Page 59 - 《精细化工》2021年第5期
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第 5 期                    余   瞻,等:  绿色合成细菌纤维素及其在面膜基材上的应用                                  ·913·


            的纳米纤维管束使V C 进入BC面膜基材需要经过更长                         与控制释放能力也远超无纺布及蚕丝面膜基材。因
            的路径和时间,从而导致 BC 的吸附速率有所减缓。                          此, BC 是制备面膜基材的一个优良选择。后续可对
            2.6.2   各种面膜基材对营养物质控释能力测试                          BC 面膜基材进一步进行细胞、小鼠等体外体内实
                 图 8 为 3 种面膜基材对营养物质 V C 的控制释放                  验,以评价 BC 面膜基材在创面修复、皮肤美白等
            结果。由图 8 可知,无纺布面膜基材在前 30 min 已                      方面的特性,为其在护肤品方向上的应用提供可靠
            释放了大部分的营养物质,随后缓慢释放至 90 min                         的理论支撑。
            达到平衡;蚕丝面膜基材在 30 min 时对营养物质的
                                                               参考文献:
            释放量达到最大,而 BC 面膜基材的最大释放量在
                                                               [1]   National Standards Committee for Perfumery and Flavor Chemicals.
            60 min。这因为 BC 内部的复杂结构使得营养物质的                           Mask: QB/T2872—2017[S]. Beijing: China Standard Press (中国标
                                                                   准出版社), 2017: 1-5.
            充分释放需要经过比其他两种基材更长的路径,因                             [2]   CAO G Q (曹光群). Formulation and preparation technology of 8
            而也就需要更长的时间。就释放总量而言,BC 面膜                               kinds of facial mask[J]. Detergent & Cosmetics (日用化学品科学),
                                                                   2015, 38(4): 50-52.
            基材均高于其他两种面膜基材,其对 V C 的最大释放                         [3]   HU T T (胡婷婷), JIA Q M (贾庆明), SHAN S Y (陕绍云). Progress
                                 2
            量约 为 10.96 µg/cm ,约 为无纺布 面膜基 材                         in application of cellulose based mask materials[J]. Cellulose Science
                                                                   and Technology (纤维素科学与技术), 2018, 26(4): 60-67.
                       2
                                                         2
            (6.08 µg/cm )的 1.80 倍,蚕丝面膜基材(5.35 µg/cm )          [4]   PACHECO G, DE MELL  C V, CHIARI-ANDRÉO B G,  et al.
                                                                   Bacterial cellulose skin masks—Properties and sensory tests[J].
            的 2.05 倍。这表明在使用时间充足的情况下,BC                             Journal of Cosmetic Dermatology, 2018, 17(5): 840-847.
                                                               [5]   FAEZAH E, SITI M T, NORLIZA A R. Overview  of bacterial
            面膜基材能使皮肤接收到更多的营养物质,获得充                                 cellulose production and application[J]. Agriculture and Agricultural
            分护理。而在实际应用中面膜的敷脸时间一般为                                  Science Procedia, 2014, 2: 113-119.
                                                               [6]   ABRAL H, LAWRENSIUS V, HANDAYANI D, et al. Preparation of
            20~30 min,在该使用时间下 BC 面膜基材中的营养                          nano-sized particles from bacterial cellulose using ultrasonication and
                                                                   their characterization[J]. Carbohydrate Polymers, 2018, 191: 161-167.
            物质虽然释放量依然略高于无纺布与蚕丝面膜基                              [7]   TANG J (唐静), HUI M (惠明), LIAO A M (廖爱美), et al. Structure
            材,却得不到充分释放。基于相同面积下 BC 面膜                               characterization and performance test of bacterial cellulose produced
                                                                   by Gluconacetobacter Xylinum G31[J]. Fine Chemicals (精细化工),
            基材的高持水锁水能力,可通过控制 BC 面膜基材                               2018, 35(9): 1524-1528.
                                                               [8]   PERUGINI P, BLEVEl M, REDONDI R, et al. In vivo evaluation of
            的厚度以减少营养物质释放至外界所需时间,从而                                 the effectiveness  of biocellulose facial masks as active delivery
            提高 BC 膜的释放速率以减少营养物质的浪费。这                               systems to skin[J].  Journal of Cosmetic Dermatology, 2020, 19(3):
                                                                   725-735.
