Page 154 - 《精细化工》2020年第2期
P. 154

·356·                             精细化工   FINE CHEMICALS                                 第 38 卷

            间没有显著差异(P>0.05)。与大孔树脂 LX-38 和聚                         and its antibacterial and antioxidant activities[J]. Science and
            酰胺相比,大孔树脂 HP-20 和 X-5 得到的洗脱液花                          Technology of Food Industry (食品工业科技), 2019, 40(2): 175-182.
                                                               [8]   ZHU C L (朱翠玲), CHEN M (陈铭),WANG M H (汪孟涵), et al. In
            色苷纯度略高。其中,体积分数为 70%酸性乙醇经                               vitro characterization of the anti-inflammatory effects of mulberry
            大孔树脂 X-5 分离的花色苷纯度最高,比其他样品                              extract and the molecular mechanisms[J]. Modern Food Science and
                                                                   Technology (现代食品科技), 2017, 33(4): 61-66.
            高出 1 倍 以上( P<0.05 ),但回收率相对较低                       [9]   SANDOVAL-RAMIREZ  B  A, CATALAN U,  FERNANDEZ-
            (4.34%)。使用大孔树脂 HP-20 和 X-5 脱溶剂使花                       CASTILLEJO S, et al. Anthocyanin tissue bioavailability in animals:
            色苷纯度从 5.76%提高到 30.00%左右。桑葚果渣样                          Possible implications for  human health. A systematic  review[J].
                                                                   Journal of Agricultural and Food Chemistry, 2018, 66: 11531-11543.
            品与大孔树脂 X-5 回收样品经过 1.5 节处理,进行                       [10]  XUE H K (薛宏坤), TAN J Q (谭佳琪), LIU C (刘钗),  et al.
            HPLC 检测,对提取物中的花色苷采用外标法进行                               Optimization of extraction process of anthocyanins  from  blueberry
                                                                   pomace and its antitumor activity[J]. Fine Chemicals (精细化工),
            定量,通过计算得到矢车菊素-3-O-葡萄糖苷与矢车
                                                                   2019, 36(9): 1881-1890.
            菊素-3-O-芸香糖苷和矢车菊素的提取量分别从桑                           [11]  ZHANG W N, HE J J, PAN Q H,  et al. Separation and character
            葚果渣中的 27.89、28.98 和 2.21 mg/g 富集到 195.41、              analysis of anthocyanins from mulberry (Morus alba L.) pomace[J].
                                                                   Czech Journal of Food Science, 2011, 29: 268-276.
            94.14 和 9.57 mg/g 花色苷粉末中。                          [12]  CAO R L  (曹日亮), HU  G Y(胡广英),  LIANG X L  (梁兴龙).
                                                                   Production  of  protein feed from fruit residue[J]. Farm Products
            3   结论                                                 Processing (农产品加工), 2003, (1): 31-32.
                                                               [13]  MOHDMAIDIN N, ORUNA-CONCHA M J, JAUREGI P. Surfactant
                 建立并优化了一种生态友好的综合提取-脱溶                              Tween20 provides stabilisation effect on anthocyanins extracted from
                                                                   red grape pomace[J]. Food Chemistry, 2019, 271: 224-231.
            剂法,可以有效地从桑葚果渣中提取花色苷。得到
                                                               [14]  ALLISON B J, SIMMONS C W. Obtaining multiple coproducts
            桑葚果渣中提取和分离花色苷的最佳工艺条件为:                                 from red grape pomace  via anthocyanin extraction and biogas
            n(氯化胆碱)∶n(草酸)=1∶1,水体积分数为 30%,                          production[J]. Journal of Agricultural and Food Chemistry, 2018, 66:
                                                                   8045-8053.
            料液比为 1∶20,超声波辅助(400 W),40  ℃条                      [15]  XUE H K (薛宏坤), HAN X Y (韩茜宇), TAN J Q (谭佳琪), et al.
            件下提取 10 min,重复 3 次,然后以大孔树脂 X-5                         Purification and thermal degradation kinetics of anthocyanins from
                                                                   blackcurrant[J]. Fine Chemicals (精细化工), 2019, 36(4): 721-729.
            为吸附载体进行脱溶剂回收花色苷,洗脱液经脱水
                                                               [16]  SUN H Y (孙浩原). Application and  research progress of eutectic
            干燥后收集,得到最终产品。结果表明,花色苷的                                 solvents in chemical industry[J]. Liaoning Chemical Industry (辽宁
            回收率可达 92.76%,纯度为 30.00%,可满足商业                          化工), 2020, 49(4): 408-410.
