Page 211 - 《精细化工》2021年第3期
P. 211
第 3 期 徐 琴,等: 超分散剂对紫色中性墨水颜料分散影响及应用 ·631·
[6] HUANG R (黄睿), DUAN P X (段培修), SHEN Y J (沈永嘉).
Practices of improving processes of the productions of some
high-performance organic pigment[J]. Shanghai Dyestuff (上海染
料), 2014, 42(2): 34-36.
[7] MU Z Y (穆振义). Synthetic process and modification technology of
C. I. Pigment Violet 23(Ⅱ)[J]. Shanghai Dyestuff (上海染料), 2019,
47(3): 16-24.
[8] MEI L (梅林). Polymeric dispersant performance in water-based
organic pigment dispersion[D]. Shanghai: Fudan University (复旦大
学), 2010.
[9] JIN Z Z (金逐中). Structure of pigment and the effect of dispersing
agent[J]. Modern Paint & Finishing (现代涂料与涂装), 2016, 19(1):
39-42.
[10] LIU J (刘佳), LU X P (卢秀萍), WU M (吴蒙), et al. Hyperdispersant
and its application in pigment dispersion[J]. Shanghai Coatings (上海
A—百乐(左)、得力(中)、自制(右)笔迹浸水前;B—百乐 涂料), 2009, 47(1): 29-31.
[11] WU H T, HUANG K Y, LEE K T. Supercritical fluid-assisted dispersion
(左)、得力(中)、自制(右)笔迹浸水 24 h 后 of C. I. Pigment Violet 23 in an organic medium[J]. Powder Technology,
图 12 百乐、得力、自制中性墨水耐水性 2011, 206(3): 322-326.
Fig. 12 Hydrolytic resistance of the gel ink made by [12] NSIB F, AYED N, CHEVALER Y. Selection of dispersants for the
dispersion of C. I. Pigment Violet 23 in organic medium[J]. Dyes and
PILOT, DELI and homemade Pigments, 2007, 74(1): 133-140.
[13] CHEN R Q (陈荣圻). Energy saving and emission reduction pigment
从图 12 可以看出,得力中性笔笔迹在浸泡 24 h printing and dyeing and auxiliaries (Ⅰ)[J]. Textile Auxiliaries (印染
助剂), 2019, 36(12): 1-6.
后笔迹完全消失,但百乐、自制紫色墨水笔迹依然 [14] LIU C S (刘草生), ZHANG Q L (张千林), XIAO Y L (肖云玲),
清晰可见。结合划线仪划线结果说明自制中性墨水 et al. Application of sand mill in solvent and water-based ink
dispersion grinding[J]. Adhesion (粘接), 2020, 41(3): 15-18.
虽然颜色较暗,但其耐水性与百乐中性墨水相当, [15] SHEN H (沈浩). Basic professional knowledge and skills of coating
industry (nine)[J]. Shanghai Dyestuff (上海染料), 2014, 42(6): 57-59.
比得力中性墨水好。 [16] DEBASHISH M, CARLOS M M, KURT K. Polymer collapse in
miscible good solvents is a generic phenomenon driven by preferential
3 结论 adsorption[J]. Nature Communications, 2014, 12(5) : 4882-4887.
[17] ZHENG X (郑雄), HE M G (何茂刚), ZHANG Y (张颖), et al. Study
of the conformation change of poly(ethylene oxide) in water and
本文采用超分散剂 6076 对颜料紫 23 进行分散, tert-butanol binary solvent[J]. Journal of Engineering Thermophysics
(工程热物理学报), 2020, 41(1): 7-11.
通过优化分散剂添加量,得到分散剂在 15%时分散 [18] CAO J (曹娟), ZHANG Z Z (张振忠), ZHAO F X (赵芳霞), et al.
效果最佳,此时可得到 D 90 为 138 nm 的色浆,其高 The effect of different surfactants on the dispersion properties of
serpentine in the alcohol solvent[J]. Lubrication and Sealing (润滑与
温储存 30 d 粒径变化不超过 5 nm,比吸光度 r 为 密封), 2007, 32(10): 83-86.