            说明利用 BC 制备的面膜基材在经过处理优化后能                           [9]  HU Y  (胡英), LI Z (李喆), KE Q F (柯勤飞), et al. Characterization
                                                                   of crystalline structure of natural cellulose[J]. Synthetic Fiber
            够拥有比无纺布与蚕丝更优越的效果。                                      Industry (合成纤维工业), 2018, 41(3): 78-81.
                                                               [10]  LYU H H (吕鸿皓), XIA X F (夏秀芳), DANG M M (党苗苗), et al.
                                                                   Characteristics and application of bacterial cellulose[J]. Food Safety
                                                                   and Quality Detection Technology (食品安全质量检测学报), 2015, (1):
                                                                   170-175.
                                                               [11] LUO B (罗冰), ZHAO S Q (赵树全). Study on culture conditions of
                                                                   nata producing strain[J]. China Brewing (中国酿造), 2012, 31(5):
                                                                   137-140.
                                                               [12]  WANG L,  WU X  J, CHEN S Y,  et al. Preparation of hyaluronic
                                                                   acid-bacterial cellulose biological  mask by  in situ  modification[J].
                                                                   Materials Review, 2015, 29(6): 43-47.
                                                               [13]  National  Technical Committee for Plastics Standardization.  Test
                                                                   method for water vapor permeability of plastic film and sheet—Cup
                                                                   method: GB/T1037—1988[S]. Beijing: China Standard Press (中国
                                                                   标准出版社), 1988: 3-5.
                                                               [14]  National Standardization Administration of China. Determination of
                                                                   tensile properties of plastics: GB/T1040.3—2006[S]. Beijing: China
                                                                   Standard Press (中国标准出版社), 2006: 1-4.
                                                               [15]  NIE Y, CHEN  C  T, ZHU C L,  et al. Research on absorbing and
                  图 8  3 种面膜基材对 V C 的控制释放曲线                        releasing behavior  of bacterial cellulose facial  mask to nutrient[J].
            Fig. 8    Controlled release curves of  V C  on three  mask   Applied Chemical Industry, 2014, 43(10): 1767-1770.
                   substrates                                  [16]  RANI M U, UDAYASANKAR K, APPAIAH K A A. Properties of
                                                                   bacterial cellulose produced in grape  medium by native isolate
                                                                   Gluconacetobacter sp[J]. Journal of Applied Polymer Science, 2015,
            3   结论                                                 120(5): 2835-2841.
                                                               [17]  VASILIKI A, MEM D E, ERMINDA T,  et al. Synthesis and
                                                                   characterization of bacterial cellulose from  citrus-based sustainable
                 利用木糖驹形氏杆菌经生物合成制备的 BC 具                            resources[J]. ACS Omega, 2018, 3(8): 10365-10373.
            有远比无纺布及蚕丝面膜基材更小的直径,且结构                             [18]  LI Z, WANG L F, HUA J C, et  al.  Production of nano  bacterial
                                                                   cellulose from waste water of candied jujube-processing industry
            致密,结晶度 83.46%,属于典型的Ⅰ型纤维素。与                             using  Acetobacter xylinum[J]. Carbohydrate Polymers, 2015, 120:
                                                                   115-119.
            无纺布和蚕丝面膜基材相比,相同面积的 BC 面膜                           [19]  SHAO Z B (邵仲柏), CAO L G (曹联攻), JIANG K J (蒋凯俊), et
            基材能够容纳更多的精华液,并能截留大量蒸发的                                 al. Research progress of fiber composite mask base cloth[J]. China
                                                                   Textile Leader (纺织导报), 2020, (3): 47-49.
            精华液,拥有更好的持水、锁水性能及力学性能。                             [20]  WU X J (吴旭君). Fabrication and evaluation  of  nanocellulose
                                                                   masks and their functionalized products[D]. Shanghai: Donghua
            此外,相同面积的 BC 面膜基材对营养物质的吸附                               University (东华大学), 2014.
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