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第 4 期 吕 斌,等: LDH@MMT/MZBMSO 的制备及其在皮革中的阻燃性能 ·797·
明,当 LDH@e-MMT 含量为 ZBMSO 质量的 12% zanthoxylum bungeanum seed oil composites to improve the flame
时,制备的 LDH@e-MMT/MZBMSO-3 加脂坯革的 retardant of leather[J]. Polymer Degradation and Stability, 2020,
183(4): 109430.
LOI 达到 28.3%。与 MZBMSO 加脂坯革相比, [11] LUO K (雒康). Preparation of modified hydrotalcite/zanthoxylum
LDH/MZBMSO、e-MMT/MZBMSO、LDH@e-MMT/ bungeanum seed oil compound fatliquor and its flame retardant
properties[D]. Xi'an: Shaanxi University of Science & Technology
MZBMSO 加脂坯革的 pHRR、THR、pSPR 均降低, (陕西科技大学), 2021.
其中 LDH@e-MMT/MZBMSO-3 加脂坯革的 pHRR、 [12] LI J H (李建华), FENG Q Q (冯倩倩), ZHU F L (朱方龙). Discussion
THR、pSPR 比 MZBMSO 加脂坯革分别降低了 on flame retardancy and fire safety test method of leather[J]. Fire
Protection Technology and Product Information (消防技术与产品信
44.6%、73.3%和 68.0%,降幅最明显,表明 LDH 和 息), 2017, (5): 10-13.
e-MMT 实现了协同隔热抑烟作用。基于锥形量热和 [13] LIANG L (梁良), REN J (任锦), XU C Q (徐常青), et al. Preparation
and release properties of methotrexate intercalated MgAl-LDH
SEM 分析,表明 LDH@e-MMT 可减缓烟气和热量
composites[J]. Fine Chemicals (精细化工), 2019, 36(6): 1166-1172.
的传输,同时 LDH@e-MMT 的热解产物包裹在坯革 [14] LIU X D, GUO J, TANG W F, et al. Enhancing the flame retardancy
纤维表面,形成的致密炭层可进一步阻隔热量和 of thermoplastic polyurethane by introducing montmorillonite
nanosheets modified with phosphorylated chitosan[J]. Composites
O 2 ,从而提升加脂坯革的阻燃抑烟性能。LDH 和 Part A: Applied Science and Manufacturing, 2019, 119: 291-298.
e-MMT 的结合为阻燃领域提供了新思路,通过对两 [15] JIANG D B, JING C, YUAN Y, et al. 2D-2D growth of NiFe-LDH
种阻燃性材料进行结构设计,可进一步提升基体阻 nanoflakes on montmorillonite for cationic and anionic dye adsorption
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