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·1312·                            精细化工   FINE CHEMICALS                                  第 35 卷

            97.77%、95.56%、77.78%,而 C 12 -PSi x -C 12 对金黄       且抗菌性能随着连接基长度的增加而下降。3 种表
            色葡萄球菌的抑菌率分别为 99.64%、99.64%、                        面活性剂对细菌抑菌效果好于对霉菌的抑菌效果,
            92.28%。说明 C 12 -PSi x -C 12 在对细菌的抗菌性中,对            其对细菌的最大抑菌率均可达到 100%,而对霉菌的
            革兰氏阳性菌(金黄色葡萄球菌)的抵抗能力优于                             最大抑菌率分别为 100%、78.95%、73.68%。
            革兰氏阴性菌(大肠杆菌)。这是由于两种细菌的细
                                                               参考文献:
            胞结构不同导致的,革兰氏阳性菌中有大量的糖醛
                                                               [1]   Cai Zhenyun (蔡振云), Yin Yan  (银燕). Preparation  of defoamer
            酸、氨基酸、磷壁酸等带有负电荷的物质,使得带                                 from silicone singly  modified with polyether[J]. Textile Auxiliaries
                                                                   (印染助剂), 2006, 23(4): 17-19.
            正电荷的 C 12 -PSi x -C 12 更易吸附在其表面。而革兰氏               [2]   Shui Lingling (水玲玲) , Zheng Liqiang (郑利强), Zhao Jianxi (赵剑
            阴性菌只有细胞膜中含有脂多糖使其带上较少的负                                 曦),  et al. Study  on the interfacial activity of Gemini surfactant
                                                                   system[J]. Fine Chemicals (精细化工), 2001, 18(2): 67-69.
                        +
            电荷,吸引 N 的能力较弱。因此,C 12 -PSi x -C 12 对革              [3]   Wang Jun (王军), Luan Lihui (栾立辉), Yang Xuzhao (杨许召), et
                                                                   al. Synthesis and surface activity of cationic Gemini surfactants[J].
            兰氏阳性菌的抗菌性优于对革兰氏阴性菌的抗菌                                  Fine Chemicals (精细化工), 2009,26(1): 14-17.
            性。这也与 Fatma       [21] 和 Negm  [22] 的报道结果一致。       [4]   Natalia Ivanova, Victor Starov, Ramon Rubio, et al. Critical wetting
                                                                   concentrations of trisiloxane surfactants[J]. Colloids and Surfaces A:
            但是 3 种表面活性剂对细菌(大肠杆菌,金黄色葡                               Physicochem and Engeering Aspects, 2010, 354: 143-148.
                                                               [5]  Huang Liangxian  (黄良仙), An Qiufeng (安秋凤). Synthesis
            萄球菌)的最大抑菌率均可以达到 100% ,而                                characterization and application  performance study of new type
                                                                   aminopolysiloxane softener[J]. Textile Auxiliaries (印染助剂), 2006,
            C 12 -PSi x -C 12 对霉菌的最大抑菌率分别为 100%,                   23(9): 22-24.
            78.95%,73.68%。说明 C 12 -PSi x -C 12 对细菌的抗菌性         [6]   Wang Guoyong, Zhang Dianlong, Du Zhiping,  et al. Spontaneous
                                                                   vesicle formation from trisiloxane-tailed gemini surfactant[J]. Journal
            优于霉菌。这是由于,一方面,霉菌表面的负电荷                                 of Molecular Liquids, 2014, 20: 1247-1250.
                                                               [7]   Han Fu (韩富), Zhang Gaoyong (张高勇). Synthesis and interfacial
                                             +
            相对较少,因此,吸附表面活性剂 N 的能力也相对                               properties of glucosamide-based  trisiloxane  surfactants[J]. Acta
                                                                   Chmica Sinica (化学学报), 2004, 62 (7): 733-737.
            较弱;另一方面,霉菌细胞壁不同于细菌的细胞壁,                            [8]   Hao Chuanming, Cui Yuezhi, Yang Pengfei, et al. Effect of siloxane
            霉菌的细胞壁是由壳多糖和 β-葡聚糖组成,其使表                               spacer length on organosilicon bi-quaternary ammonium amphiphiles
                                                                   [J]. Colloids and Surfaces B: Biointerfaces, 2015, 128: 528-536.
                                                               [9]  Bao Yan (鲍艳), Guo Jiajia (郭佳佳), Wang Xian (王宪). Synthesis
            面活性剂的疏水吸附能力更弱。因此,C 12 -PSi x -C 12
                                                                   and properties of ammonium organic  silicon Gemini surfactant[J].
            对霉菌的抗菌性低于对细菌的抗菌性。                                      Fine Chemicals (精细化工), 2016, 33(6): 644-647.
                                                               [10]  Bao  Yan, Guo Jiajia, Ma Jianzhong,  et al. Cationic silicon-based
                                                                   Gemini surfactants: effect of hydrophobic chains on surface activity,
            3    结论                                                physic-chemical properties and aggregation behaviors[J]. Journal of
                                                                   Industrial & Engineering Chemistry, 2017, 53: 51-61.
