Page 110 - 《精细化工》2023年第4期

g796g ㇫㏳ࡃጒ FINE CHEMICALS す 40 ࢤ

Ⱕ䗨⮱㘣Ҁ͸䬡э䔿喑Ӱ䔈䔉䌊⻨⩢ၽэ䔿 [70] ȡڤ NH 2 -MIL-53(Fe)ͧ䭠Ხ⮱ MFC ⮱ߌ⢴ჳᏓ倅䓫
2
ᰶ 3D 㐀Ჱ⮱ CNTs/Į-Fe 2 O 3 ฺवᱽ᫆ڤᰶ๔ႁᒱȠ 255 mW/m 喑℁ВΆ◁叾ͧ䭠Ხ⮱ MFC 倅ܧ 53%ȡ
倅℁㶕䲏⼜হх䊷⮱ᄩ⩢ᕔ喑जВ෋ߍϔ⩢㏳㣹ౕ ⵁ⾣㶕ᬻ喑⅕ധ⮱ᑂڒ෋ᑧγ䭠Ხ⮱⩌➖Ⱕღᕔ喑
ߌ㘪⩢Ხ̷⮱叼䭱喑Ӱ䔈 EET 䓴⼸ȡCHEN ぶ [71] ᣽倅γ䭠Ხ㶕䲏⩢㢤喑ᄦϔ⩢㏳㣹ϔ⩌䲆⩢॥ᑂ᩵
⩕ Ȗ-Fe 2 O 3 ㏠ㆠㆿၽ喍NPs喎ԛ亝⶘䔅࣌ౝᱳ㣹喑Ό Ꮑ喑ϻ㔹෋ߍγ㏳㣹⮱䭱Ɑ䛼喑᣽倅γᰶᱧ➖⮱⅔
ःᓄγहᵤ⮱᩵᳉ȡ ࡃ䕌⢴ [82-83] ȡⰛݺ喑MOFs ᩦᕔ MFC 䭠Ხ⮱ⵁ⾣
2.2.4 MOFs
MOFs ᭜⩞䛾ᆋ⻨ၽ̻ᰶᱧ䙺Ҁ䕇䓴䙺Ѻ䩛㏱㷲 䒰ᄾ喑ज㻮喑ڤᰶ⠙➦㐀Ჱ⮱ MOFs ౕӰ䔈 EET
㔹᜽⮱ᓛႁ㑾㐉᠀᝾㐀Ჱ⮱ᰶᱧ-ᬍᱧᱯࡃᱽ᫆ [72-73] ȡ Ꮑ⩕⮱⒉߈䰭㺮䔈̭ₒࣾᣅ喑Ϻ䰭ᐭࣾڤᰶхᐯ⩢
ڣڤᰶ⽠Ⴧ⮱⩌➖ⰥღᕔȠ倅ᄩ⩢ᕔȠ倅ႁ䯆⢴Ƞ ࡃ႓ᕔ㘪⮱᫝ಸ䭠Ხᱽ᫆喑В჋⣝ MFC ⮱倅ᕔ㘪
倅℁㶕䲏⼜হ㐀Ჱ็ᵤᕔ喑ധλ䔆ψ➦ᒮ喑̭ψ䛾 ⵁ⾣ȡ
ᆋᝃ䛾ᆋ⅔ࡃ➖ധ⮱ MOF ᱽ᫆፥㷘⩕҉יࡃݯᲒ 2.3 ᄩ⩢㖇व➖
᣽倅 MFC ᕔ㘪 [74-76] ȡ䕇䓴ᩦअ䛾ᆋᝃ䙺ҀजВᄦ㏱ ㏠ㆠᄩ⩢㖇व➖喑ຯ㖇ॎড়Ƞ㖇㠜㘧Ƞ㖇็ጡ
ܳহ㐀Ჱ䔈㵹ᢿᎼ喑Вݣิ็ߌ㘪䭠Ხᱽ᫆喑䔆Ό 㘧ぶ喑⩞λڣх㞜⮱ᄩ⩢ᕔহ⣜ධ㔽Ͳᕔ喑ͨ㺮⩕
