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·1182· 精细化工 FINE CHEMICALS 第 38 卷

总体来说，MOF-808@PAN 纳米纤维膜性质比 organic frameworks[J]. Coordination Chemistry Reviews, 2016, 346:
较稳定，仍能对 CEES 保持较高降解率，仍可继续用 101-111.
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通过静电纺丝技术成功合成了 MOF-808@PAN 37(11): 2223-2228, 2237.
纳米纤维膜，有效防止了 MOF-808 粉末团聚，克服 [13] LEE D T, ZHAO J J, OLDHAM C, et al. UiO-66-NH 2 MOF
nucleation on TiO 2, ZnO, and Al 2O 3 ALD-treated polymer fibers:
了其不易回收的难题。MOF-808@PAN 纳米纤维膜 Role of metal oxide on MOF growth and catalytic hydrolysis of
对 CEES 具有较好的降解效果，使用 3 次后，仍保 chemical warfare agent simulants[J]. ACS Applied Materials &
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持稳定的结构。MOF-808@PAN 纳米纤维膜的最佳 [14] MAUTSCHKE H H, DRACHE F, SENKOVSKA I, et al. Catalytic
调节剂 TFA 含量为 33.3%，反应温度 100 ℃及反应 properties of pristine and defect-engineered Zr-MOF-808 metal
时间为 12 h。5 μL CEES 在 MOF-808@PAN 纳米纤 organic frameworks[J]. Catalysis Science & Technology, 2018,
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