质的报道较少， Single-layer MoS 2 transistors[J]. Nature Nanotechnology, 2011, 6(3):
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是模拟废水，尽管都表现出对单一目标污染物的高 979-990.
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–
–
干扰杂质，如以 Cl 和 HCO 3 为代表的阴离子和以腐 processes for organic wastewater treatment[J]. Journal of Environmental
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植酸和蛋白质为代表的天然有机物，这些杂质对 [15] NAVALON S, DE MIGUEL M, MARTIN R, et al. Enhancement of
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性更强的中间产物，都有待进一步研究； [16] HUANG C P, HUANG Y H. Comparison of catalytic decomposition
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要从天然矿物或工业废弃物中寻找有效的催化剂，
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