Page 114 - 《精细化工》2020年第2期

·316· 精细化工 FINE CHEMICALS 第 38 卷

CO 2 、N 2 ）起到稀释易燃气体的作用，阻燃剂的加 (化工学报), 2013, 64(1): 182-197.
入延缓了 MCC 的燃烧。在 434~600 ℃之间，失重 [6] LIU H (刘晖), SHI T J (史铁钧), WU X L (吴星林). Synthesis of
pyridine-based polyether ionic liquid and mechanical properties of its
较为缓慢，其次，MP、APP 加热易失水，生成高交 curing system with epoxy resin[J]. Plastics Manufacture (塑料制造),
联度的氮磷化合物炭层附着于 MCC 基体上，隔离 2011, (3): 70-73.
[7] ZHAO H L (赵海丽), TANG Z X (汤正新), ZHANG Q G (张庆国),
了热量的相互传递作用。纳米 SiO 2 的加入增强了 et al. Inorganic synthesis in ionic liquids[J]. Progress in Chemistry
MCC 的刚性，提高了燃烧物的残炭率 [22] 。 (化学进展), 2009, 21(10): 2077-2083.
[8] GUO L Y (郭立颖), ZHANG B (张彬), WANG Z M (王志明), et al.
Preparation of phenolic resin composites with functional ionic liquids
and their liquefaction product of wood powder[J]. Acta Polymerica
Sinica (高分子学报), 2015, (5): 556-563.
[9] SWATLOSKI R P, SPEARP S K, HOLBREY J D, et al. Dissolution
of cellose with ionic liquids[J]. Journal of the American Chemical
Society, 2002, 124(18): 4974-4975.
[10] LAI S L (来水利), WANG H (王花), LI C H (李晨辉), et al.
Synthesis and process optimization of [CmVIM]Cl ionic liquid[J].
Applied Chemical Industry (应用化工), 2020, 49(1): 126-129.
[11] National Textile Standardization Technical Committee. Testing
method of degree of polymerization oframie cellulose: GB/T 5888—
1986[S]. Beijing: China Standard Press (中国标准出版社), 1986:

1-11.
图 8 MCC-0 与 MCC-12 的 TG 曲线 [12] WANG L L (王琳琳), WEI L G (魏立纲), MA Y C (马英冲), et al.
Fig. 8 TG curves of MCC-0 and MCC-12 Effect of 1-butyl-3-methylimidazolium chloride-water mixtures on
cellulose[J]. CIESC Journal (化工学报), 2015, 66(1): 32-37.
[13] XU H Z, BRONNER T, YAMAMOTO M, et al. Regeneration of
3 结论 cellulose dissolved in ionic liquid using laser-heated melt-
electrospinning[J]. Carbohydrate Polymers, 2018, 201: 182-188.
[14] National Plastics Standardization Technical Committee. Plastics—
（1）当溶解温度为 90 ℃，TBAC 含量为 8%时， Determination of burning characteristics—Horizontal and vertical
[CmVIM]Cl/TBAC 体系对 MCC 的溶解率达 6.3%， test: GB/T2408—2008[S]. Beijing: China Standard Press (中国标准
出版社), 2008: 1-18.
此时 MCC 的聚合度降至 505，结晶度为 46.4%，表 [15] National Plastics Standardization Technical Committee. Plastics—
明此溶剂对 MCC 具有良好的溶解性。 Determination of burning behaviour by oxygen index—Part 1:
（2）相比于原 MCC，再生 MCC 结晶度降低， Guidance: GB/T 2406. 1—2008[S]. Beijing: China Standard Press
(中国标准出版社), 2008: 1-7.
晶型结构由纤维素Ⅰ转为纤维素Ⅱ，热稳定性下降， [16] MA H (马浩), LIAO C Y (廖春燕), FAN M L (樊梅林), et al.
且其表面粗糙呈不规则结构，为 MCC 的转化利用 Dissolution of cellulose in carboxylate-based task-specific ionic
liquids[J]. Chinese Journal of Applied Chemistry (应用化学), 2018,
提供了崭新的平台。
35(4): 449-456.
（3）当 MP、APP、SiO 2 的质量分数分别为 5%、 [17] XU Y G (许耀光). Synthesis of novel imidazole ionic liquids and
10%、10%时，阻燃纤维素复合材料的阻燃效果最佳， their solubility to cellulose[D]. Fuzhou: Fujian Agriculture and
Forestry University (福建农林大学), 2017.
LOI 为 33.5%，垂直燃烧等级为Ⅴ-0，拓宽了 MCC [18] CUI Y H (崔玉虎). Study on dissolution and regeneration of
的应用领域。 cellulose in the new solvent system[D]. Chengdu: Southwest
Jiaotong University (西南交通大学), 2017.
参考文献： [19] LIU H B, SALE K L, HOLMES B M, et al. Understanding the
interactions of cellulose with ionic liquids: A molecular dynamics
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[5] LI C Z (李昌志), WANG A Q (王爱琴), ZHANG T (张涛). Progress Preparation of PAA/ATP nanocomposites and their flame retardancy
of conversion of cellulose resource in ionic liquids[J]. CIESC Journal for leather[J]. Fine Chemicals (精细化工), 2018, 35(2): 298-302.