Page 59 - 《精细化工》2020年第9期

第 9 期 武小明，等: 一种检测铜离子的荧光探针及其应用 ·1773·

2.6 应用研究 [2] KREITMAN G Y, DANILEWICZ J C, JEFFERY D W, et al.
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为了验证 P1 的实用性，对葡萄酒和啤酒样品中 model wine. Part 2: Iron-and copper-catalyzed oxidation[J]. Journal
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Cu 的浓度进行了检测。将 3 种不同品牌的葡萄酒 of Agricultural and Food Chemistry, 2016, 64: 4105-4113.
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P1（10 μmol/L）体系中，测定样品中 Cu 的浓度。 Relationship with and effects on wine chemical composition[J].
Journal of Agricultural and Food Chemistry, 2017, 65: 9488-9495.
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中检测出不同质量浓度 Cu ，分别为 0.56、0.47、 [5] KONTOUDAKIS N, GUO A, SCOLLARY G R, et al. The impact
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限量标准。加标回收率为 90.00%~108.30%，说明 319-328.
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P1 对葡萄酒和啤酒中的 Cu 有良好的检测能力。结 [6] VELA E, HERNÁNDEZ-ORTE P, FRANCO-LUESMA E, et al. The
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表 1 葡萄酒和啤酒中 Cu 浓度的测定 Macromolecules, phenolic and sulfur compounds[J]. Food Research
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Table 1 Determination of Cu concentrations in wines [8] KREITMAN G Y, DANILEWICZ J C, JEFFERY D W, et al. Copper
and beers (Ⅱ)-mediated hydrogen sulfide and thiol oxidation to disulfides and
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Cu 计算 Cu 添加 Cu 测试 相对标准 organic polysulfanes and their reductive cleavage in wine: Mechanistic
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%
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本研究合成了一种用于检测 Cu 的 P1。在 P1 disease gene is a putative copper transporting P-type ATPase similar
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