Page 84 - 《精细化工》2021年第7期
P. 84
·1366· 精细化工 FINE CHEMICALS 第 38 卷
+
2+
+
2+
2+
2+
+
与 Ba 、Hg 的亲和力,K 、Na 、Cs 和 Ca 等 4 种 其是 Pb 具有选择响应性能,且该自组装膜对 Pb 2+
金属离子与凝胶中冠醚基团的亲和力非常弱。因此, 的响应性能具有可逆性,并易于通过其结构色的变
自组装膜对以上金属离子的敏感性遵循相同的趋势。 化进行判断。总之,该膜的研究为开发具有裸眼可
2+
2+
2.3.4 自组装膜对 Pb 的响应可逆性 视检测的温度和重金属离子尤其是 Pb 检测试纸化
2+
自组装膜对 Pb 的可逆响应是评价自组装膜是否 材料提供了重要思路。
有实际应用价值的重要指标。图 8 展示了自组装膜在 参考文献:
2+
Pb 浓度为 60 和 0 μmol/L 水溶液中循环响应的结果。
[1] FENZL C, HIRSCH T, WOLFBEISO S. Photonic crystals for
chemical sensing and biosensing[J]. Angewandte Chemie International
Edition, 2014, 53(13): 3318-3335.
[2] ZHANG J H, LI Y F, ZHANG X M, et al. Colloidal self-assembly
meets nanofabrication: From two-dimensional colloidal crystals to
nanostructure arrays[J]. Advanced Materials, 2010, 22(38): 4249-4269.
[3] LIU P M, BAI L, YANG J J, et al. Self-assembled colloidal arrays for
structural color[J]. Nanoscale Advances, 2019, 1(5): 1672-1685.
[4] QIAN W W, ZHAO C L, HE S L, et al. High-sensitivity temperature
sensor based on an alcohol-filled photonic crystal fiber loop
mirror[J]. Optics Letters, 2011, 36(9): 1548-1550.
[5] HAMEED M F O, AZAB M Y, HEIKAL A M, et al. Highly sensitive
plasmonic photonic crystal temperature sensor filled with liquid
crystal[J]. IEEE Photonics Technology Letters, 2016, 28(1): 59-62.
[6] JIA X L, WANG J Y, WANG K, et al. Highly sensitive
mechanochromic photonic hydrogels with fast reversibility and
mechanical stability[J]. Langmuir, 2015, 31: 8732-8737.
[7] WANG Z, XUE M, ZHANG H R, et al. Self-assembly of a nano
hydrogel colloidal array for the sensing of humidity[J]. RSC
Advances, 2018, 8(18): 9963-9969.
[8] LIU J, LI M Z, ZHOU J M, et al. Reversibly phototunable TiO 2
photonic crystal modulated by Ag nanoparticles′ oxidation/
reduction[J]. Applied Physics Letters, 2011, 98(2): 023110.
[9] MEN D D, ZHANG H H, HANG L F, et al. Optical sensor based on
hydrogel films with 2D colloidal arrays attached on both the surfaces:
Anti-curling performance and enhanced optical diffraction intensity[J].
Journal of Materials Chemistry C, 2015, 3(15): 3659-3665.
[10] GAO Y F, SERPE M J. Light-induced color changes of microgel-
based etalons[J]. ACS Applied Materials & Interfaces, 2014, 6(11):
8461-8466.
[11] LIU F, HUANG S Y, XUE F, et al. Detection of organophosphorus
compounds using a molecularly imprinted photonic crystal[J].
Biosensors and Bioelectronics, 2012, 32(1): 273-277.
[12] WANG F Y, ZHU Z G, XUE M, et al. Cellulose photonic crystal film
sensor for alcohols[J]. Sensors and Actuators B: Chemical, 2015,
220: 222-226.
