Page 208 - 《精细化工》2022年第5期
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·1062·                            精细化工   FINE CHEMICALS                                 第 39 卷













                                           图 16  ADDA 含量为 1.3%残酸的 SEM 图
                                      Fig. 16    SEM images of ADDA content of 1.3% spent acid

                 如图 16 所示,ADDA 含量为 1.3%的残酸有明                       increasing[J]. Special Oil  and Gas  Reservoirs (特种油气藏), 2018,
                                                                   25(1): 150-154.
            显的三维网状结构,表明 ADDA 分子可以通过疏水                          [7]   LI Y L (李亚林), JING X W (敬显武), LU H S (鲁红升). Research
                                                                   on clean diverting acid in carbonate gas reservoir[J]. Progress of Fine
            缔合作用形成三维网状结构,宏观上表现为表观黏                                 Petrochemical Industry (精细石油化工进展), 2015, 16(4): 9-11.
            度的增加     [23] ,以此封堵地层,实现转向效果。                      [8]   JIANG D S (蒋德生), LI X P (李晓平), JIANG K W (姜凯文), et al.
                                                                   Study on acid diversion capacity of heterogeneous reservoir in
                                                                   Gaomo area[J]. Petroleum and Natural Gas Chemical Industry (石油
            3   结论                                                 与天然气化工), 2021, 50(4): 92-95.
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                                                                   Experimental evaluation and process optimization of temporary
                (1)自转向剂的合成条件为:单体配比 n(AM)∶                          plugging and acid fracturing in fractured carbonate reservoir[J].
                                                                   Petroleum and Natural Gas Chemical Industry (石油与天然气化工),
            n(DMAPMA)∶n(DMAAC-18)∶n(ACMO) = 90∶                    2021, 50(3): 90-95.
            10∶1.8∶10,引发剂含量 0.5%,单体含量为 30%,                    [10]  PAN B F (潘宝风), CHEN Y H (陈颖袆), LIU X H (刘徐慧), et al.
                                                                   Effect of  temperature stabilizer on high  temperature rheology  of
            反应温度 55  ℃,反应时间 6 h,pH=7。红外光谱和                         self-rotating acid[J]. Drilling Fluid and Completion Fluid (钻井液与
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            1 HNMR 结果表明,合成的自转向剂与设计的分子结                         [11]  GAO X (高翔), XU Y N (许永楠), SUN S X (孙世轩), et al. Effect
                                                                      3+
            构一致。                                                   of Fe  on the properties of VES for self-rotating acid[J] Petroleum
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                (2)在 30 和 90  ℃下,ADDA 自转向酸都具有                      46(4): 67-71.
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            较好的转向效果,且 ADDA 酸液具有较好的抗盐性                              Research and application of turning acid process[J]. Application in
                                                                   Petrochemical Industry (石油化工应用), 2015, 34(2): 56-59.
            能。残酸的流变性能测试结果表明,ADDA 残酸具                           [13]  LIU C, HONG B, XU K. Synthesis and application of salt tolerance
            有较好的抗温性,为聚合物非交联自转向酸的应用                                 amphoterichydrophobic associative flocculants[J]. Polymer Bulletin,
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            提供了理论支持。                                           [14]  WANG H  R (王浩儒). Research  on viscoelastic acid steering
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                (3)配伍性实验结果表明,自转向剂与油田常                              油大学), 2015.
            用的酸化外加剂具有良好的配伍性。                                   [15]  LI B F (李宾飞), LI Z M (李兆敏), XU Y H (徐永辉), et al. Foam
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                (4)在酸岩反应过程中,由于 CaCl 2 的生成增                         Natural Gas Industry (天然气工业), 2006, 26(12): 130-132.
                                                               [16]  QUAN H P (全红平), JIANG S L (蒋思龙), MA Y (马英), et al. A
            强了 ADDA 聚合物分子间的疏水缔合作用,所以                               self-thickening polymer for pH responsive acidification[J].
            ADDA 酸液的表观黏度才会随着酸岩反应的进行持                               Petrochemical Industry (石油化工), 2020, 49(11): 1093-1099.
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            续增加,并且残酸的 SEM 图可以观察到由疏水缔合                              properties and thickening mechanism of a novel thickener based on
                                                                   hydrophobically associating water-soluble polymer during the acid
            作用形成的三维网状结构。本文为聚合物非交联自                                 rock reaction[J]. Journal of Petroleum Science and Engineering,
            转向酸的增稠机理提供了理论参考。                                       2020, 188: 106895.
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