Page 108 - 《精细化工》2023年第4期

g794g ㇫㏳ࡃጒ FINE CHEMICALS す 40 ࢤ

2
᭜ⷠ㏥喍CP喎喍142 mW/m 喎হ CP/GNS 䭠Ხ喍203 ᰶᴁᕔ喑जВౕअᒏ 50%⮱ᗲ̸ۢᖏฺȡᒀⴠ෕
2
mW/m 喎⮱ 4.2 Ժহ 3.0 ԺȡZHU ぶ [47] 䛴⩕ⴠ෕☜ ☜⊤㐢҉ͧ MFC ⮱䭠Ხᬣ喑ڣᰭ๔ߌ⢴ჳᏓ䓫ݝ
2
喍GE喎㏠ㆠ❴হ㖇͆☜㘧⯽䚥⯽喍PAH喎็ᅯ㛉䕇 42700 mW/m 喑倅λВⷠℎ҉ͧ䭠Ხᱽ᫆ݣิ⮱
䓴ᅯᅯ㜗㏱㷲ឭᱜԛ亝 MFC ⮱䭠Ხȡ喍PAH/GE喎 2 MFCȡ䔆ψⵁ⾣⮱᜽ߌजᑿ఍λⴠ෕☜⽠Ⴧ⮱⩢ࡃ
ԛ亝⮱䭠ᲮҀ㈨⮱ᰭ๔䓀ܧ⩢≮᭜⾧⮪⅔ࡃ䨌䩎 ႓ᕔ㘪Ƞ䒰๔⮱℁㶕䲏⼜হ㞜ສ⮱⩢ᄩ⢴喑ͧ㏳㣹
喍ITO喎䭠ᲮҀ⮱ 3.4 ԺȡCHEN ぶ [48] ⩕۝὎Წ∂ݣ ᣽ӈγ䋠์⮱㔽ऄ叼䭱㘪߈喑Ӱ䔈γڲ⎽ᕔϸ䉕̻⩢
ิᴁᕔ๔ႁ̶㐡ⴠ෕☜⊤㐢ȡݣิ⮱ⴠ෕☜⊤㐢ڤ Ხ͸䬡⮱倅᩵⩢ၽ䒙⼨ȡ

ఫ 2 ፓᰶ㜗♣⩌䪬⩌➖㛉喍a喎হ䓴␑⩌➖㛉喍bȠc喎⮱ᬍᎼ CNFs喠㜗♣⩌䪬⩌➖㛉喍d喎হ䓴␑⩌➖㛉喍eȠf喎⮱
Ⴧा CNFs喠ڤᰶ㜗♣⩌䪬⩌➖㛉喍g喎হ䓴␑⩌➖㛉喍hȠi喎⮱Ⴧा CNTs/CNFs ⮱ SEM ఫ [40]
Fig. 2 SEM images of disordered CNFs with naturally grown biofilm (a), with filtrated biofilm (b, c); oriented CNFs with
naturally grown biofilm (d), with filtrated biofilm (e, f); Oriented CNTs/CNFs with naturally grown biofilm (g), with
filtrated biofilm (h, i) [40]