+
pH=7,c(Li )=0.03 mol/L,25 ℃ [13] HOU J, ZHANG H C, YANG Q, et al. Hydrophilic-hydrophobic
2+
图 8 自组装膜在 c(Pb )=60 和 0 μmol/L 之间循环的 patterned molecularly imprinted photonic crystal sensors for
high-sensitive colorimetric detection of tetracycline[J]. Small, 2015,
UV-Vis 光谱 11(23): 2738-2742.
Fig. 8 UV-Vis spectra of the self-assembled film cycling [14] HUANG Y, LI F Y, QIN M, et al. A multi-stopband photonic-crystal
2+
between c(Pb )=60 and 0 μmol/L microchip for high-performance metal-ion recognition based on
fluorescent detection[J]. Angewandte Chemie International Edition,
2013, 52(28): 7296-7299.
可以看到,自组装膜衍射峰均能恢复到初始位 [15] ARUNBABU D, SANNIGRAHI A, JANA T. Photonic crystal
2+
2+
置,这是由于冠醚基团与 Pb 的结合是一个可逆的 hydrogel material for the sensing of toxic mercury ions (Hg ) in
water[J]. Soft Matter, 2011, 7(6): 2592-2599.
过程。因此,该自组装膜具有可重复利用的性能 [23] 。 [16] ZHANG X D (张晓栋), QIN L Y (秦立彦), CHEN M Q (陈明清),
et al. Fabrication of a responsive hydrogel photonic crystal sensing
film for cadmium ions[J]. Acta Physico-Chimica Sinica (物理化学学
3 结论 报), 2016, 32(12): 2976-2982.
[17] ZHANG M L, JIN F, ZHENG M L, et al. Inverse opal hydrogel
sensor for the detection of pH and mercury ions[J]. RSC Advances,
本文采用自由基乳液聚合,并经 ABC 修饰合成 2014, 4(39): 20567-20572.
[18] JIANG H L, ZHU Y H, CHEN C, et al. Photonic crystal pH and
了粒径约为 300 nm、单分散性良好的 P(NIPAm- metal cation sensors based on poly(vinyl alcohol)hydrogel[J]. New
Journal of Chemistry, 2012, 36(4): 1051-1056.
AABC-NMA)微凝胶;通过溶剂挥发法制备了对温 [19] WANG Y, LIU Z, LUO F, et al. A novel smart membrane with
度和重金属离子具有双重响应性能的胶体晶体自组 ion-recognizable nanogels as gates on interconnected pores for
simple and rapid detection of trace lead(Ⅱ) ions in water[J]. Journal
装膜。对该自组装膜的 UV-Vis 光谱分析表明,在不 of Membrane Science, 2019, 575: 28-37.
[20] LUO Q F, GUAN Y, ZHANG Y J, et al. Lead-sensitive PNIPAM
同的顺序升、降温条件下,其衍射峰位置发生明显 microgels modified with crown ether groups[J]. Journal of Polymer
Science Part A: Polymer Chemistry, 2010, 48(18): 4120-4127.
变化,并导致其结构色发生有规律变化。当金属离 [21] CHEN M, ZHOU L, GUAN Y, et al. Polymerized microgel colloidal
+
+
子的浓度在 0~120 μmol/L 之间变化时,K 、Na 、 crystals: Photonic hydrogels with tunable band gaps and fast
response rates[J]. Angewandte Chemie International Edition, 2013,
2+
52(38): 9961-9965.
+
Cs 和 Ca 等对自组装膜中微凝胶的粒径无明显影 [22] LIU Y Q, JU X J, PU X Q, et al. Visual detection of trace lead(Ⅱ)
2+
2+
2+
响,Ba 和 Hg 浓度变化对其有一定影响,Pb 的 using a forward osmosis-driven deviceloaded with ion-responsive
nanogels[J]. Journal of Hazardous Materials, 2021, 404:124157.
浓度变化对微凝胶粒径的影响最为显著,可使其衍 [23] HOLTZ J H, ASHER S A. Polymerized colloidal crystal hydrogel
films as intelligent chemical sensing materials[J]. Nature, 1997,
射峰红移 60 nm 左右。表明该膜对重金属离子,尤 389(6653): 829-832.