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第 6 期 秦安然,等: 基于间苯二甲胺单体的聚酰亚胺的合成与性能 ·1147·
率较大;而 PI-6FDA/MXDA 中刚性苯环及两个酰亚 fluorinated poly(ether ketone imide)s based on a new unsymmetrical and
胺环之间更短的距离使分子链刚性更强,杨氏模量 concoplanar diamine: 3,5-Dimethyl-4-(4-amino-2-trifluoromethylphenoxy)
-4'-aminobenzophenone[J]. Polymer, 2009, 50(7): 1709-1716.
更大,另外,分子中含有的—CF 3 使分子链间距离 [12] LIAW D J , CHANG F C , LEUNG M K, et al. High thermal stability
更大,分子间作用力更小,堆积密度低,所以拉伸强 and rigid rod of novel organosoluble polyimides and polyamides
based on bulky and noncoplanar naphthalene-biphenyldiamine[J].
度较低。 Macromolecules, 2005, 38(9): 4024-4029.
[13] GUO X X, FANG J H, TANAKA K, et al. Synthesis and properties
3 结论 of novel sulfonated polyimides from 2,2'-bis(4-aminophenoxy)
biphenyl-5,5'-disulfonic acid[J]. Journal of Polymer Science Part A:
Polymer Chemistry, 2004, 42(6): 1432-1440.
本文以 MXDA 为关键单体,采用间甲酚一步法
[14] YANG C P, SU Y Y. Properties of organosoluble aromatic polyimides
成功将带有芳香环的脂肪族二胺 MXDA 应用于 PI from 3'-trifluoromethyl-3,4'-oxydianiline[J]. Polymer, 2003, 44(20):
1
的制备,并合成了 5 种 PI。通过 FTIR、HNMR、DSC、 6311-6322.
[15] MUSHTAQ N, CHEN G F, SIDRA L R, et al. Organosoluble and
TGA、DMA、UV-Vis 表征了 PI 的结构与性能,测 high T g polyimides from asymmetric diamines containing N-amino
试了其溶解性。研究发现,5 种 PI 都具有良好的溶 and N-aminophenyl naphthalimide moieties[J]. RSC Advances, 2016,
6(30): 25302-25310.
解性和优异的热稳定性,制备的薄膜具有良好的光 [16] ZENG K, ZHOU S H, FAN H J, et al. Synthesis and characterization
学透明性,可用于对材料透明性有较高要求的领域, of highly organosoluble polyimides based on a new asymmetric
dianhydride[J]. Designed Monomers & Polymers, 2012, 15(1): 53-62.
解决了 PI 类材料加工工艺复杂及薄膜透明性差的问 [17] CHANG C W, YEN H J, HUANG K Y, et al. Novel organosoluble
题,同时,良好的机械性能也能够满足加工需要。 aromatic polyimides bearing pendant methoxy-substituted triphenylamine
moieties: Synthesis, electrochromic, and gas separation properties[J].
其中,性能最佳的 PI-6FDA/MXDA 薄膜的截止波长 Journal of Polymer Science Part A: Polymer Chemistry, 2008, (46):
为 308 nm,400 nm 处的透过率高达 85%,透过率 7937-7949.
[18] WU Q, MA X R, ZHENG F, et al. Synthesis of highly transparent
80%时的波长为 375 nm。本文制备的系列 PI 材料易 and heat-resistant polyimides containing bulky pendant moieties[J].
于加工,综合性能优异。 Polymer International, 2019, 68(6): 1186-1193.
[19] WANG C Y, ZHAO X Y, LI G, et al. High solubility and optical
参考文献: transparency of novel polyimides containing 3,3',5,5'-tetramethyl
pendant groups and 4-tert-butyltoluene moiety[J]. Polymer Degradation
[1] GOUZMAN I, GROSSMAN E, VERKER R, et al. Advances in & Stability, 2009, 94(9): 1526-1532.
polyimide-based materials for space applications[J]. Advanced [20] SHEN Y (沈雁), ZHAO J (赵军), ZHU L W (朱丽雯), et al. The
Materials, 2019, 31(18): 1807738. qualitative and quantitative analysis of MXD6/PA66 and MXD6/PA6
[2] HUA Q L, SUN J L, LIU H T, et al. Skin-inspired highly stretchable blends[J]. Shanghai Chemical Industry (上海化工), 2015, 40(2):
and conformable matrix networks for multifunctional sensing[J]. 11-14.
