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·102·                             精细化工   FINE CHEMICALS                                 第 38 卷

                 由图 6 可知,起始时 DDS-β-CD 乳液的平均粒                       and properties of  waxy corn starch esters with  different molecular
            径为 4.42 μm,随时间的延长,乳液的粒径逐渐变小,                           weight[J]. Food Industry Technology (食品工业科技), 2019, 40(22):
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            48 h 后乳液平均粒径变化趋于平稳。其原因可能是                          [9]   YIN Z H (尹沾合), QIN W (覃雯), BAI J (白俊), et al. Study on the
            随时间的推移,乳液中的油相逐渐分离出来,导致                                 preparation and interaction of starch octenylsuccinate[J]. Food
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            乳液粒径变小,在 48 h 后乳液趋于稳定状态,致使
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            乳液中的油相分离极为缓慢,粒径变化较小,并且                                 anhydride starch ester by semi-dry method with vacuum-microwave
            乳液在放置 120 h 后,上层并未见明显油相,表现                             assistant[J]. International Journal of Biological Macromolecules,
                                                                   2019, 141: 1128-1136.
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            3   结论                                                 octenyl succinate[J]. Jiangsu Agricultural Sciences (江苏农业科学),
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                 FTIR 表征证实以 DDSA 和 β-CD 为原料成功制                 [12]  LI Y P (李彦萍), CHEN P (陈佩). Preparation and structure
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            备了 DDS-β-CD;TGA 分析发现 DDS-β-CD 的热稳                      Sciences (江苏农业科学), 2015, 43(7): 268-271.
            定性有所降低,但其耐热性仍能满足在多种领域的                             [13] HU  Y  N  (胡艳娜). Preparation of  octane succinic cyclodextrin
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            应用。随 DDS-β-CD 取代度的增大,其溶解性提高,
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            当 DDS-β-CD 取代度为 0.198 时,其质量分数为 6%                      南理工大学), 2017.
            的水溶液的透光率仍可达 97%以上。当 DDS-β-CD                       [14]  LI G T, XU X, ZHU F. Physicochemical properties of dodecenyl
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            取代度为 0.295 时,HLB 值高达 16.520,为亲水性
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            乳化剂。DDS-β-CD 具有一定的起泡能力,与相同                         [15]  WANG Q (汪茜), LI D (李迪), WANG X F (王小凤), et al. Study on
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            随取代度增大,DDS-β-CD 乳化能力相应提高,与                         [16]  JING P F (荆鹏飞), LIU H J (刘慧君), HU C (胡趁), et al. Progress
            相同质量分数的 SDS 相比,合成产品对液体石蜡的                              in preparation and application of β-cyclodextrin derivatives[J]. Fine
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            乳化能力较差,而对植物油的乳化能力与 SDS 相当。
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            由 DDS-β-CD 配制的水包植物油乳液的起始平均粒                            aqueous self-assembly of octenylsuccinic corn dextrin ester with high
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            CD 有望作为一种绿色功能性乳化剂。                                                2+
                                                                   Adsorption of Pb  by crosslinked carboxymethyl tamarind gum[J].
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