Page 190 - 《精细化工》2020年第8期

·1688· 精细化工 FINE CHEMICALS 第 37 卷

5、6 d 病毒微胶珠使幼虫的死亡率提高 30%~40%。 Journal of Invertebrate Pathology, 2006, 93(2): 88-95.
[12] CARMEN A L, BARBARA B F, PUGA A M, et al. Crosslinked ionic
而 P/S-N 微胶珠经紫外线照射后，总体优于经紫外 polysaccharides for stimuli-sensitive drug delivery[J]. Advanced
Drug Delivery Reviews, 2013, 65(9): 1148-1171.
线处理后病毒的杀虫活性。前 3 d 病毒与病毒微胶 [13] DRAGAN E S. Design and applications of interpenetrating polymer
network hydrogels. A review[J]. Chemical Engineering Journal.
珠的致死率均接近于 0，在第 4 d 开始产生大量死虫， 2014, 243: 572-590.
这说明微胶珠中的聚多巴胺和海藻酸钠并不影响病 [14] SHI Z P (史占萍), SHI M (史迈), ZHANG W H (张文惠), et al.
Preparation, characterization and toxicological analysis of alginate-
毒在昆虫中肠内的释放与对中肠上皮细胞的侵染， phospholipid vesicle composite hydrogels[J]. Chemical Journal of
Chinese Universities (高等学校化学学报), 2017, 38(7): 1270-1277.
这种病毒微胶珠可以在抵御紫外线对病毒破坏的同 [15] YI X F, YANG M X, MO L D, et al. Modification of chitosan/
calcium alginate/Fe 3O 4 hydrogel microsphere for enhancement of
时降低对其活性的影响。 Cu(Ⅱ) adsorption[J]. Environmental Science and Pollution Research,
2018, 25(4): 3922-3932.
[16] FAN J C, SHI Z X, LIAN M, et al. Mechanically strong graphene
3 结论 oxide/sodium alginate/polyacrylamide nanocomposite hydrogel with
improved dye adsorption capacity[J]. Journal of Materials Chemistry,
2013, 1(25): 7433-7443.
采用雾化凝固法制备包埋甜菜夜蛾核型多角体 [17] DAEMI H, BARIKANI M. Synthesis and characterization of calcium
病毒海藻酸钠微胶珠，并进行聚多巴胺覆膜，得到 alginate nanoparticles, sodium homopolymannuronate salt and its
calcium nanoparticles[J]. Scientia Iranica, 2012, 19(6): 2029-2028.
了 P/S-N 复合微胶珠。由于海藻酸钠和聚多巴胺的 [18] ZOU A H, YANG Y, CHENG J G, et al. Construction and characterization
of a novel sustained-release delivery system for hydrophobic pesticides
双层保护作用，所制备的病毒微胶珠的主体结构热 using biodegradable polydopamine-based microcapsules[J]. Journal
of Agricultural and Food Chemistry, 2018, 66(25): 6262-6268.
稳定性比单一材料有所提升。在经过 2 h 紫外线处 [19] MICHINARI K, KENSHI Y, AYAKA K, et al. Polydopamine-based
3D colloidal photonic materials: structural color balls and fibers from
理后，相对于病毒而言，在投毒第 5、6 d 病毒微胶 melanin-like particles with polydopamine shell layers[J]. ACS Applied
Materials & Interfaces, 2018, 10(9): 7640-7648.
珠使幼虫的死亡率提高 30%~40%，说明在紫外线的
[20] LIN C M, GONG F Y, YANG Z J, et al. Bio-inspired fabrication of
照射下聚多巴胺保护了病毒的活性。与乳化法制得 core@shell structured TATB/polydopamine microparticles via in situ
polymerization with tunable mechanical properties[J]. Polymer Testing,
的病毒微胶囊制剂相比，喷雾干燥法具有反应液可 2018, 68: 126-134.
[21] SUN Y H, ZHONG S A. Nanoscale trifunctional bovine hemoglobin
回收利用，制备工艺绿色安全无污染，水中分散性 for fabricating molecularly imprinted polydopamine via pickering
emulsions-hydrogels polymerization[J]. Colloids and Surfaces B:
好，微胶珠壁材不会在水中溶解和溶胀等诸多优势。 Biointerfaces, 2018, 159: 131-138.
本文结果为稳定高效昆虫病毒制剂的研究和应用提 [22] ZHU B, LIU J D, WANG S F, et al. Mixed matrix membranes
containing well-designed composite microcapsules for CO 2
供了思路。 separation[J]. Journal of Membrane Science, 2019, 572: 650-657.
[23] TANG C X, LI Y Z, PUN J S, et al. Polydopamine microcapsules
from cellulose nanocrystal stabilized pickering emulsions for
参考文献： essential oil and pesticide encapsulation[J]. Colloids and Surfaces A:
Physicochemical and Engineering Aspects, 2019, 570: 403-413.
[1] XIAO H Z (肖化忠), QI Y P (齐义鹏), YANG F H (杨复华).
