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第 9 期 杨 柳,等: 透明光子晶体薄膜的力致变色调控及防伪应用 ·1819·
3 结论 [7] ZHANG G R (张国睿), NIU W B (牛文斌), WANG Y P (王云朋),
et al. Photoelectric double response sensor based on dodecyl
采用 SiO 2 胶体粒子构筑三维蛋白石光子晶体阵 glyceride itaconate[J]. Fine Chemicals ( 精细化工), 2020, 37(8):
1594-1600, 1644.
列,再将其嵌入 PDMS 弹性体内,成功制备了一种 [8] MA W, KOU Y S, ZHAO P, et al. Bioinspired structural color
具有力致变色性能的光子晶体薄膜。由于 SiO 2 与 patterns derived from 1D photonic crystals with high saturation and
brightness for double anti-counterfeiting decoration[J]. ACS Applied
PDMS 具有相似的折射率,光子晶体薄膜在正常状 Polymer Materials, 2020, 2(4): 1605-1613.
态下是无色透明的,但其仍具有明显的反射信号, [9] YE S Y, FU Q Q, GE J P. Invisible photonic prints shown by
deformation[J]. Advanced Functional Materials, 2014, 24(41): 6430-6438.
隐蔽性极强。施加拉力时,薄膜显现明亮的结构色, [10] YE S Y, GE J P. Soaking based invisible photonic print with a fast
随着拉伸应变增加至 60%,薄膜依次出现绿色、青 response and high resolution[J]. Journal of Materials Chemistry C,
2015, 3(31): 8097-8103.
蓝色和蓝色,最大反射波长可蓝移 115 nm,最大反 [11] JIA L Z, LI M M, JIANG L X, et al. Revealable photonic prints with
射峰反射率随拉伸应变的增加不断增大。撤销应力, oppositely responsive polymers for improved visual sensing[J]. Journal
of Materials Chemistry C, 2020, 8(27): 9286-9292.
薄膜颜色可逆变化直至消失。在经历 100 次拉伸循 [12] LI W Y, WANG Y, LI M, et al. Inkjet printing of patterned, multispectral,
环后,薄膜依旧保持稳定的光学性能。将光子晶体 and biocompatible photonic crystals[J]. Advanced materials, 2019,
31(36): 1901036.
薄膜进行图案化设计,通过施加拉力可使隐藏于其 [13] WANG W T, TANG B T, MA W, et al. Easy approach to assembling
中的图案从无色透明依次转变为绿色、青蓝色和蓝 a biomimetic color film with tunable structural colors[J]. Journal of
the Optical Society of America A, 2015, 32(6): 1109-1117.
色;撤销拉力后图案消失。该薄膜可直接用作防伪 [14] MENG Z P, WU S L, TANG B T, et al. Structurally colored polymer
标签或附着于柔性基材实现防伪功能,在此基础上 films with narrow stop band, high angle-dependence and good mechanical
robustness for trademark anti-counterfeiting[J]. Nanoscale, 2018, 10(30):
进一步降低薄膜厚度,可使其防伪隐蔽性更佳。 14755-14762.
[15] MALITSON I H. Interspecimen comparison of the refractive index
参考文献: of fused silica[J]. Journal of the Optical Society of America, 1965,
55(10): 1205-1209.
[1] NARUSE M, TATE N, OHTSU M. Optical security based on near-
field processes at the nanoscale[J]. Journal of Optics, 2012, 14(9): [16] RAMAN K, MURTHY T R S, HEGDE G M. Fabrication of
094002. refractive index tunable polydimethylsiloxane photonic crystal for
[2] YOON B, LEE J, PARK I S, et al. Recent functional material based biosensor application[J]. Physics Procedia, 2011, 19: 146-151.
approaches to prevent and detect counterfeiting[J]. Journal of Materials [17] WANG W T, FAN X Q, LI F H, et al. Magnetochromic photonic
Chemistry C, 2013, 1(13): 2388-2403. hydrogel for an alternating magnetic field-responsive color display[J].
[3] GE J P, YIN Y D. Responsive photonic crystals[J]. Angewandte Advanced Optical Materials, 2018, 6: 1701093.
Chemie, 2011, 50(7): 1492-1522. [18] CHAU K, MILLARE B, LIN A, et al. Dependence of the quality of
[4] HONG W, YUAN Z K, CHEN X D. Structural color materials for adhesion between poly(dimethylsiloxane) and glass surfaces on the
optical anticounterfeiting[J]. Small, 2020, 16(16): 1907626. composition of the oxidizing plasma[J]. Microfluidics and Nanofluidics,
[5] HOU J, LI M Z, SONG Y L. Patterned colloidal photonic crystals[J]. 2011, 10(4): 907-917.
Angewandte Chemie, 2018, 57(10): 2544-2553. [19] BONIFACIO L D, LOTSCH B V, PUZZO D P, et al. Stacking the
[6] LIAO J L, ZHU C, GAO B B, et al. Multiresponsive elastic colloidal nanochemistry deck: Structural and compositional diversity in one-
crystals for reversible structural color patterns[J]. Advanced Functional dimensional photonic crystals[J]. Advanced Materials, 2009, 21(16):
Materials, 2019, 29(39): 1902954. 1641-1646.
(上接第 1787 页) [28] DING L B ( 丁丽 兵 ). Study on synthesis and properties of
[25] KIEFER J, FRIES J, LEIPERTZ A. Experimental vibrational study imidazolium-type ionic liquid polymers[D]. Beijing: Beijing Institute
of imidazolium-based ionic liquids raman and infrared spectra of 1- of Technology (北京理工大学), 2015.
ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide and 1- [29] MOHAMMADKAZEMI F, KHADEMIBARANGENANI R, KOOSHA
ethyl-3-methylimidazolium[J]. Applied Spectroscopy, 2007, 61(12): M. The effect of oxidation time and concentration on physicochemical,
1306-1311. structural, and thermal properties of bacterial nano-cellulose[J]. Polymer
[26] GUO W H, YANG F, ZHAO Z G, et al. Cellulose-based ionic liquids Science Series A, 2019, 61(3): 265-273.
as an adsorbent for high selective recovery of gold[J]. Minerals [30] TROGER-MULLER S, BRANDT J, ANTONIETTI M, et al. Green
Engineering, 2018, 125: 271-278. imidazolium ionics-from truly sustainable reagents to highly functional
[27] ZHANG S L, CHEN H Y, ZHANG S L, et al. Polyethylenimine ionic liquids[J]. Chemistry, 2017, 23(49): 11810-11817.
grafted H 2O 2-oxidized cellulose membrane as a novel biosorbent for [31] DIAZ-LINAN M C, GARCIA-VALVERDE M T, LUCENA R, et al.
Cr( Ⅵ ) adsorption and detoxification from aqueous solution[J]. Paper-based sorptive phases for microextraction and sensing[J].
Cellulose, 2019, 26(5): 3437-3453. Analytical Methods, 2020, 12(24): 3074-3091.