Page 36 - 《精细化工》2023年第4期

g722g ㇫㏳ࡃጒ FINE CHEMICALS す 40 ࢤ

ݣิ⮱ڕధᔮ㏑㐡⟣ V-MOF 䨹⻨ၽ⩢↍㶕⣝ܧх ព᪐হ⩢ၽ䒙⼨䕌⢴෋ᑧ喑ϻ㔹჋⣝䊲倅ღ䛼
3
3
ᐯ⮱Ҁ⼜ღ䛼喑ౕ́倅㘪䛼ჳᏓ喍17.4 mW·h/cm 喎 喍457.5 mA·h/cm 喎㏑㐡⩢↍⮱ݣิȡ㐩̷᝭䔝喑
3
⮱हᬣکڤ倅ߌ⢴ჳᏓ喍1.46 mW·h/cm 喎ȡͧγ䔈 ⷠ㏠ㆠノ㏑㐡ज҉ͧᩜᦾᝃ俕᳣喑᣽倅ധҀᱽ᫆⮱
̭ₒ᣽倅㏑㐡⩢Ხו㘪ᕔ㘪喑䛴⩕࣌ၽᣧᱯឭᱜज ⩢ᄩ⢴喠ι⅔ࡃ䩝ȠVO x ぶ≨ᕔᱽ᫆ज̻ⷠ㏠ㆠノ
ᰶ᩵᣽倅ڣ℁⩢ღȡHE ぶ [28] В ZIF-67 ͧ὎Წ喑ᄦ ㏑㐡ฺवᒏ᜽ₐᲮᱽ᫆喑᣽倅ڣ㘪䛼ႅוহ⩢㢤ჳ
ڣ䔈㵹⅛ⷠ喍NC喎ᣧᱯ喑ݣิ⅛ⷠᣧᱯⷠ㏠ㆠ㏑㐡 Ꮣȡₑใ喑䕇䓴ᩦ䔈≨ᕔᱽ᫆⮱᜽ಸ᫦ᐼࣷⷠ㏠ㆠ
喍CNTF@NC喎喑ںᄳρ⅔ࡃι䦿㏠ㆠ❴Ⅱ☚⩌䪬ݝ ノ㏑㐡⮱䶱ั⤳ጒ㞧喑जᒏ᜽ᓛ㻯ᒏ䆹㻱᪡⮱⩢Ხ
CNTF@NC ̷喑ᒏ᜽ᵥภ㐀Ჱ喍CNTF@NC@V 2 O 5 喎喑 ᱽ᫆喑᣽倅≨ᕔ➖䉕䉌䒪䛼喑ϻ㔹๔፲᣽倅㏑㐡䨹
ຯఫ 5g ᝭⹧喑В NC ͧᵥᅯ喑ρ⅔ࡃι䦿ͧภᅯȡ ⻨ၽ⩢↍⮱ღ䛼ȡ
ڣ⠙➦⮱ह䒡㐀Ჱ喑Ҭ≨ᕔ➖䉕䉌䒪䛼෋ߍȠ⻨ၽ

ఫ 5 CNT ധ㏑㐡⟣䨹⻨ၽ⩢↍喟ധλ MnO 2 @CNT ㏑㐡ₐᲮহ Zn ㏬䉌Ხ⮱ Zn-MnO 2 ㏑㐡⩢↍⮱ݣิጒ㞧⹧ᘼఫ [24]
2
喍a喎喠㏞㏬⮱ݣ҉হᄮ㷲⹧ᘼఫ [25] 喍b喎喠ᄳ 8 ͗㏞㏬⩢↍͟㖁ͧ 100 ͗ LED ▜হ 100 cm 䲏࠲Წӈ⩢ [25] 喍c~d喎喠
̺हⅡ☚ᬣ䬡⮱ V-MOF ⮱ SEM ఫ [27] 喍e~f喎喠CNTF@NC@V 2 O 5 ᵥภ㐀Ჱ⮱ᒏ᜽ᱧ⤳⹧ᘼఫ [28] 喍g喎
Fig. 5 CNT-based fibrous zinc ion battery: Schematic diagram of preparation process of Zn-MnO 2 cable-like battery based
on MnO 2 @CNT fiber cathode and Zn wire anode [24] (a); Schematic diagram of fabrication and encapsulation of yarn [25]
2
(b); Eight segmented yarn batteries were connected in series to 100 LED lights and 100 cm electroluminescent
panel [25] (c~d); SEM images of V-MOF with different hydrothermal times [27] (e~f); Schematic diagram of formation
mechanism of CNTF@NC@V 2 O 5 core-shell structure [28] (g)

3 Ꭰ䲏㏴➖⟣䨹⻨ၽ⩢↍喍̶ᬻ⇨ಸ喎 ϧጒᮧ㘪Ƞ⣝Аٶ⩢ၽ႓হڣЃ㘪⎽Ⱕڠ䃫ิぶ䶳
ഌ [29-30] ȡ
㏧㏴ധ䨹⻨ၽ⩢↍䮑γ㏑㐡⟣㐀Ჱ喑䔅ज䛴⩕ 3.1 ⷠጰധᎠ䲏䨹⻨ၽ⩢↍
㏴➖ͧധҀᲱまㆨэ㐌݇ᕔ⩢↍⮱ᅯᅯളऍᎠ䲏㐀 ᬖ᱌ⵁ⾣ϧঅⰡᣒ䛴⩕䛾ᆋ䨹チ҉ͧ䨹⩢↍⮱
Ჱ喍ࣵ⼝̶ͧᬻ⇨㐀Ჱ喎喑㏱᜽࠲᠙㏴➖⩢↍ₐ䉌 䉌Ხ喑ѳᴁᕔጛҬᓄ⩢Ხ㏼็⁎ᑜᰟऻⰡᣒ᫚㷯喑
Ხহ⩢↍䯁㛉ȡ̻㏑㐡⟣䨹⻨ၽ⩢↍Ⱕ℁喑̶ᬻ⇨ ͒䛺ݣ㏓ڣᏁ⩕౧ᮜȡͧγᓄݝᴁᕔ⩢Ხ喑ⵁ⾣ϧ
ಸ䨹⻨ၽ⩢↍⮱ᕨ㘪䛼ႅוᰡ倅喑ᰡᭀ㏱㷲᜽ੳ অ䕇䓴В㏧㏴㏴➖ͧധᏂ喑䛴⩕⊯㺳Ƞ⩢↶⼜ȠⅡ
͇ࡃϔ৮և᜽䒜࠲⩢↍䓽⩕λЬ⩌႓Ƞࡨ⫄Ԋ֒Ƞ ☚হ⅁Ⱕ↶⼜ぶ᫦∂ᄳ≨ᕔ➖䉕䉌䒪ౕ㏧㏴䲏᫆⮱