                                                               [17]  SKARPALEZOS D, DETSI A. Deep eutectic solvents as extraction
            化应用,在食品、化妆品等领域都有着广泛的应用
                                                                   media for valuable flavonoids from natural sources[J]. Applied
            前景。                                                    Science-Basel, 2019, 9: 4169.
                                                               [18]  DAI Y T, WITKAMP G J, VERPOORTE R,  et al. Natural deep
            参考文献:                                                  eutectic solvents as a new extraction media for phenolic metabolites
                                                                   in  Carthamus tinctorius  L.[J]. Analytical Chemistry, 2013, 85:
            [1]   WU B B (吴滨滨), ZHEN D D (甄丹丹), ZHEN H S (甄汉深), et al.
                                                                   6272-6278.
                 Research progress of mulberry[J]. Asia-Pacific Traditional Medicine
                 (亚太传统医药), 2015, 11(6): 41-43.                 [19]  BAKIRTZI C, TRIANTAFYLLIDOU K, MAKRIS D P. Novel lactic
            [2]   ZHOU Z M, ZHOU B, REN L P, et al. Effect of ensiled mulberry   acid-based natural deep eutectic solvents: Efficiency in the
                                                                   ultrasound-assisted extraction  of antioxidant  polyphenols from
                 leaves and sun-dried mulberry fruit pomace on finishing steer growth
                 performance,  blood  biochemical  parameters,  and  carcass  common native Greek  medicinal plants[J]. Journal of Applied
                 characteristics[J]. PLoS One, 2014, 9: e85406.     Research on Medicinal and Aromatic Plants, 2016, 3: 120-127.
                                                               [20]  GUO N, KOU P, JIANG Y W, et al. Natural deep eutectic solvents
            [3]   PEL P, CHAE H  S, NHOEK P,  et al. Chemical  constituents with
                 proprotein convertase subtilisin/kexin type 9 mRNA expression   couple with integrative extraction technique as an effective approach
                 inhibitory activity from dried immature Morus alba fruits[J]. Journal   for mulberry anthocyanin extraction[J]. Food Chemistry, 2019, 296:
                                                                   78-85.
                 of Agricultural and Food Chemistry, 2017, 65: 5316-5321.
            [4]   MA J T (马金同), LIU L (刘露), LIU  G Y  (刘国英),  et al.   [21]  DAI Y T, VERPOORTE R,  CHOI  Y H. Natural deep eutectic
                 Simultaneous determination of five anthocyanins in mulberry health   solvents  providing enhanced stability of natural colorants from
                                                                   safflower (Carthamus tinctorius)[J]. Food Chemistry,  2014, 159:
                 wine by UPLC-Q-Tof/MS[J]. Liquor  Making  (酿酒), 2019,  46(4):
                 98-100.                                           116-121.
            [5]   WANG C (汪超), ZHANG L H (张莉会), QIAO Y (乔宇),  et al.   [22]  FU R P (付瑞平). Application of deep eutectic solvent in extraction
                                                                   of natural product[D]. Huai'an: Huaiyin Institute of Technology (淮
                 Study  on different fermentation treatment antioxidant constituents
                 and activities  of mulberry wine during fermentation[J]. The Food   阴工学院), 2019.
                 Industry (食品工业), 2018, 39(11): 204-209.       [23]  HUANG Y Y (黄玉岩). Study on extraction and purification of four
                                                                   main compositions of anthocyanins from  Ribes nigrum L.[D].
            [6]   MEMON  A A, MEMON N, LUTHRIA D L,  et al. Phenolic acids
                 profiling and antioxidant potential of mulberry (Morus laevigata W.,   Harbin: Northeast Forestry University (东北林业大学), 2017.
                 Morus nigra L., Morus alba L.) leaves  and fruits  grown in   [24]  ZHANG P J (张平静). The application of  natural deep eutectic
                                                                   solvents in preparation and analysing of flavonoid aglycones[D].
                 Pakistan[J]. Polish Journal of Food & Nutrition Sciences, 2010, 60:
                 25-32.                                            Hangzhou: Zhejiang Gongshang University (浙江工商大学), 2019.
            [7]   CAO P J (曹培杰), CUI J (崔晋), MA Y H (马艳弘). Optimization   [25]  KOU P, KANG Y  F, WANG L T, et al. An integrated strategy for
                                                                   production of four anthocyanin compounds from Ribes nigrum L. by
                 of ultrasonic enzymatic extraction of flavonoids from mulberry seed
   149   150   151   152   153   154   155   156   157   158   159