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第 35 卷第 9 期 精 细 化 工 Vol.35, No.9
201 8 年 9 月 FINE CHEMICALS Sept. 2018

表面活性剂
脂肪酸三乙醇胺单酯琥珀酸酯磺酸盐的

制备及表面活性

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郭灼能 ，强西怀 ，陈梦思 ，方银军 ，闫 哲
（1. 陕西科技大学 轻工科学与工程学院，陕西 西安 710021；2. 浙江赞宇科技股份有限公司，浙江 杭
州 310009；3. 浙江传化股份有限公司，浙江 杭州 311215）
摘要：以三乙醇胺、长链脂肪酸为原料，制得脂肪酸三乙醇胺单酯（FTME），再经磺化反应合成了 4 种脂肪酸
三乙醇胺单酯琥珀酸酯磺酸盐（FTMS）两性表面活性剂，以月桂酸、棕榈酸、硬脂酸、油酸为脂肪酸合成的
FTMS 分别命名为 FTMS-1、FTMS-2、FTMS-3、FTMS-4。分别用碱性亚甲基蓝法和酸性溴酚蓝法验证了产物
的离子性，并考察了 FTMS 结构中的烷基链长度及其不饱和度对表面张力、Krafft 点、样品液粒径及粒径分布、
乳化能力的影响。结果表明：产物显示出两性离子的特征，随着脂肪链碳数增加，其 Krafft 点升高，平均粒径
逐渐增大，但脂肪链中的不饱和双键有助于 Krafft 点的降低和粒径的减小。FTMS-1 和 FTMS-4 具有优异的表面
活性。其中，FTMS-1 的临界胶束质量浓度（CMC）为 52.97 mg/L，表面张力 γ CMC 为 36.1 mN/m，其乳化能力
与脂肪醇聚氧乙烯醚(AEO-9)相当且优于十二烷基磺酸钠。
关键词：脂肪酸；三乙醇胺；脂肪酸三乙醇胺单酯；琥珀酸酯磺酸盐；两性表面活性剂
中图分类号：TQ423.3 文献标识码：A 文章编号：1003-5214 (2018) 09-1518-06

Preparation and Surface Activity of Fatty Acid Triethanolamine
Monoester Sulfosuccinate

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GUO Zhuo-neng , QIANG Xi-huai , CHEN Meng-si , FANG Yin-jun , YAN Zhe
（1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an
710021, Shaanxi, China; 2. Zhejiang Zanyu Technology Co., Ltd., Hangzhou 310009, Zhejiang, China; 3. Transfar Shares
Co., Ltd., Hangzhou 311215, Zhejiang, China）
Abstract: Fatty acid triethanolamine monoester (FTME) was synthesized from fatty acid and triethanolamine.
Subsequently, four kinds of fatty acid triethanolamine monoester sulfosuccinate (FTMS) surfactants were
obtained by esterification of FTME with maleic anhydride and then sulfonation with sodium sulfite,
wherein, the FTMS products synthesized by laurate, palmitate, stearic acid and oleic acid were named as
FTMS-1, FTMS-2, FTMS-3 and FTMS-4, respectively. The ionicity of the products were verified by
alkaline methylene blue and acid bromophenol blue. The effects of alkyl chain length and unsaturation of
products on the surface tension, Krafft point, particle size, particle size distribution and emulsifying ability
were investigated. The results showed that the amphoteric products were successfully obtained. Krafft point
and average particle size increased with the increase of alkyl chain length, however, the unsaturation in
alkyl chain was conducive to the decrease of Krafft point and average particle size. Especially, FTMS-1 and
FTMS-4 exhibited excellent surfactivity. The critical micelle concentration (CMC) of FTMS-1 was
52.97 mg/L, and the surface tension at CMC (γ CMC) reached 36.1 mN/m. The emulsifying ability of
FTMS-1 was equivalent to that of AEO-9 and superior to that of sodium dodecyl sulfate.
Key words: fatty acid; triethanolamine; fatty acid triethanolamine monoester; sulfosuccinate; amphoteric
surfactant
Foundation items: National Key R & D Program of China (2017YFB0308500); Zanyu Science Foundation

收稿日期：2017-09-02; 定用日期：2017-11-30; DOI: 10.13550/j.jxhg.20170478
基金项目：国家重点研发计划项目（2017YFB0308500）；浙江赞宇科技基金项目；陕西科技大学创新科研团队（TD12-04）；陕西科技
大学研究生创新基金
作者简介：郭灼能（1991—），男，硕士生。联系人：强西怀（1963—），男，教授，电话：029-86168675，E-mail：qiangxihuai@163.com。