Page 142 - 201901
P. 142

·128·                             精细化工   FINE CHEMICALS                                  第 36 卷

                                                               [4]   Winger R J, König J, House D A.  Technological issues associated
                                                                   with iodine fortification of foods[J]. Trends  in  Food Science
                                                                   &Technology, 2008, 19(2): 94-101.
                                                               [5]   Mazumdar N, Ahmad S I, Ganie S A,  et al. Iodine complexes of
                                                                   acid-functionalized poly (vinyl alcohol) hydrogels:  synthesis,
                                                                   characterization and release studies[J]. Journal of Polymer Materials,
                                                                   2016, 33(1): 41-52.
                                                               [6]   Yin Z J, Xu S Q, Zhan T G, et al. Ultrahigh volatile iodine uptake by
                                                                   hollow microspheres formed from  a heteropore covalent organic
                                                                   framework[J]. Chemical Communications, 2017, 53(53): 7266-7269.
                                                               [7]   Zimmermann M B, Wegmueller R, Zeder C, et al. Triple fortification
                                                                   of salt with microcapsules of iodine, iron, and vitamin A[J]. The
                                                                   American Journal of Clinical Nutrition, 2004, 80(5): 1283-1290.
                                                               [8]   Ørning P, Hoem  K S, Coron A E,  et al. Alginate microsphere
                                                                   compositions dictate different mechanisms of complement activation
                                                                   with consequences for cytokine release and leukocyte activation[J].
                                                                   Journal of Controlled Release, 2016, 229: 58-69.
                                                               [9]   Martín M J, Calpena A C, Fernández F,  et al. Development of
                                                                   alginate microspheres as nystatin carriers for  oral mucosa drug
                                                                   delivery[J]. Carbohydrate Polymers, 2015, 117: 140-149.
                                                               [10]  Hossain K M Z, Patel U, Ahmed I. Development of microspheres for
                                                                   biomedical applications: a review[J]. Progress in Biomaterials, 2015,
                                                                   4(1): 1-19.
                                                               [11]  Martín M J, Lara-Villoslada F, Ruiz M A, et al. Microencapsulation
                                                                   of bacteria: a review of different technologies and their impact on the
                                                                   probiotic effects[J]. Innovative Food Science &  Emerging
                                                                   Technologies, 2015, 27: 15-25.
                                                               [12]  Zhou Mingson (周明松), Liu Qingfang (刘庆芳), Wang Suya (王素雅),
                                                                   et al. Preparation of avermectin microcapsules by electrostatic self-
                                                                   assembly method[J]. Fine Chemicals (精细化工), 2017, 34(5): 519-524.
                                                               [13]  Zou Q, Zhao  J, Liu X,  et al. Microencapsulation  of
                                                                   bifidobacteriumbifidum F-35 in reinforced alginate microspheres
                        图 6  CISAMC 制备示意图                          prepared by emulsification/internal gelation[J]. International Journal
                                                                   of Food Science & Technology, 2011, 46(8): 1672-1678.
            Fig.6  Schematic illustration  of process for  preparation of   [14]  Lupo B, Maestro A, Porras M,  et al. Preparation of alginate
                   CISAMC                                          microspheres by emulsification/internal gelation to encapsulate cocoa
                                                                   polyphenols[J]. Food Hydrocolloids, 2014, 38: 56-65.
            3    结论                                            [15]  Cai S, Zhao M, Fang Y,  et al. Microencapsulation of lactobacillus
                                                                   acidophilus CGMCC1. 2686  via  emulsification/internal gelation of
                                                                   alginate using Ca-EDTA  and CaCO 3 as calcium sources[J]. Food
                                                                   Hydrocolloids, 2014, 39: 295-300.
                 利用液体石蜡和 Span 80 对 Ca(IO 3 ) 2 进行分散,           [16]  Pérez-Madrigal M M, Torras J, Casanovas J, et al. Paradigm shift for
                                                                                  2+
            以 Nano-CaCO 3 为交联剂,采用改良的内源乳化法                          preparing versatile  M -free gels from unmodified sodium
                                                                   alginate[J]. Biomacromolecules, 2017, 18(9): 2967-2979.
            制得 CISAMC,其载药率和包封率分别为 41.0%和                       [17]  Ching S H, Bansal N, Bhandari B. Alginate gel particles–a review of
                                                                   production techniques and physical properties[J]. Critical Reviews in
            61.5%。                                                 Food Science and Nutrition, 2017, 57(6): 1133-1152.
