Page 17 - 《精细化工》2022年第5期
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第 5 期                  沈一鸣，等:  天然多糖与纳米材料在皮革无铬鞣制中的研究进展                                    ·871·


            能及综合成本等方面仍存在不足，尚不能完全取代                                 Production, 2020, 244: 118706.
            铬鞣剂，主要存在以下问题：                                      [3]   UKHUREBOR K E, AIGBE U O, ONYANCHA R B, et al. Effect of
                                                                   hexavalent chromium on the environment and removal techniques: A
                （1）天然多糖类材料经醛基化改性后应用于鞣                              review[J]. Journal of Environmental Management, 2021, 280:
            革，易部分过度氧化成酸，影响其鞣制效果。因此，                                111809.
                                                               [4]   WU B D, YU S Y, ZHANG G Y, et al. Role of complexation in the
            需在其氧化降解的过程中，调控其分子尺寸以及醛
                                                                   photochemical reduction of chromate by acetylacetone[J]. Journal of
            基化程度，避免其过度氧化。与此同时，天然多糖                                 Hazardous Materials, 2020, 400: 123306.
            类材料经酸化改性后，往往需要结合一些金属盐才                             [5]   LIMA C G, MONTEIRO J L, DE MELO LIMA T, et al. Angelica
                                                                   Lactones: From biomass-derived platform chemicals to value-added
            能实现较好的鞣制作用，而金属盐又易导致皮表面                                 products[J]. ChemSusChem, 2018, 11(1): 25-47.
            过鞣，且多数天然多糖鞣剂鞣制后坯革主体颜色偏                             [6]   RORRER J E, BELL A T, TOSTE  F D. Synthesis of biomass-
            黄，对于白湿皮的鞣制仍存在技术挑战。此外，相                                 derived ethers for  use as fuels and  lubricants[J]. ChemSusChem,
                                                                   2019, 12(13): 2835-2858.
            比于传统铬鞣，其鞣制后成革的丰满性略有不足，                             [7]   JIANG Z C, GAO M, DING W,  et al. Selective degradation and
            坯革等电点降低，不利于后续工段中阴离子材料的                                 oxidation of hemicellulose in corncob to  oligosaccharides: From
                                                                   biomass into masking agent for sustainable leather tanning[J].
            渗透与结合，易产生染色不均、易染花等问题。后
                                                                   Journal of Hazardous Materials, 2021, 413: 125425.
            期研发时，可以尝试引入纳米材料或者改善合成条                             [8]   SATHISH M, MADHAAN B, SREERAM K J,  et al. Alternative
            件等以提高鞣制后坯革的丰满度、白度及正电性等。                                carrier medium for sustainable leather manufacturing—A review and
                                                                   perspective[J]. Journal of cleaner production, 2016, 112: 49-58.
                （2）纳米复合鞣剂的研究过程中，将 MMT、
                                                               [9]   MITCHELL M J, BILLINGSLEY  M M, HALEY  R M,  et al.
            MOFs 等纳米材料用于皮革鞣制，与皮胶原的交联                               Engineering precision nanoparticles for drug delivery[J]. Nature
            度不足，导致胶原纤维松散性较低，不利于后续工                                 Reviews Drug Discovery, 2021, 20(2): 101-124.
                                                               [10]  LI Y ( 李运 ). Study of amphoteric vinyl polymer/inorganic
            段材料的渗透，仍未达到理想的鞣制效果。后期纳                                 nanocomposite tanning agent and its modification of collagen
            米材料的鞣制重点应着眼于如何与皮胶原上的活性                                 fiber[D]. Xi'an: Shaanxi University of Science & Technology (陕西
                                                                   科技大学), 2013.
            基团产生更多的牢固交联，研究方向不在纳米材料
                                                               [11]  JIA L, MA J  Z,  GAO D G,  et al. Facile preparation approach of
            本身，而在于优化其结构，增加与胶原的作用位点，                                nanocomposite based on water-soluble polymer and layered double
            探究其与胶原的作用机理，致力于提高二者间的共                                 hydroxides for the enhancement of leather dyeing[J]. Applied Clay
                                                                   Science, 2018, 152: 22-28.
