Page 106 - 《精细化工》2021年第5期

第 38 卷第 5 期 精 细 化 工 Vol.38, No.5
202 1 年 5 月 FINE CHEMICALS May 2021

表面活性剂
十二烷基硫酸钠对亚麻织物喷墨印花性能的影响

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梁迎超 ，刘秀明 1,3* ，房宽峻 1,2,3,4,5* ，安芳芳 ，刘 昊 ，李 畅
〔1. 天津工业大学 纺织科学与工程学院，天津 300387；2. 青岛大学 纺织服装学院，山东 青岛
266071；3. 省部共建生物多糖纤维成形与生态纺织国家重点实验室（青岛大学），山东 青岛 266071；4. 山
东省生态纺织协同创新中心，山东 青岛 266071；5. 国家先进印染技术创新中心，山东 泰安 271000〕

摘要：为提高亚麻织物的喷墨印花颜色效果，将十二烷基硫酸钠（SDS）与海藻酸钠（SA）协同作用于亚麻织
物的预处理工艺，对处理后织物表面墨滴的铺展面积、喷墨印花色块的颜色参数进行了测试，使用接触角测量
仪、SEM、表面 Zeta 电位仪、XPS 和 FTIR 对预处理前后亚麻织物表面物理和化学性能进行了表征。结果表明：
与 SA 预处理织物相比，SDS 的引入可使亚麻织物表面墨滴铺展面积减小 14%，墨滴渗化程度也明显减小；青
色和黑色印花色块的表观颜色深度增加，摩擦色牢度略有降低，断裂强力和耐日晒色牢度无明显改变。预处理
后，SDS+SA 预处理剂在亚麻织物表面形成了薄膜，纤维间以锯齿状的膜结构堵塞了孔隙，促使更多的活性染
料在滴落的位置与纤维发生共价结合；此外，预处理后织物的亲水性增加，有利于染料对亚麻纤维的上染。
关键词：十二烷基硫酸钠；亚麻织物；喷墨印花；活性染料；海藻酸钠；表面活性剂
中图分类号：TS194.4 文献标识码：A 文章编号：1003-5214 (2021) 05-0960-07

Effect of sodium dodecylsulfate on inkjet printing performance of linen fabrics

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LIANG Yingchao , LIU Xiuming 1,3* , FANG Kuanjun 1,2,3,4,5* , AN Fangfang , LIU Hao , LI Chang
[1. College of Textile Science and Engineering, Tiangong University, Tianjin 300387, China; 2. College of Textiles &
Clothing, Qingdao University, Qingdao 266071, Shandong, China; 3. State Key Laboratory of Bio-Fibers and
Eco-Textiles（Qingdao University）, Qingdao 266071, Shandong, China; 4. Collaborative Innovation Center for
Eco-Textiles of Shandong Province, Qingdao 266071, Shandong, China; 5. National Manufacturing Innovation Center
of Advanced Dyeing and Finishing Technology, Taian 271000, Shandong, China]
Abstract: In order to improve the inkjet printing performance of linen fabric, sodium dodecylsulfate (SDS)
and sodium alginate (SA) were used in the pretreatment of linen fabric. The spreading area of ink droplets
on the treated fabrics surface and the color parameters of the inkjet printing color blocks were tested. The
surface physical and chemical properties of linen fabrics before and after pretreated were characterized by
contact angle, SEM, surface Zeta potential instrument, XPS and FTIR. The results showed that compared
with SA pretreatment fabric, the introduction of SDS could reduce the spread area of ink droplets by 14%
and the degree of ink droplets penetration. Moreover, the apparent color depth of cyan and black printing
blocks increased, the rubbing color fastness decreased slightly, and the breaking strength and color fastness
to sunlight had no obvious change. After pretreatment, the SDS+SA pretreatment agent formed a film on the
surface of the fabric, and the serrated membrane structure among the fibers blocked the pores, prompting
more reactive dyes to covalently bond with fibers at the dropping position. In addition, the hydrophilicity of
the pretreated fabric increased, which was conductive to the dye uptake of linen fiber.
Key words: sodium dodecylsulfate; linen fabric; inkjet printing; reactive dye; sodium alginate; surfactants

收稿日期：2020-09-28; 定用日期：2020-12-22; DOI: 10.13550/j.jxhg.20200904
基金项目：国家重点研发计划资助（2017YFB0309800）；山东省重大科技创新工程项目资助（2019TSLH0108）；省部共建生物多糖纤
维成形与生态纺织国家重点实验室（青岛大学）开放课题资助项目（KF2020207）
作者简介：梁迎超（1995—），女，硕士生，E-mail：15231195785@163.com。联系人：刘秀明（1980—），女，博士，副教授，E-mail：
liuxiuming@tiangong.edu.cn；房宽峻（1963—），男，博士，教授，E-mail：13808980221@163.com。