Page 37 - 《精细化工》2023年第4期

す 4 ᱌ ႆ↌͉喑ぶ: ㏧㏴ധᴁᕔ䨹⻨ၽ⩢↍⮱ⵁ⾣䔈ᆂ g723g

㶕䲏ᒏ᜽⩢Ხᱽ᫆ȡ䩝ധ⅔ࡃ➖᭜Ꭰ䲏㐀Ჱ䨹⻨ၽ Вι⅔ࡃ䩝ͧҸ喑ڤᰶ Į-Ƞȕ-ȠȜ-Ƞį-MnO 2 ぶ㐀Ჱ喑
⩢↍Ҭ⩕ᰭ็⮱≨ᕔᱽ᫆喑ڤᰶѻ᜽᱙Ƞ⣜ධࣸສȠ Ხͧ͝ჹȡWU ぶ [32] В ZIF-67 ͧ㜗➧➟὎Წ䛴⩕͑
ѻ⃿⮱х◦ [31] ȡₑใ喑䩝⅔ࡃ➖ᰶ็Фᔮ喑̺हФ ₒ∂व᜽䊲㪱ι⅔ࡃ䩝㏠ㆠ❴喑ں㏱㷲᜽͚⾧⿸Ҁ
ᔮ⮱ᮣҀ㐀Ჱ̺ह喑ह⻺➖䉕࣌ၽᢿጰΌ̺Ⱕह喑 ᓛ㻯㐀Ჱ⮱᫝ಸₐᲮᱽ᫆喑ຯఫ 6a ᝭⹧ȡ

c ͚喑1Ƞ3Ƞ5 А㶕Ҭ⩕叼㐀ݯ喠2Ƞ4Ƞ6 А㶕Ⅱ☚⩌䪬∂喠3Ƞ4 А㶕ᑜᰟᬣ喠5Ƞ6 А㶕ᑜᰟऻ
[33]
[32]
ఫ 6 ⷠጰധ䨹⻨ၽ⩢↍喟ⷠጰ̷Ⅱ☚व᜽ MnO 2 ㏠ㆠ❴⮱⹧ᘼఫ 喍a喎喠 C-MnO 2 @CC ݣิ⹧ᘼఫ 喍b喎喠 V 6 O 13 @CC
⮱ٶ႓⚔❴ [34] 喍c喎喠ౕ̺ह⮱ᑜᰟ㻿Ꮣ̸ͧ LED ▜ӈ⩢ [32] 喍d喎喠ⷠጰ̷࣌Ѻ⩌䪬 V 2 O 5 ㏠ㆠ㏬⹧ᘼఫ [35] 喍e喎
Fig. 6 Carbon cloth-based zinc ion batteries: Schematic illustration of synthesis of MnO 2 nanosheet on carbon cloth [32] (a);
Schematic diagram of C-MnO 2 @CC preparation [33] (b); Optical pictures of V 6 O 13 @CC [34] (c); Powering LED lights at
different bending angles [32] (d); Schematic diagram of in situ growth of V 2 O 5 nanowires on carbon cloth [35] (e)

͚⾧㐀Ჱ⮱ι⅔ࡃ䩝ڤᰶ倅℁㶕䲏⼜喑ᰶݖλ ᐯ⮱▢≨ᕔȡ᫝ಸ⮱㏧㏴ധ䨹⻨ၽ⩢↍̺ϲ㺮Ⅿ倅
⩢㼐䉕⮱⍄䔼喑ើݣҀ⼜㛕㗭喑㔹ⷠጰധᏂڤᰶ̭ 㘪䛼ჳᏓȠ䪬ᓗ⣜ᄬপ喑㔹́䰭㺮␎䋠ᬍ⃿ᬍ↎ᴀȠ
Ⴧ⮱ᄩ⩢ᕔ喑जᰶ᩵Ӱ䔈⩢ၽэ䔿ȡВι⅔ࡃ䩝ⷠ Фᵩѻ᏶হ䉱⎽जᠮ㐚ᕔȡLI ぶ [33] ऄݝڤᰶᑧ叼䭱
ጰฺव⮱⩢Ხ喍MnO 2 /CC喎ౕ⩢≮ჳᏓͧ 1 A/g ̸ ᕔ็ጡ㘧⮱ड़ࣾ喑В㖇็ጡ㘧ᅯ҉ͧĄ䄞ᄩݯąӰ
ᓗ⣜ 300 ⁎ऻ喑᭫⹧ܧ 263.9 mA·h/g ⮱倅ज䔳℁ღ 䔈 į-MnO 2 ౕⷠጰ̷⮱⩌䪬喑Ą㟞⨐⟣ą⮱㏠ㆠ㐀Ჱ
䛼喑䔉䔉䊲䓴ੳ⩕ι⅔ࡃ䩝⩢Ხȡ㏱㷲⮱ᴁᕔ䨹⻨ Ⴙڕ࠲㸦ౕⷠ㏑㐡㶕䲏喑ຯఫ 6b ᝭⹧喑෋ᑧγι⅔
ၽ⩢↍ౕ⩢≮ჳᏓͧ 0.1 A/g ̸ᓗ⣜ 30 ⁎ऻ喑⩢ࢸ ࡃ䩝⮱㐀Ჱ⽠Ⴧᕔȡݣิ⮱ᴁᕔ⩢Ხ喍C-MnO 2 @CC喎
2
2
ᩫ⩢Ꭰझ⽠Ⴧౕ 1.53 V喑ᩫ⩢℁ღ䛼ͧ 91.7 mA·h/gȡ ౕ⩢≮ჳᏓͧ1.0 A/cm ᬣ喑݊໸℁ღ䛼ͧ1.3 mA·h/cm 喑
2
㏱㷲ݣิ⮱ᴁᕔ䨹⻨ၽ⩢↍㘪์ౕ̺ह⮱ᑜᰟ⟣ᔮ 10000 ⁎ٲᩫ⩢ᓗ⣜ऻ喑℁ღ䛼㶝ۼͧ 0.25 mA·h/cm ȡ
̸ͧ LED ӈ⩢喍ఫ 6d喎喑䔆㶕ᬻ䄒㏴➖⩢↍ڤᰶх В C-MnO 2 @CC ͧₐᲮ喑Zn@ⷠጰͧ䉌Ხ喑㖇͆☜䚝