Page 125 - 《精细化工》2019年第11期

第 36 卷第 11 期 精 细 化 工 Vol.36, No.11
2019 年 11 月 FINE CHEMICALS Nov. 2019

医药与日化原料
利用均匀设计法制备撕剥型干洗剂及性能分析

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武玉和，郑果林，刘 帅，苏青春，张 丹
（江南大学 生态纺织教育部重点实验室，江苏无锡 214122）

摘要：为开发环保无毒和无粉尘的便携干洗剂，选用聚乙烯醇（PVA）、水、乙醇、D-柠檬烯、硅胶和羧甲基纤
维素（CMC）采用控制变量法初步制备了撕剥型干洗剂。以 PVA、CMC、硅胶和 D-柠檬烯的质量分数为自变
量因素，去污效率为表征指标，取 4 因素 7 水平设计均匀实验。再以 SPSS 软件对结果进行回归分析得到数学
模型，以 MATLAB 软件对模型进行计算，得到优化配比（质量分数，以体系总质量为基准）：PVA 2488（牌号）
为 4.5%、CMC 为 1.5%、800 目硅胶为 7.5%、D-柠檬烯为 11%。该配方去污效率可达 97.08%。通过 FTIR 和 SEM
对干洗剂所得薄膜及织物进行结构表征和去污原理分析，并对织物的物理性能进行测试。结果表明，干洗剂对
粉尘微粒与油渍的去污效果很好，织物上残留很少，织物仍保留着较好的服用性能。
关键词：干洗剂；撕剥型；均匀设计；聚乙烯醇；D-柠檬烯；日化原料
中图分类号：TS973.1 文献标识码：A
文章编号：1003-5214 (2019) 11-2273-06 开放科学 (资源服务) 标识码 (OSID)：

Preparation of Peel-off Type Dry Cleaning Agent by Uniform

Design Method and Its Performance Analysis

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WU Yu-he, ZHENG Guo-lin, LIU Shuai, SU Qing-chun, ZHANG Dan
（Key Laboratory of Eco-Textiles, Ministry of Education, Jiangnan University, Wuxi 214122, Jiangsu, China）

Abstract: In order to develop environmentally friendly, non-toxic, dust-free and portable dry cleaning
agents, polyvinyl alcohol (PVA), water, ethanol, D-limonene, silica gel and carboxymethyl cellulose (CMC)
were employed to prepare peel-off type dry cleaning agents. A four-factor and seven-level uniform design
test was conducted to screen the optimum formulation of dry cleaning agent by using the mass fractions of
PVA, CMC, silica gel and D-limonene as the independent variables, the decontamination efficiency as the
dependent variable. The results were analyzed by SPSS software and the mathematical model was obtained.
The model was calculated by MATLAB software, and the optimized ratios (mass fractions) were as follows:
PVA 2488 4.5%, CMC 1.5%, 800 mesh silica gel 7.5% and D-limonene 11%. The decontamination
efficiency of the formulation reached 97.08%. FTIR and SEM were employed to characterize the structure
of the fabric and the membrane obtained by dry cleaning agent, and the decontamination principle was
analyzed. The physical properties of fabric were tested. The results showed that the prepared dry cleaning
agent had good decontamination effect on dust particles and oil stains, and there were few residues on the
fabric, and the fabric still retained good clothing performance.
Key words: dry cleaning agent; peel-off type; uniform design; polyvinyl alcohol; D-limonene; cosmetic materials

随着现代生活节奏的加快，人们希望能迅速方 洗剂、布艺干洗去污剂和衣物泡洗颗粒等。其中溶
便地处理日常家务。因此，在国内外市场上涌现出 剂型干洗喷雾剂的应用最为广泛，它凭借免水洗、
了许多高效的清洁日用品，如纳米海绵、小白鞋干 可小面积施用、便携且无使用条件限制等优势而受

收稿日期：2019-04-19; 定用日期：2019-05-20; DOI: 10.13550/j.jxhg.20190337
基金项目：国家自然科学基金（31600478）；江苏省自然科学基金（BK20140145）；中央高校基本科研业务费专项资金（重点项目
JUSRP51718A）；江苏高校优势学科建设工程资助项目（苏政办发[2014]37）
作者简介：武玉和（1994—），男，硕士生，E-mail：2320002091@qq.com。联系人：张 丹（1981—），男，副教授，硕士生导师，
E-mail：zhangdan@jiangnan.edu.cn。