            价交联，而非弱的氢键、静电作用等。后期研发时，                            [12]  GAO D G, WANG P P, SHI J B, et al. A green chemistry approach to
            通过调控纳米粒子的尺寸以及分散性，同时配合引                                 leather tanning process: Cage-like octa (aminosilsesquioxane)
                                                                   combined with tetrakis (hydroxymethyl) phosphonium sulfate[J].
            入一些天然多糖类材料，有望提高其在皮胶原内的
                                                                   Journal of Cleaner Production, 2019, 229: 1102-1111.
            渗透与扩散，进而增加与胶原的作用位点。                                [13]  HU H Y (胡浩岩), LYU S H (吕生华), LEI Y (雷颖), et al. Synthesis
                （3）新型鞣剂材料的研制与其配套工艺的开发                              and tanning  properties of Fe-based metal organic framework
                                                                   MIL-53-Fe[J]. Fine Chemicals (精细化工), 2019, 36(5): 963-970.
            密不可分，后期可以简化工艺，创新旧工艺，甚至                             [14]  WANG J C, DU  W N, ZHANG  Z T,  et al. Biomass/polyhedral
            颠覆传统工艺，应积极开发适用于无铬鞣剂的工艺                                 oligomeric silsesquioxane nanocomposites: Advances in preparation
            以及后续工序的材料（复鞣剂、加脂剂、染料等），                                strategies and performances[J]. Journal of Applied Polymer Science,
                                                                   2020, 138(2): 49641.
            形成相对完善的无铬鞣体系，从而在未来完全取代                             [15]  SOO L B, ABDULLAH M, SOO T B, et al. Polymer nanocomposites
            现有铬鞣系统。                                                based on silylated-montmorillonite: A review[J]. Progress in Polymer
                 总之，传统皮革行业迫切需要转型升级，实现                              Science, 2018, 85: 57-82.
                                                               [16]  MA J Z, GAO  D G, LYU B,  et al.  Study on PVP/C-MMT
            绿色制革、清洁制革，主体阶段在于鞣制的绿色化，                                nanocomposite  material  via  polymer  solution-intercalation
            而天然多糖与纳米材料的结合使用，有望减少铬鞣                                 method[J]. Materials and Manufacturing Processes, 2007, 22(6):
                                                                   715-720.
            剂的用量甚至取缔铬鞣剂。未来无铬鞣制生产技术
                                                               [17]  GAO D G, CHENG Y M, WANG P P, et al. An eco-friendly approach
            在新理论、新材料、新技术的带动下定能够顺利解                                 for leather manufacture based on P(POSS-MAA)-aluminum tanning
            决生产需求与环境保护之间的矛盾问题。                                     agent combination tannage[J]. Journal of Cleaner Production, 2020,
                                                                   257: 120546.
            参考文献：                                              [18]  MA J Z, YANG N, GAO  D  G,  et al. Layered double hydroxide/
                                                                   polymer supramolecule with different structures for leather
            [1]   MOKTADIR M A, AHMADI H B, SULTANA R,  et al. Circular   multiperformance intensification[J]. Macromolecular Materials and
                 economy practices in the leather industry: A practical step towards   Engineering, 2020, 305(7): 2000195.
                 sustainable development[J]. Journal of Cleaner Production, 2020,   [19]  FENG X L, ZHANG X F, LI S Q, et al. Preparation of aminated fish
                 251: 119737.                                      scale  collagen and oxidized sodium  alginate hybrid hydrogel for
            [2]   JIA X J, ZHANG C X, SADAQAT A C, et al. A salt-free pickling   enhanced full-thickness wound  healing[J]. International  Journal of
                 chrome tanning technology: Pretreatment with the  collective   Biological Macromolecules, 2020, 164: 626-637.
                 polyoxyethylene diepoxy ether and urotropine[J]. Journal of Cleaner   [20]  DUAN X B (段徐宾),  YAN W F (闫文飞), LI X (李幸),  et al.
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