[19] GONG J P (宫建平). Observation of Brownian motion[J]. Physical
96%,离心稳定性较好,最佳研磨时间为 2.5 h。通 Experiment (物理实验), 1996, 16(4): 182-183.
过对比颜料紫 23、6076 及色浆的红外光谱图得出, [20] DONG X (董霞), ZHANG B (张宾), HE J X (何瑾馨). Influence of
dye-polyether derivatives architecture on the adsorption to the surface
分散剂在颜料紫 23 上的吸附推动力应为分散剂的 of its parent dye particle[J]. Chinese Journal of Synthetic Chemistry
(合成化学), 2010, 18( A1): 70-76.
疏水基团稠环芳烃与颜料紫 23 上苯环结构的 π-π 堆 [21] ZHOU Y (周煜). The dispersion stability and rheology of C. I. Pigment
积作用。自制的色浆调配成中性墨水后触变值为 Red 122 suspension[D]. Shanghai: Donghua University (东华大学),
2003.
5.48,流变性能符合国家标准,与百乐、得力紫色 [22] HOU Q C (侯其超). Research on dispersion and stability of organic
pigments[D]. Beijing: Beijing Institute of Printing Technology (北京
中性墨水相比颜色偏深,线条无明显差别,出墨量 印刷学院), 2017.
与百乐、得力中性墨水相接近,划线长度大于 400 m, [23] ZHANG Z (张卓), HE X (何璇), LI L (李琳). Synthesis and performance
of polyacrylate resin used on pigment-dispersion[J]. Liquid Crystal
符合国家标准,耐水性远好于得力牌紫色中性墨水, and Display (液晶与显示), 2010, 25(4): 481-485.
[24] HU Z L (胡卓林), HAO R G (郝瑞光), LIU S J (刘守军), et al. The
为有机颜料分散剂的选择提供了方向,为颜料型彩 effect of dispersant on the stability and thixotropy of gel ink[J].
色中性墨水的开发提供了参考。 China Writing Instruments (中国制笔), 2009, (4): 14-18.
[25] LIU S J (刘守军), HE C X (贺晨霞), FENG B H (冯博洪), et al.
Study on the correlation between gel ink rheological property and
参考文献: writing performance[J]. Journal of Taiyuan University of Technology
[1] FANG Z Q (方震乾). Optimization of synthesis process and pigmentation (太原理工大学学报), 2013, (3): 259-263.
of C. I. Pigment Purple 23[D]. Shanghai: East China University of [26] SHEN H (沈辉). Quality improvement and rheological characterization
Science and Technology (华东理工大学), 2006. of carbon black gel ink[D]. Shanghai: East China University of
[2] ZHANG H J (张合杰). Pigment violet 23[J]. Shanghai Dyestuff (上 Science and Technology (华东理工大学), 2012.
海染料), 2020, 48(1): 14-16. [27] CHEN Y J (陈义军), YAO H Z (姚鹤忠). Effect of rheological
[3] CHEN X H (陈信华). Illustrated varieties and properties of organic properties of neutral ink on writing performance[J]. China Writing
pigments for plastic coloring (Ⅹ)[J]. Shanghai Dyestuff (上海染料), Instruments (中国制笔), 2014, (1): 4-26.
2018, 46(3): 34-36. [28] LI Y Y (李月月). Study on formula optimization of pigment neutral
[4] WANG X (王璇). Some engineering problems and solutions of ink[D]. Taiyuan: Taiyuan University of Technology (太原理工大学),
organic pigments[D]. Shanghai: East China University of Science 2014.
and Technology (华东理工大学), 2013. [29] State Administration for Market Regulation, Standardization
[5] MU Z Y (穆振义). Synthetic process and modification technology of Administration of China. Gel ink ball pen and refills: GB/T 37853—
C. I. Pigment Violet 23(Ⅰ)[J]. Shanghai Dyestuff (上海染料), 2019, 2019[S]. Beijing: China Standard Press (中国标准出版社), 2019:
47(2): 23-30. 1-24.