ᅪノⴠ෕☜ԛ亝ऻ⮱䭠Ხᰶݖλ⩢≨ᕔ⩌➖㛉 2.1.3 ڣЃⷠധव᜽ᱽ᫆
⮱ᒏ᜽喑Ӱ䔈ᓛ⩌➖হ⩢Ხ͸䬡⮱ EET喑♣㔹䔆ψ 䮑γⷠ㏠ㆠノহⴠ෕☜ᱽ᫆͸ใ喑ڣЃ倅ᄩ⩢
⩢Ხ㶕䲏㜗♣ᒏ᜽⮱⩌➖㛉⮱ᕨ⩌➖䛼䉌㢤䒰ѻ喑 ᕔȠ倅ᕔ㘪⮱ⷠധव᜽ᱽౕ᫆Ӱ䔈 EET 䓴⼸͚ᓄݝ
䭽ݣγ MFC 䓀ܧߌ⢴⮱䔈̭ₒ᣽倅ȡ఍ₑ喑ͧγ᣽ Ꭼ∈Ꮑ⩕ȡKARRA ぶ [50] В≨ᕔ◚㏠ㆠ㏑㐡喍ACNF喎
倅 MFC ⮱ᕔ㘪喑YONG ぶ [49] ᄳ䔅࣌⅔ࡃⴠ෕☜ ͧ䭠Ხᱽ᫆喑ВӰ䔈㏳㣹⩌➖㛉⮱⩌䪬喑᣽倅 MFC
喍rGO喎হጹ⨓ℼ㣹㐀वౕ̭䊤喑ౕ⩢Ხ̷ᒏ᜽ rGO/ ᕔ㘪ȡACNF ҉̭ͧ⻺㞜ສ⮱⩌➖㛉ᩜᠮᱽ᫆喑ڤ
ጹ⨓ℼ㣹ᱯࡃ⩌➖㛉ȡ㏱㷲ᒏ᜽⮱̶㐡๔ႁ㑾㐉ज ᰶ䒰倅⮱⩌➖जݖ⩕℁㶕䲏⼜হο㖁㑾㐉喑๔๔䭺
Ҭ๔䛼⮱㏳㣹䔈ڒ⩌➖㛉ധ䉕͚喑ᒏ᜽็䛺⮱ᄩ⩢ ѻγэ䉕䭨߈喑ϻ㔹෋ᑧγ⩢ၽэ䔿ȡACNF ౕ⩌
䕁ᒱ喑ϻ㔹Ӱ䔈㏳㣹হ⩢Ხ͸䬡⮱ EETȡ̻㜗♣⩌ ➖㛉⩌䪬Ƞࣾ⩢হࡃ႓䰭⅔䛼喍COD喎ࣨ䮑᫦䲏ڤ
➖㛉Ⱕ℁喑⌤व⩌➖㛉⮱ใा⩢≮喍ϻ㏳㣹ݝ⩢Ხ喎 ᰶᬻ᭫⮱х߬ȡSONG ぶ [51] 䕇䓴キᭀڞ↶⋭∂ݣิ
෋ߍ 25 Ժ喑ڲा⩢≮喍ϻ⩢Ხݝ㏳㣹喎෋ߍ 74 Ժȡ γⷮᕔ䷄ㆿ≨ᕔ◚喍MGAC喎⩕λѻᑧᏓᏌⅡ⮱ࢹ
㏳㣹ౕ 3D ⩌➖㛉⮱ rGO ㏠ㆠ❴̷⮱㉔ჳ䩇Ⴧ๔๔ ⅔⊵ࡃȡMGAC ั⤳ܧⅡ CODȲ(44.5±1.5) mg/L喎ȳ
ۼᄾγ⩢ၽ⾬ᷚ⮱ EET 䌊⻨喑́ 3D ๔ႁ⮱䔅࣌⅔ 䒰ᄦ⚔喍ᬍᄩ⩢⌨ߍݯ喎ั⤳䭺ѻ 43%喑ϔ⩟☤䛼
ࡃⴠ෕☜/㏳㣹⌤व⩌➖㛉喑෋ߍγ⩌➖䛼⮱䉌䒪喑 Ȳ(4.7± 0.2) mL/cycle喎ȳ᭜ᄦ⚔⮱ 3.6 ԺȡMGAC ෋
෋ߍγ℁㶕䲏⼜হ⩢ࡃ႓≨ᕔ喑Ҭڣࣹा⩢ၽ䒙⼨ ᑧγ㏳㣹̻㏳㣹͸䬡⮱⩢ၽэ䔿喑᣽倅γ⩟☤ϔ䛼喑
㘪์хλ㜗♣⩌䪬⮱⩌➖㛉ȡ ϔ⩌γ倅䉕䛼⮱ܧⅡȡ