Estimate the safety of baculovirus insecticides: the history and the [24] CHEN M F, FAN D C, LIU S M, et al. Fabrication of self-healing
hydrogels with surface functionalized microcapsules from stellate
status quo[J]. Chinese Journal of Biotechnology (生物工程学报),
2001, 17(3): 236-240. mesoporous silica[J]. Polymer Chemistry, 2019, 10(4): 503-511.
[2] GUO H F (郭慧芳), FANG J C (方继朝), HAN Z J (韩召军). [25] SHEN Y, WANG Y, ZHAO X, et al. Preparation and physicochemical
Advances in insect virus synergists[J]. Acta Entomologica Sinica (昆 characteristics of thermo-responsive emamectin benzoate microcapsules
虫学报), 2003, 46(6): 766-772. [J]. Polymers, 2018, 9(9): 418.
[3] MA X M (马晓梅), ZHU X R(朱西儒), TIAN C E (田长恩). New [26] YE W, WANG N, HU K B, et al. Bio-inspired microcapsule for
progress in research and application of microbial pesticides in targeted antithrombotic drug delivery[J]. Solar Energy Materials and
China[J]. Journal of Wuhan University of Science and Engineering Solar Cells, 2018, 8(48): 27253-27259.
(武汉科技学院学报), 2006, 19(11): 42-46. [27] ZHANG H X, HU Q T, ZHENG X W, et al. Incorporating
[4] ZHANG Y L (张彦龙), WU S A (武三安), GUO W X (郭文霞), et phosphoric acid-functionalized polydopamine into Nafion polymer
al. Research progress on biological control of fall webworm by in situ sol-gel method for enhanced proton conductivity[J].
(Hyphantria cunea Drury) in China[J]. Hebei Journal of Forestry and Journal of Membrane Science, 2019, 570: 236-244.
Orchard Reserach (河北林果研究), 2008, 23(1): 70-77. [28] GAO Z D, PANG L, FENG H J, et al. Preparation and characterization
[5] ZHANG E N (张二娜), CHEN Z M (陈智明). Study on the ecological of a novel imidacloprid microcapsule via coating of polydopamine
control technology system of cauliflower mot[J]. Agriculture of and polyurea[J]. RSC Advances, 2017, 7(26): 15762-15768.
Henan (河南农业), 2016, 384(4): 32-33, 42. [29] KUMAR D, DIPAK R, MEENAKSHI S S A S, et al. Sulfonated poly
[6] DUAN L Q (段立清). Sublethal effect of insect virus on the (ether sulfone) composite membranes customized with polydopamine
Lepidoptera defoliators[J]. Forest Pest and Disease (中国森林病虫), coated molybdenum disulfide nanosheets for renewable energy
2002, 21(3): 33-35. devices[J]. Polymer, 2019, 175: 255-264.
[7] CHEN Z F (陈泽藩). Effects of climate and sunlight on the survival [30] DIBYAKANTA S, HARI N M, SANKAR C D. Effect of
of viral insecticides[J]. Guangdong Forestry Science and Technology microencapsulation using extrusion technique on viability of bacterial
(广东林业科技), 1980, 2: 36. cells during spray drying of sweetened yoghurt[J]. International Journal
[8] ZHANG J P (张金平). An invisible killer of pests: The karyotype of Biological Macromolecules, 2017, 103: 802-807.
polyhedrovirus[J]. Agricultural Market Information (农药市场信息), [31] FU S, BUCKNER I S, BLOCK L H. Inter-grade and inter-batch
2017, 28: 71-72. variability of sodium alginate used in alginate-based matrix tablets[J].
[9] JIANG J X (蒋杰贤), WANG D S (王冬生), ZENG A P (曾爱平), et AAPS PharmSciTech, 2014, 15(5): 1228-1237.
al. Influence of incubation and inoculation temperatures on the [32] KIM B J, PARK T, PARK S Y, et al. Control of microbial growth in
epizootic of Spodoptera exigua nuclear polyhedrosis virus[J]. Acta alginate/polydopamine core/shell microbeads[J]. Chemistry-An Asian
Ecologica Sinica (生态学报), 2004, 24(8): 1726-1733. Journal, 2015, 10(10): 2130-2133.
[10] KURMEN J E C, ALVAREZ M I G, RIVERO L F V. [33] SHEN Z C, ZHOU X H, SUN X H, et al. Preparation of 2,
Microencapsulation of a colombian spodoptera frugiperda 4-dichlorophenoxyacetic acid loaded on cysteamine-modified
nucleopolyhedrovirus with Eudragit (R) S100 by spray drying[J]. polydopamine and its release behaviors[J]. Journal of Applied
Brazilian Archieves of Biology and Technology, 2015, 58(3): Polymer Science, 2019, 136(20): 47469.
468-476. [34] LIM G P, AHMAD M S. Development of Ca-alginate-chitosan
[11] ARTHURS S P, LACEY L A, BEHLE R W. Evaluation of spray- microcapsules for encapsulation and controlled release of imidacloprid
dried lignin-based formulations and adjuvants as solar protectants for to control dengue outbreaks[J]. Journal of Industrial and Engineering
the granulovirus of the codling moth, Cydia pomonella (L)[J]. Chemistry, 2017, 56: 382-393.