Page 33 - 《精细化工》2020年 第10期

第 10 期 鲍 艳，等: 模板法制备介孔 SiO 2 及其孔径调节研究进展 ·1963·

[16] BAO Y, KANG Q L, MA J Z, et al. Structural regulation of hollow
3 结语与展望 spherical TiO 2 by varying titanium source amount and their thermal
insulation property[J]. Colloids and Surfaces A: Physicochemical and
Engineering Aspects, 2018, 537: 69-75.
尽管已经合成了不同介孔 SiO 2，但是在精准控制 [17] WU Y Q, WEI J W, WANG D Q. Removal of heavy metals in water
by functionalized mesoporous silica materials: A review[J].
介孔 SiO 2 的结构、提高介孔稳定性、制备大孔径且高 Advanced Materials Research, 2013, 785/786: 693-696.
度有序的介孔 SiO 2 等方面仍存在一定的困难。因此， [18] GU X X, HAN Y, CHEN J J, et al. Advances in studies on the
adsorption of dyes in wastewater using mesoporous materials[J].
在未来的发展中，介孔 SiO 2 的研究将主要集中在以下 Advanced Materials Research, 2012, 356/360: 349-354.
[19] HUIRACHE A A R, NAVA R, PEZA L C, et al. SBA-15 mesoporous
几个方面：（1）深度探索介孔 SiO 2 孔结构的形成机 silica as catalytic support for hydrodesulfurization catalysts-
理；（2）改进现有工艺以获得性能更加优异、结构更 review[J]. Materials, 2013, 6(9): 4139-4167.
[20] LUQUE R, GARCIAN M J. Editoria: From mesoporous supports to
加有序的介孔 SiO 2 ；（3）拓展介孔 SiO 2 的合成工艺， mesoporous catalysts: Introducing functionality to mesoporous
materials[J]. ChemCatChem, 2013, 5(4): 827-829.
并研究其合成机理；（4）加大对大孔有序 SiO 2 的研 [21] YANG C (杨翠), SHEN T (申腾), TENG H N (滕弘霓). Research
究；（5）探究具有多级孔结构的介孔 SiO 2 的合成； progresson preparation of mesoporous materials using surfactants as
templates[J]. Journal of Shandong University of Science and
（6）借助计算机模拟，从分子水平或微观结构上揭示 Technology (山东科技大学学报), 2016, 35(6): 49-55.
[22] KUMAR S, MALIK M M, PUROHIT R, et al. Synthesis methods of
表面活性剂-无机材料之间的相互作用。探究介孔 SiO 2 mesoporous silica materials[J]. Materials Today: Proceedings, 2017,
材料在不同领域的潜在应用，扩大其实际应用范围。 4(2): 350-357.
[23] BAO Y, SHI C H, WANG T. Recent progress in hollow silica:
Template synthesis, morphologies and applications[J]. Microporous
参考文献： and Mesoporous Materials, 2016, 227: 121-136.
[24] BAO Y, WANG T, KANG Q L. Micelle-template synthesis of hollow
[1] LI W, ZHAO D Y. An overview of the synthesis of ordered silica spheres for improving water vapor permeability of waterborne
mesoporous materials[J]. Chemical Communications, 2013, 49: polyurethane membrane[J]. Scientific Reports, 2017, 7: 46638-46651.
943-946. [25] ZHOU J, PENG S, QIN H J, et al. Fabrication and visible emissions
[2] BAO Y, YANG Y Q, MA J Z, et al. Fabrication of monodisperse of ZnO nanocrystal doped transparent zinc silicate glass-ceramics[J].
hollow silica spheres and effect on water vapor permeability of Jouenal of Alloys and Compounds, 2019, 5(776): 52-58.
polyacrylate membrane[J]. Journal of Colloid and Interface Science, [26] XU X Z (许宪祝). Mesoporous materials and anion exchangers[M].
2013, 407: 155-163. Harbin: Northeast Forestry University Press (东北林业大学出版社),
[3] ZHOU Y Y, LI X X, CHEN Z X, et al. Rapid synthesis of 2005.
well-ordered mesoporous silica from sodium silicate[J]. Powder [27] LI M, WANG H, LI X B, et al. Organosilica nanotube templates:
Technology, 2012, 226: 239-245. One-pot synthesis of carbon-modified polymeric carbon nitride
[4] ZHANG F R, SU D, HE J, et al. Methyl modified SiO 2 aerogel with nanorods for photocatalysis[J]. ChemCatChem, 2018, 10(3): 581-589.
tailored dual modal pore structure for adsorption of organic [28] QIU H B, CHE S A. Chiral mesoporous silica: Chiral construction
solvents[J]. Materials Letters, 2019, 1(238): 202-205. and imprinting via cooperative self-assembly of amphiphiles and
[5] LEE K J, CHOE Y J, KIM Y H, et al. Fabrication of silica aerogel silica precursors[J]. Chemical Society Reviews, 2011, 40(3): 1259-
composite blankets from an aqueous silica aerogel slurry[J]. 1268.
