Page 182 - 《精细化工》2022年第8期

第 39 卷第 8 期 精 细 化 工 Vol.39, No.8
2022 年 8 月 FINE CHEMICALS Aug. 2022

皮革化学品
P（POSS-IA）纳米复合材料的制备及其鞣制性能

高党鸽 1,2,3 ，李欣静 1,2,3 ，吕 斌 1,2,3 ，马建中 1,2,3 ，赵 苹 1,2,3

（1. 陕西科技大学 轻工科学与工程学院，陕西 西安 710021；2. 西安市绿色化学品与功能材料重点实
验室，陕西 西安 710021；3. 陕西科技大学 轻化工程国家级实验教学示范中心，陕西 西安 710021）

摘要：以八乙烯基笼型倍半硅氧烷（POSS-Vi）和衣康酸（IA）为原料，通过自由基聚合制得聚（笼型倍半硅
1
氧烷-衣康酸）〔P（POSS-IA）〕纳米复合材料。通过 FTIR、 HNMR、XRD、TEM 对其结构进行了表征，POSS-Vi
均匀分散在聚合物基体中，直径在 50 nm 左右。将 P（POSS-IA）应用于坯革鞣制工序中，与聚（衣康酸）
〔P（IA）〕、聚（丙烯酸）〔P（AA）〕、聚（笼型倍半硅氧烷-丙烯酸）〔P（POSS-AA）〕、聚（甲基丙烯酸）
〔P（MAA）〕、聚（笼型倍半硅氧烷-甲基丙烯酸）〔P（POSS-MAA）〕鞣制坯革进行了性能对比。结果表明，
P（POSS-IA）鞣制坯革具有较高的收缩温度，达到 68.2 ℃；P（POSS-MAA）鞣制坯革增厚率最大，可达到
53.3%；P（POSS-AA）鞣制坯革的抗张强度和撕裂强度最高，分别达到 31.6 MPa、59.3 N/mm。坯革的 SEM 和
EDS 结果表明，P（POSS-IA）纳米复合材料在鞣制坯革中分散更均匀。
关键词：笼型倍半硅氧烷；衣康酸；自由基聚合；无铬鞣制；皮革化学品
中图分类号：TS529.2 文献标识码：A 文章编号：1003-5214 (2022) 08-1682-08

Preparation and tanning properties of P (POSS-IA)
nanocomposite material

GAO Dangge 1,2,3 , LI Xinjing 1,2,3 , LYU Bin 1,2,3 , MA Jianzhong 1,2,3 , ZHAO Ping 1,2,3
（1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an
710021, Shaanxi, China; 2. Xi'an Key Laboratory of Green Chemicals and Functional Materials, Xi'an 710021, Shaanxi,
China; 3. National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University
of Science & Technology, Xi'an 710021, Shaanxi, China）

Abstract: Poly(polyhedral oligomericsilsesquioxane-itaconic acid) [P(POSS-IA)] nanocomposite material
was prepared by free radical polymerization of octavinylpolyhedral oligomericsilsesquioxane (POSS-Vi)
1
with itaconic acid (IA). Characterization by FTIR, HNMR, XRD and TEM indicated that the synthesized
nanoparticle diameter was about 50 nm with POSS-Vi uniformly dispersed in the polymer matrix. The
tanning properties of P(POSS-IA) for trimming the crust leather were further investigated using tanning
agents poly(itaconic acid) [P(IA)], poly(acrylic acid) [P(AA)], poly(polyhedral oligomericsilsesquioxane-
acrylic acid) [P(POSS-AA)], poly(methacrylic acid) [P(MAA)] and poly(polyhedral oligomericsilsesquioxane-
methacrylic acid) [P(POSS-MAA)] as control. The results revealed that the crust leather tanned with
P(POSS-IA) exhibited higher shrinkage temperature of 68.2 ℃ while that tanned with P(POSS-MAA)
displayed highest thickening rate of 53.3%, and the ones treated with P(POSS-AA) showed highest tensile
strength and tear strength, which were 31.6 MPa and 59.3 N/mm, respectively. Meanwhile, SEM and EDS
results demonstrated that P(POSS-IA) nanocomposite material was more evenly dispersed in tanned crust
leather in comparison to controls.
Key words: polyhedral oligomericsilsesquioxane; itaconic acid; free radical polymerization; chromium-free
tanning; leather chemicals

收稿日期：2021-12-28; 定用日期：2022-05-05; DOI: 10.13550/j.jxhg.20211328
基金项目：国家自然科学基金面上项目（21878182）；陕西省“高层次人才专项支持计划”项目；陕西省创新能力支撑计划资助
（2021TD-16）
作者简介：高党鸽（1982—），女，博士，教授，E-mail：dangge2000@126.com。