Page 39 - 《精细化工》2023年第4期

す 4 ᱌ ႆ↌͉喑ぶ: ㏧㏴ധᴁᕔ䨹⻨ၽ⩢↍⮱ⵁ⾣䔈ᆂ g725g

℁ღ䛼ϲ䭺ѻγ 14%ȡࢠҬౕ 30 A/g ⮱倅⩢≮ჳᏓ ᩲ䄒⩢Ხ⩢㢤䒙⼨䕌⢴ᬻ᭫᣽ࡴ喑჋⣝γ⩢ࡃ႓ڲ䭨
̸喑ϺजԊᰶ 248 mA·h/g ⮱ᩫ⩢℁ღ䛼ȡ㶕ᬻ喑VOG ⮱䭺ѻ喑㑀㼐γ㏠ㆠᱽ᫆⮱Ҁ⼜᩵Ꮑ喑Ҭฺव⩢Ხ
⩢Ხڤᰶ⽠Ⴧ⮱ᮣҀ㐀ᲱȡⰥ℁λ̭㐡㏠ㆠ㏬喑෋ ⽠Ⴧᓗ⣜ٲᩫ⩢ȡ఍ₑ喑ⴠ෕☜㏠ㆠ❴⮱ߍڒ喑Ҭᓄ
ߍ㏠ㆠᱽ᫆⮱䪬Ꮣज䭺ѻ⩢ࡃ႓ڲ䭨喑䊲䪬⮱㏠ㆠ 䨹⻨ၽ⮱ព᪐㈨᪝෋ߍ̭͗᪝䛼㏔ȡ䔆ᑿ఍λⴠ෕
᷿̻ⴠ෕☜㏠ㆠ❴ฺव喑ᒏ᜽̶㐡⾬᣿㑾㐉ȡDUAN ☜㏠ㆠ❴๖♣⮱ι㐡喍2D喎㐀Ჱহх䊷⮱⩢ၽᄩ⩢
ぶ [42] 䕇䓴Ⅱ☚∂व᜽ H 2 V 3 O 8 ㏠ㆠ᷿/ⴠ෕☜ฺवᱽ ᕔ喑ज䕇䓴⾧䬡㏓᲌᩵Ꮑহ⩹䲏Ⱕο҉⩕喑ᰶ᩵ౝ㑀
᫆҉ͧ䨹⻨ၽ⩢↍⮱ₐᲮ喑ݣิ≮⼸⹧ᘼఫຯఫ 7e 㼐㏠ㆠᱽ᫆⮱ള⼜喑ᩦ઱⩢ၽэ䓀䕇䖀喑ѳⴠ෕☜ᱽ
᝭⹧ȡ⩞λ H 2 V 3 O 8 ㏠ㆠ᷿䪬Ꮣज䓫 600 nm喍ఫ 7f喎喑 ᫆⮱⩢↍ღ䛼䉎⡛䒰ᄾ喑Ϻ䯫В䓫ݝ⤳䃧ღ䛼ⅡᎠȡ

ఫ 7 ⴠ෕☜ധ䨹⻨ၽ⩢↍喟ZnMn 2 O 4 /NG व᜽⹧ᘼఫ [38] 喍a喎喠H 2 V 3 O 8 ㏠ㆠ㏬/ⴠ෕☜ฺवᱽ᫆㐀Ჱ⹧ᘼఫ [40] 喍b喎喠̺
ह⩢≮ჳᏓ̸⮱ᓗ⣜ᄬপহᏀϾ᩵⢴ [40] 喍c~d喎喠H 2 V 3 O 8 ㏠ㆠ᷿/ⴠ෕☜ฺवᱽ᫆व᜽≮⼸⹧ᘼఫ [42] 喍e喎喠H 2 V 3 O 8
㏠ㆠ᷿ SEM ఫ [42] 喍f喎
Fig. 7 Graphene-based zinc ion batteries: Schematic illustration of synthesis of ZnMn 2 O 4 /NG [38] (a); Schematic structure of
H 2 V 3 O 8 nanowire/graphene composite [40] (b); Cycle life and coulomb efficiency at different current densities [40] (c~d);
Flow charts of H 2 V 3 O 8 nanorods/graphene composite [42] (e); SEM image of H 2 V 3 O 8 nanorods [42] (f)

4 㐀᲌䄚̻ᆂ᱈ ็ӊ䊃λѻ᏶⮱᜽᱙х߬㔹䲋⻾ឭх߬ȡ఍ₑ喑
䕇䓴ज⾬ᝡ㏧㏴৮⮱䛺◦ⵁࣾ喑ᄨⅯϔ͇ϻ㏧㏴๔
ᩦ䲖ᐭᩫВᲒ喑㏧㏴͇᭜͚పܧऐ⮱䛺㺮ϔ͇ పݝ㏧㏴ᑧప⮱䒙अ喑჋⣝ᑜ䖀䊲䒓喑᭜͚ప㏧㏴
͸̭ȡ2021 Ꭱ喑͚పᄦ䔆ఈ๔э㐌ጯ౧喍㒻పȠ͉ ͇⮱䛺◦⾮ⵡȡ
ⰌȠ⁔Ⰼহᬒ᱙喎⮱㏧㏴৮᰺㷲ܧऐव䃎 1724.9 Ϭ すఈ⁎ጒ͇䲖পᰡ็ౝ䉸εϔ৮ԎᖜࡃȠߌ㘪
㒻ٰ喑㏓ࢍᄦڕ⤰ܧऐ℁䛺⮱ 55%ȡ♣㔹喑͚పϺ ࡃ⮱䰭Ⅿ喑㔹ᐭࣾߌ㘪ٰУ⮱ӈ㘪ࢂٰ᜽ͧᮧ㘪㏧
᭜㏧㏴๔ప喑㔹䲋㏧㏴ᑧప⮱⣝⟣喑㏧㏴৮ܧऐᰡ ㏴৮⾮ⵡ⮱ധⴠȡᄨⅯ䨯䉱⎽ᰬА⮱倅וิȠѻ᜽