[21] TANG W J (唐伟家), WU F (吴汾), LI M Y (李茂彦), et al. Nylon
Nature Communications, 2018, 9(1): 244.
[3] TAPASWI P K, HA C S. Recent trends on transparent colorless nanocomposite material and its application in packaging[J]. Plastics
Packaging (塑料包装), 2008, (2): 75-81, 87.
polyimides with balanced thermal and optical properties: Design and [22] KOHEI G, AKIIKE T, INOUE Y, et al. Polymer design for thermally
synthesis[J]. Macromolecular Chemistry and Physics, 2019, 220(3): stable polyimides with low dielectric constant[J]. Macromolecular
1800313. Symposia, 2003, 199(1): 321-332.
[4] DING M X (丁孟贤). Polyimide: The relationship between chemistry, [23] YU H C, KUMAR S V, SONG Y K, et al. Nanoporous thin films of
structure and performance and materials[M]. Beijing: Science Press fully alicyclic polyimides[J]. Macromolecular Research, 2011, 19(12):
(科学出版社), 2006. 1272-1277.
[5] VOLKSEN W, CHA H J, SANCHEZ M I, et al. Polyimides derived [24] LIU J G (刘金刚), HE M H (何民辉), WANG F S (王佛松), et al.
from nonaromatic monomers: Synthesis, characterization and Alicyclic polyimides and the application in liquid crystal alignment
potential applications[J]. Reactive & Functional Polymers, 1996, films[J]. Polymer Bulletin (高分子通报), 2001, (3): 1-8.
30(1/2/3): 61-69. [25] WATANABE Y, SAKAI Y, SHIBASAKI Y, et al. Synthesis of
[6] LIAW D J, HUANG C C, CHEN W H. Optically transparency and wholly alicyclic polyimides from n-silylated alicyclic diamines and
light color of novel highly organosoluble alicyclic polyimides with alicyclic dianhydrides[J]. Macromolecules, 2002, 35(6): 2277-2281.
4-tert-butylcyclohexyl group[J]. Macromolecular Chemistry & Physics, [26] OGURA T, UEDA M. Facile synthesis of semiaromatic poly(amic
acid)s from trans-1,4-cyclohexanediamine and aromatic tetracarboxylic
2010, 207(4): 434-443. dianhydrides[J]. Macromolecules, 2007, 40(10): 3527-3529.
[7] HASEGAWA M, HIRANO D, FUJII M, et al. Solution-processable [27] YAO D H, YANG Y, DENG Y H, et al. Flexible polyimides through
colorless polyimides derived from hydrogenated pyromellitic dianhydride one-pot synthesis as water-soluble binders for silicon anodes in
with controlled steric structure[J]. Journal of Polymer Science Part lithium ion batteries[J]. Journal of Power Sources, 201, 8(379): 26-32.
A: Polymer Chemistry, 2013, 51(3): 575-592. [28] XU W H, MA X R, SU Y H, et al. Synthesis of highly transparent
[8] FANG X Z, WANG Z, YANG Z H, et al. Novel polyimides derived and thermally stable copolyimide with fluorine-containing dianhydride
from 2,3,3',4',-benzophenonetetracarboxylic dianhydride[J]. Polymer, and alicyclic dianhydride[J]. Journal of Applied Polymer Science,
2003, 44(9): 2641-2646. 2020, 137(17): 48603.
[9] KIM S D, LEE S, HEO J, et al. Soluble polyimides with trifluoromethyl [29] WU A X, DRAYTON J A, RODRIGUEZ K M, et al. Influence of
aliphatic and aromatic fluorine groups on gas permeability and
pendent groups[J]. Polymer, 2013, 54(21): 5648-5654. morphology of fluorinated polyimide films[J]. Macromolecules,
[10] TAO L M, YANG H X, LIU J G, et al. Synthesis and characterization of 2020, 53(13): 5085-5095.
highly optical transparent and low dielectric constant fluorinated [30] WANG Z Q, ZHANG M Y, HAN E L, et al. Structure-property
polyimides[J]. Polymer, 2009, 50(25): 6009-6018. relationship of low dielectric constant polyimide fibers containing
[11] WANG C Y, LI G, JIANG J M. Synthesis and properties of fluorine groups[J]. Polymer, 2020, (206): 122884.