                                                               [18]  Paques J P, Sagis  L M C, van Rijn  C J M,  et al. Nanospheres of
                (1)FTIR 和 SEM 分析表明,有大量 Ca(IO 3 ) 2                 alginate prepared through W/O emulsification and internal gelation
                                                                   with nanoparticles of CaCO 3[J]. Food Hydrocolloids, 2014, 40:
            颗粒附着在 CISAMC 表面,SAMC、CISAMC 上均                         182-188.
                                                               [19]  National Center for Health Inspection and Supervision (卫生部食品
            存在孔隙,并且 CISAMC 上褶皱明显。TG 和 XRD
                                                                   卫生监督检验所). Methods of food hygienic analysis—physical and
            分析表明,Ca(IO 3 ) 2 以结晶态分布在 SAMC 中,                       chemical section—general principles (食品卫生检验方法理化部分
                                                                   总则): GB/T 5009. 1—2003[S]. Beijing: Standards Press of China(北
            CISAMC 中的 Ca(IO 3 ) 2 分解温度较纯 Ca(IO 3 ) 2 降低。           京:中国标准出版社), 2003, 14-15.
                                                               [20]  Wang Haijia (王海佳). Study the stability vitamin C by ultraviolet
                (2)CISAMC 对 Ca(IO 3 ) 2 具有良好的保护性。                  spectrophotometry and determination of the contents in several kinds
                                                                   of fruits, vegetables and juices[D].Taiyuan:Shanxi Medical
            在 V C 水溶液中加入 Ca(IO 3 ) 2 和 CISAMC 后,V C 的              University (山西医科大学), 2015.
                                                               [21]  Deepa B, Abraham E, Pothan L A,  et al. Biodegradable
            t 50% 分别为 54.8 和 78.3 min。CISAMC 能显著提高                 nanocomposite films based on  sodium alginate and cellulose
            Ca(IO 3 ) 2 在含有 V C 等还原性物质饲料中的稳定性。                     nanofibrils[J]. Materials, 2016, 9(1): 50.
                                                               [22]  Na Shasha (那沙沙), Li Weixing (李卫星), Xing Weihong (邢卫红).
            CISAMC 具有取代 Ca(IO 3 ) 2 应用到饲料行业中的潜                     Development of inorganic nano particles  modified sodium alginate
                                                                   hybrid membranes for pervaporation[J]. CIESC Journal (化工学报),
            在价值。此外,后续研究应对 CISAMC 在肠胃液中                             2016, 67(9): 3730-3737.
                                                               [23]  Lin Yueshun (林粤顺), Zhou Xinhua (周新华) , Zhou Hongjun (周红
            释放 Ca(IO 3 ) 2 的机制及其动力学,动物饲养效果等                        军), et al. Preparation and slow-release performance of chlorpyrifos/
            方面展开探讨。                                                feather keratin/sodium alginate microspheres[J]. Agrochemicals (农
                                                                   药), 2014, 53(12): 892-896
                                                               [24]  Gasmi H, Danede  F, Siepmann J,  et al. Does  PLGA microparticle
            参考文献:                                                  swelling control drug release? New insight based on single particle
                                                                   swelling studies[J]. Journal of Controlled Release, 2015, 213: 120-127.
            [1]   Flachowsky G, Franke K, Meyer U,  et al. Influencing factors on   [25]  Shitole S J. Synthesis and characterization of calcium iodate,
                 iodine content of cow milk[J]. European Journal of Nutrition, 2014,   monohydrate crystals grown in silica gel[M]//Recent  Trends in
                 53(2): 351-365.                                   Physics  of Material Science and Technology. Singapore: Springer
            [2]   Du Y, Gao Y, Meng F, et al. Iodine deficiency and excess coexist in   Science Business Media, 2015: 245-257.
                 China and induce thyroid dysfunction and disease: a cross-sectional   [26]  Kong Q, Wang B, Ji Q,  et al.  Thermal degradation and flame
                 study[J]. Plos One,2014,9(11):e111937.            retardancy of calcium alginate fibers[J]. Chinese Journal of Polymer
            [3]   Samios D N, Karayannis M I, Hadjiioannou T P. Investigation on the   Science, 2009, 27(6): 807-812.
                 rate law of the reaction of ascorbic acid and iodate. calculation  of   [27]  Seebauer V, Petek J, Staudinger G. Effects of particle size, heating
                 kinetic parameters  applying stopped-flow techniques[J].  Zeitschriftfür   rate and pressure on  measurement of pyrolysis kinetics by
                 Physikalische Chemie, 1977, 104(4/5/6): 189-198.     thermogravimetricanalysis[J]. Fuel, 1997, 76(13): 1277-1282.
   137   138   139   140   141   142   143   144   145   146   147