Page 202 - 《精细化工》2020年 第10期

第 37 卷第 10 期 精 细 化 工 Vol.37, No.10
2020 年 10 月 FINE CHEMICALS Oct. 2020

纺织染整助剂
氧化石墨烯浸轧-还原法制备导电棉织物

黄海涛

（河南工程学院 纺织学院，河南 郑州 450007）

摘要：采用超声氧化剥离法制备氧化石墨烯（GO），通过浸轧-还原法得到一种高效、简单制备还原氧化石墨烯
（RGO）导电棉织物的方法。探讨了 GO 质量浓度、GO 溶液 pH、还原条件、浸轧-还原次数等因素对 RGO 整
理棉织物表面电阻的影响，采用 SEM 和 Raman 光谱对整理棉织物进行表征。结果表明，棉织物用质量浓度
2.5 g/L、pH=6 的 GO 溶液浸轧后，再用质量浓度 5.0 g/L 的保险粉于 90 ℃对浸轧 GO 烘干后的棉织物还原 30 min，
得到的整理棉织物表面电阻降低至 2220 Ω，经过 4 次和 8 次浸轧-还原后棉织物表面电阻可分别降低至 0.22 和
0.13 kΩ。通过 SEM 观察整理棉织物发现，RGO 能在棉纤维表面形成薄膜并包覆纤维，且随着浸轧-还原次数的
增加，棉织物表面沉积的 RGO 逐渐增多。Raman 光谱较好地证实了 GO 在棉织物表面的沉积，且 GO 较充分地
还原成 RGO。通过对整理棉织物的耐洗性能测试发现，整理织物的导电耐久性较好。
关键词：氧化石墨烯；棉织物；导电性；还原；浸轧；纺织染整助剂
中图分类号：TQ340；TS195.5 文献标识码：A 文章编号：1003-5214 (2020) 10-2132-06

Preparation of conductive cotton fabrics by
padding reduction of graphene oxide

HUANG Haitao
（School of Textile, Henan University of Engineering, Zhengzhou 450007, Henan, China）

Abstract: Graphene oxide (GO) was prepared by ultrasonic oxidation stripping method. A highly efficient
and simple method for the preparation of reduced graphene oxide (RGO) conductive cotton fabrics was
developed, in which, the cotton fabrics was immersed by GO solution, then, the GO padded cotton fabrics
was dried, finally the reduced graphene oxide (RGO) coated conductive cotton fabrics was obtained by
chemical reduction. The effects of GO mass concentration, GO solution pH value, reduction condition,
padding-reduction times on the surface resistance of cotton fabrics were investigated. The treated cotton
fabrics were characterized by SEM and Raman spectra. The results showed that the optimal conditions were
obtained as follows: GO mass fraction of 2.5 g/L, pH value of GO solution of 6, sodium hydrosulfite mass
fraction of 5.0 g/L, reduced temperature 90 ℃ and reaction time 30 min. Under these conditions, the
surface resistance of the treated cotton fabrics was decreased to 2220 Ω, 0.22 kΩ and 0.130 kΩ after 4 and 8
times of padding-reduction process, respectively. SEM results revealed that RGO could form film on the
surface of cotton fiber and cover the fiber, and with the increase of the number of padding reduction, the
deposition of RGO on the surface of cotton fabrics increased gradually. Raman spectra results showed that
GO was deposited on the surface of cotton fabrics and fully reduced to RGO. Moreover, the conductive
durability of the treated fabric was excellent.
Key words: graphene oxide; cotton fabrics; conductivity; reduction; padding; dyeing and finishing auxiliaries

柔性导电材料具有与常规坚硬导电材料相似的 件、可穿戴智能材料、新型太阳能电池、电子皮肤
导电性，且轻便易携带、柔韧性好，在柔性电子器 等领域具有广泛的应用前景 [1-4] 。其中，柔性导电纺

收稿日期：2020-04-18; 定用日期：2020-06-07; DOI: 10.13550/j.jxhg.20200330
基金项目：河南省高等学校重点科研项目（18B540001）
作者简介：黄海涛（1979—），男，硕士，讲师，E-mail：ht80856@163.com。