Ceramics International, 2018, 2(44): 2204-2208. [29] BAO Y, KANG Q L, MA J Z. Monodisperse hollow TiO 2 spheres for
[6] YADAV A K, GAUTAM C. Dielectric behavior of perovskite glass thermal insulation materials: Template-free synthesis, characterization
ceramics[J]. Journal of Materials Science: Materials in Electronics, and properties[J]. Ceramics International, 2017, 43(12): 8596-8602.
2014, 25(12): 5165-5187. [30] BAO Y (鲍艳), GAO M (高敏), DONG Y F (董雨菲). Fabrication of
[7] BAO Y, ZHANG Y X, MA J Z, et al. Controllable fabrication of hollow TiO 2 spheres and effect on properties of polyacrylate film[J].
one-dimensional ZnO nanoarrays and their application in Chemical Journal of Chinese Universities (高等学校化学学报),
constructing silver trap structures[J]. RSC Advances, 2014, 4(63): 2017, 38(12): 2328-2336.
33198-33205. [31] KANG Q L (康巧玲). Fabrication of thermal insulation hollow
[8] LINDLAR B, LUCHINGER M, ROTHLIS B A, et al. Chemical spheres and their application in polyacrylate[D]. Xi'an: Shaanxi
modification of high-quality large-pore M41S materials[J]. Journal of University of Science & Technology (陕西科技大学), 2018.
Materials Chemistry, 2002, 12(3): 528-533. [32] BAO Y (鲍艳), KANG Q L (康巧玲). Fabrication of hollow TiO 2
[9] MARTINERZ M L, FALCON H, BELTEAMONER A R. Synthesis spheres and their effect on thermal insulation property of
and characterization of 2D-hexagonal, 3D-hexagonal and cubic polyacrylate film[J]. Journal of Inorganic Materials (无机材料学报),
mesoporous materials using CTAB and silica gel[J]. Materials & 2017, 32(6): 581-586.
Design, 2016, 104: 251-258. [33] BAO Y (鲍艳), KANG Q L (康巧玲). Progress of double-shelled
[10] FANG X L, CHEN C, LIU Z H, et al. A cationic surfactant assisted inorganic hollow microspheres: Preparation method, formation
selective etching strategy to hollow mesoporous silica spheres[J]. mechanism and application[J]. Materials Reports (材料导报), 2016,
Nanoscale, 2011, 3(4): 1632-1639. 30(23): 1-8.
[11] YOUNG B J. CO 2 capture by amine-functionalized mesoporous [34] YANG J, LIN G S, MOU C Y, et al. Mesoporous silica thin
hollow silica[J]. Journal of Nanoscience & Nanotechnology, 2017, membrane with tunable pore size for ultrahigh permeation and
17(10): 7418-7422. precise molecular separation[J]. ACS Applied Materials & Interfaces,
[12] PELUSO A, GARGIULO N, APREA P, et al. Nanoporous materials 2020, 12(6): 7459-7465.
as H 2S adsorbents for biogas purification: A review[J]. Separation [35] BELOSTOZKY A, BRETLER S, KOLITZ D M, et al. Solidifcation
and Purification Reviews, 2019, 2(1): 78-89. of oil liquids by encapsulation within porous hollow
[13] CROISSANT J G, FATIEIEV Y, ALMALIK A, et al. Mesoporous silicamicrospheres of narrow size distribution for pharmaceutical and
silica and organosilica nanoparticles: Physical chemistry, biosafety, cosmeticapplications[J]. Materials Science & Engineering
delivery strategies and biomedical applications[J]. Advanced C-Materials for Biological Application, 2019, 97(4): 760-767.
Healthcare Materials, 2018, 7(4): 1700831. [36] MALGRAS V, TANG J, WANG J, et al. Fabrication of nanoporous
[14] FARJADIAN F, ROOINTAN A, MOHAMMADI S S, et al. carbon materials with hard- and soft-templating approaches: A
Mesoporous silica nanoparticles: Synthesis, pharmaceutical review[J]. Journal of Nanoscience and Nanotechnology, 2019, 19(7):
applications, biodistributio, and biosafety assessment[J]. Chemical 3673-3685.
Engineering Journal, 2019, 1(359): 684-705. [37] SHI C H (时春华). Soft-template synthesis of hollow silica spheres
[15] KARAMAN D S, MANNER S, ROSENHOLM J M, et al. and their effects on the properties of waterborne polyurethane[D].
Mesoporous silica nanoparticles as diagnostic and therapeutic tools: Xi'an: Shaanxi University of Science & Technology (陕西科技大
How can they combat bacterial infection[J]. Therapeutic Delivery, 学), 2015.
2018, 9(9): 241-244. [38] BAO Y (鲍艳), YANG Y Q (杨永强), MA J Z (马建中). Research