Page 103 - 《精细化工》2023年第9期

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第 9 期 邵 琦，等: 可逆型荧光探针的合成及对 Cu 和 Pd 的双重检测 ·1951·
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现了对 Cu 和 Pd 的双重检测，在 V(DMSO)∶ Contact Dermatitis, 2006, 55(6): 338-341.
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中对 Cu 和 Pd 具有高灵敏度、特异性的荧光猝灭 [16] BAKER M S, PHILLIPS S T. A two-component small molecule
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探针 PHM 与 Cu 以物质的量比为 1∶1 形成了配合 Journal of American Chemical Society, 2011, 133(14): 5170-5173.
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特性。通过 Job's 曲线、DFT 计算以及 HNMR 核磁 element determination of Pt, Pd and Ir traces in environmental
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滴定实验验证了 PHM 与 Cu 和 Pd 可能的络合机 samples by ICP-MS after pre-concentration[J]. Talanta, 2012, 99:
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制。PHM 探针已成功地应用于环境样品中 Cu 和 [19] PIROGOV A V, HAVEL J. Determination of platinum, palladium,
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