Page 130 - 《精细化工》2019年第11期
P. 130
·2278· 精细化工 FINE CHEMICALS 第 36 卷
但程度都较小,织物仍保留着较好的服用性能。
(5)撕剥型干洗剂在去污领域尚属首创,有着
广阔的应用前景,今后在其基础上的改进方向有速
干型、适应织物面广、无残留等。
参考文献:
[1] Chen Xinde (陈信德), Ma Yijing (马怡敬), Sui Qinglan (隋庆兰).
Prepration and performance analysis of a new fabric oil stain spot
remover[J]. Journal of Tianjin Textile Institute (天津纺织工学院学
报), 1986, 5(1): 38-43.
[2] Sui Qinglan (隋庆兰), Zhou Changnian (周昌年), Zhang Liangsheng
(张良生). Performance and development of a new spray dry cleaning
agent[J]. Journal of Textile Research (纺织学报), 1986, 7(11): 19-21.
[3] Liu Lin ( 刘林 ), Peng Shujin ( 彭蜀晋 ). Talking about the
tetrachloroethylene dry cleaning agent[J]. Chinese Journal of
图 6 涤纶布表面(a)及放大(b)、涤纶布经向(c)和纬向 (d) Chemical Education (化学教育), 2007, 28(12): 1-2,5.
[4] Liu Yidan (刘懿丹). Study on determination of residual chlorination
截面的 SEM 图 of tetrachloroethylene and environmental release behavior in dry
Fig. 6 SEM images of polyester fabric surface (a), magnified cleaned cloth[D]. Hangzhou:Zhejiang Sci-Tech University (浙江理工
polyester fabric surface(b), warp section of polyester 大学), 2017.
fabric (c) and weft section of polyester fabric (d) [5] Beringhs A O, Rosa J M, Stulzer H K, et al. Green clay and aloe vera
peel-off facial masks: Response surface methodology applied to the
2.5 织物的物理性能分析 formulation design[J]. AAPS Pharm Sci Tech, 2013, 14(1): 445-455.
[6] Velaseo M V R, Vieira R P, Fernandes A R. Short-term clinical of
由表 7 可见,与 SEM 观察所推测的一样,涤纶 peel-off facial mask moisturizers[J]. International Journal of
织物在经过干洗剂整理后,透气性和折皱回复角均 Cosmetic Science, 2014, 36: 355-360.
[7] Liu Lixian (刘丽仙), Jiang Ligang (蒋丽刚), Shen Fengshou (申奉
有所下降,透气性从 103.6 mm/s 降为 88.4 mm/s, 受), et al. Mask formulation technology and mask fabric overview[J].
折皱回复角从 147.5(急)和 172.3(缓)降为 129.7 Detergent & Cosmetics (日用化学品科学), 2015, 38(6): 6-9, 44.
[8] Guo Yaonan (郭耀楠). Preparation and properties of SiO 2/P(MMA-
和 150.2,但下降程度均较小。另外,纬向与经向 co-MAA) self-brittle detergent[D]. Mianyang: Southwest University
of Science and Technology (西南科技大学), 2018.
强力有所增加,即经干洗剂处理后的织物部分物理
[9] Lei Chuntang (雷春堂), Pan Xiaoyong (潘晓勇), Yao Guohong (姚
机械性能反而增强了。综上所述,干洗剂使用后对 国红), et al. Progress in water-soluble polyvinyl alcohol[J]. China
Plastics Industry (塑料工业), 2011, 39(2): 10-13.
织物影响较小,织物仍保留着较好的服用性能。 [10] Zhu Jing (朱晶), Ai Licheng (艾立诚), Chen Jing (陈静). Method for
dissolving polyvinyl alcohol[J]. Journal of North Pharmacy (北方药
表 7 原涤纶织物与去污后涤纶织物的物理性能 学), 2011, 8(3): 7-8.
Table 7 Physical properties of original polyester fabric and [11] Hasenclever K D. Wet cleaning of textiles-handbook for cleaning/
decontaminated polyester fabric decontamination of surfaces-D.2[M]. Elsevier Science B V, 2007:
427-438.
断裂强力/N 透气性/(mm/s) 折皱回复角/() [12] Hu Shengfa (胡生发), Hua Er (花儿). Prepration of an orange peel
essential oil dry cleaning agent[J]. China Surfactant Detergent &
原涤纶 经向 714.5±8.1 急 147.5±1.4
103.6±1.5 Cosmetics (日用化学工业), 2014,44 (2): 87-89.
织物 纬向 382.6±6.5 缓 172.3±2.0 [13] Pan Lijun (潘丽军), Chen Jinquan (陈锦权). Test design and data
去污后涤 经向 722.1±10.4 急 129.7±1.6 processing[M]. Nanjing: Southeast University Press (东南大学出
88.4±2.8 版社), 2008, 2.
纶织物 纬向 390.8±6.9 缓 150.2±2.3
[14] Zhang Faming ( 张法明 ), Chang Jiang ( 常江 ), Eberhard B.
Dissolution of poly(vinyl alcohol)-modified carbon nanotubes in a
3 结论 buffer solution[J]. New Carbon Materials (新型炭材料), 2010,
25(4): 241-247.
[15] Guo Yuning (郭雨宁), Shao Dongyan (邵冬燕), Chai Wenlong (柴文
(1)以 PVA、CMC、硅胶、D-柠檬烯、乙醇和 龙 ), et al. Removal performance of TBCC activated oxygen
bleaching system on textile colored stains[J]. China Surfactant
水等环保型原材料制备了可成膜撕剥型干洗去污剂。 Detergent & Cosmetics (日用化学工业), 2018, 48(4): 201-204.
(2)通过均匀实验设计和软件分析得到了优化 [16] Chen Cunkai (陈存凯), Ding Yun (丁昀), Yun Qian (云倩), et al.
Optimization of the chlorine oxidation resistance of low-temperature
方案(质量分数):PVA 2488 4.5%、CMC 1.5%、800 plasma modified cation exchange membrane by uniform design[J].
目硅胶 7.5%、D-柠檬烯 11%,余量为水、乙醇,质 Materials Reports (材料导报), 2018, 32(S1): 532-538.
[17] Standardization Administration of the People's Republic of China (中
量比为 1∶2。在该配方下干洗剂的去污效率可达 国国家标准化 管理委员会 ), GB/T5453 — 1997, Textiles -
97.08%,远高于市售溶剂型喷雾干洗剂。 Determination of the permeability of fabrics to air [S].
Beijing:Standards Press of China(中国标准出版社), 1997: 1-7.
(3)通过 FTIR 及 SEM 证明,撕剥型干洗剂在 [18] Standardization Administration of the People's Republic of China (中
国国家标准化管理委员会), GB/T 3923.1—2013, Textiles-Tensile
织物上的残留很少,其干燥后所得的薄膜主要是 properties-Part 1: Determination of breaking strength and elongation
PVA 骨架和硅胶微粒构成的复合材料,其三维孔洞 at break (strip method)[S]. Beijing:Standards Press of China(中国标准
出版社), 2013.
及沟壑结构保证了干洗剂对污渍的吸附和移除能力。 [19] Standardization Administration of the People's Republic of China (中
(4)经过撕剥型干洗剂处理的涤纶织物,其透 国国家 标准 化 管理委 员会 ), GB/T 3819 — 1997, Textiles -
Determination of crease recovery of fabrics - Reply angle method
气性、折皱回复角略有下降,断裂强度有所上升, [S]. Beijing:Standards Press of China(中国标准出版社), 1997: 1-7.