                                                               [11] Xu Yifei (徐怡斐). Experimental and theoretical study on the surface
                 (1)以聚乙二醇二缩水甘油醚和羟基封端聚二                             tensions of carbonated aqueous solution of aikanol amines[D]. North
            甲基硅氧烷为主要原料,通过开环反应和季铵化反                                 China Electric Power University(Baoding) (华北电力大学保定校
                                                                   区), 2012.
            应制备了不同连接基长度的 3 种季铵盐有机硅双子                           [12] Mao Peikun (毛培坤). Industrial analysis of surfactant products[M].
                                                                   Beijing: Chemical Industry Press(化学工业出版社), 2002: 430-433.
                                               1
            表面活性剂 C 12 -PSi x -C 12 ,并用 FTIR、 HNMR 对产          [13]  Hu Xiaoxia ( 胡晓 侠 ), He Jiangping  ( 贺江 平 ). Synthesis  of
                                                                   anti-microbical agent with silicon quaternary ammonium salt[J].
            物结构进行了确证。                                              Dyeing and Finishing (印染), 2014, 40(8): 13-17.
                 (2)C 12 -PSi x -C 12 水溶液的表面张力均随质量             [14]  Li Mingchun (李明春), Zhou Shengquan (周盛全), Xin Meihua (辛
                                                                   梅华), et al. Synthesis and antimicrobial activity of N-long chitosan
            浓度的增大而减小,且随着 C 12 -PSi x -C 12 中连接基硅                   quaternary ammonium salt[J]. Functional Materials (功能材料).
                                                                   2012, 17(43): 2338-2342.
            氧链长度的减小表面活性逐渐增强,其 γ CMC 依次为                        [15] Lin Qiuyun(林秋云), Du Guangwen(杜光文). Experimental study on
                                                                   antimicrobial effect of nano antibacterial disk[J]. Chinese Journal of
            29.74、31.17、44.95 mN/m。                                Health Laboratory Technology(中国卫生检验杂志),2005,15(2):
                 (3)3 种季铵盐有机硅双子表面活性剂均具有                            211-212.
                                                               [16]  Han Shiyan (韩世岩), Li Shujun (李淑君), Zhao Yanyan (赵颜颜),
            良好的乳化稳定性。其中,C 12 -PSi 40 -C 12 的乳化稳定                   et al. Effect of spacer chain character on surface activities of rosin-
                                                                   based quaternary ammonium Gemini surfactants[J]. Chemistry and
            性最好,其对液体石蜡、煤油、油酸的乳化稳定时                                 Industry of Forest Products (林产化学与工业), 2012, 32(4): 39-42.
            间分别为 260.5、732.3、1537.0 s,3 种季铵盐有机硅                [17]  Zana R, Benrraou M, Rueff R. Effect of the spacer chain length on
                                                                   the critical  micelle concentration and  micelle ionization degree[J].
            双子表面活性剂对 3 种油的乳化稳定性不同,其对                               Langmuir, 1991, 7(6): 1072-1075.
                                                               [18]  Ma Xiaodan (马小单), Li Huajing (李华静), Li Yuangang (李远刚),
            油酸的乳化稳定性最好,稳定时间都在 1200 s 以上。                           et al. Synthesis and properties of Gemini surfactants containing ester
                                                                   coupling groups[J]. Journal of Xi'an University of Science  and
                 (4)3 种表面活性剂均具有良好的润湿性,其                            Technology (西安科技大学学报), 2012, 32(5): 627-631.
            水溶液对 3 种基材的接触角均低于纯水,且 3 种表                         [19]  Zhang  Yue, Zhang Gaoyong, Han Fu. The spreading and
                                                                   superspeading behavior of new glucosamide-basedtrisiloxane
            面活性剂对 3 种基材的接触角均随连接基长度的增                               surfactants on hydrophobic foliage[J]. Colloids and Surfaces A:
                                                                   Physicochem and Engeering Aspects, 2006, 276: 100-106.
            大而增大,其水溶液在玻璃表面的接触角分别为                              [20]  Yang Jisheng (杨继生). Principle and application  of  surfactant[M].
                                                                   Nanjing:Southeast University Press(东南大学出版社), 2012: 52-54.
            48.3、59.9、65.6;在 PVC 表面的接触角分别为                  [21]  Fatma N, Panda M, Beg M. Ester-bonded cationic Gemini
            63.4°、73.1、76.8;在铝板表面的接触角分别为                         surfactants: Assessment of their cytotoxicity and antimicrobial
                                                                   activity[J]. Journal of Molecular Liquids, 2016, 222: 390-394.
            75.8、83.1、83.2。                                 [22]  Negm N A,  Tawfik S M.  Characterization, surface properties and
                                                                   biological activity of some synthesized anionic surfactants[J]. Journal
                 (5)3 种表面活性剂均表现出一定的抗菌性,                            of Industrial and Engineering Chemistry, 2014, 20(6): 4463-4472.
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