जВ෋ᑧ㏳㣹叼䭱হ⩌➖㛉⮱ᒏ᜽喑ߍ䕌 EET Ꭳ෋ λԛ亝䭠Ხ⩢Ხ喑В᣽倅㏳㣹㏳㘋⮱叼䭱㘪߈ [84-85] ȡ
ᑧ⩌➖⩢יࡃ≨ᕔ [77-78] ȡ ᄩ⩢㖇व➖जВ෋ᑧ䭠Ხ⮱ϟⅡᕔ喑᣽倅㏳㣹㏳㘋
KAUR ぶ [79] ᄳ䧮ധ䛾ᆋᰶᱧᵳ᳣̻㖇㠜㘧 ⮱叼䭱㘪߈喑Ӱ䔈ᓛ⩌➖⮱ჹ䯳㘪߈喑ᩦ઱⩹䲏⮱
喍PANI喎ฺव喑᝭ᓄݝ⮱ MIL-53(Fe)/PANI ㏠ㆠฺ э䉕ڲ䭨喍R ct 喎喑䔈㔹෋ᑧ EET [86] ȡ
वᱽ᫆Ⱑᣒ⩕҉ MFC ⮱䭠ᲮȡMFC ⮱ߌ⢴ჳᏓͧ 2.3.1 㖇㠜㘧
2
2
680 mW/m 喑Ხ䭽⩢≮ჳᏓͧ 3500 mA/m ȡWANG PANI ڤᰶ㞜ສ⮱⩌➖ⰥღᕔȠ⽠Ⴧᕔহᄩ⩢
ぶ [80] ౕⷠጰ喍CC喎̷࣌Ѻ⩌䪬 MOFs 㵺⩌⮱⅔ࡃ䧮喑
ᕔ喑㷘Ꭼ∈Ꮑ⩕ݝ MFC 䭠Ხ⮱ⵁ⾣ [87-88] ȡLI ぶ [89]
ݣิγ MIL-Fe 2 O 3 /CC হ MIL-Fe 3 O 4 /CC ͑⻺䭠Ხᱽ
䛴⩕ PANI হ㖇㠜㘧䗨⅕ധ㠜䚇喍PAOA喎͑⻺ᄩ⩢
᫆ȡMIL-Fe 2 O 3 /CC-MFC হ MIL-Fe 3 O 4 /CC-MFC ⮱ 倅ܳၽᱽ᫆ԛ亝ⷠℎ䭠ᲮȡPANI হ PAOA ͧ䭠Ხ⮱
2
ᰭ๔ߌ⢴ჳᏓܳݘ䓫ݝ 3603 হ 4305 mW/m 喑ܳݘ
2
MFC ⮱ᰭ๔ߌ⢴ჳᏓܳݘ䓫ݝ 27.4 হ 23.8 mW/m 喑
᭜ CC-MFC ⮱ 7.73 Ժহ 9.24 Ժȡຯఫ 3 ᝭⹧喑
MIL-Fe 3 O 4 /CC जВहᬣ᣽ӈᓛ⩌➖А䅏⮱Ѻ◦Ƞᰡ ̻᱗ᩦᕔ⮱ MFC喍ⷠℎͧ䭠Ხ⮱ MFC喎Ⱕ℁ܳݘ
ສ⮱⩢ᄩ⢴হ倅Ꮣᯡ䱟⮱䧮≨ᕔѺ◦喑⅔ࡃ䧮̻⩢ ᣽倅γ 35%হ 18%ȡDING ぶ [90] ⩌᜽γಯⰡᢿ݄⮱
≨ᕔᓛ⩌➖⮱倅᩵ᣒ㼓Ӱ䔈γ㏳㘋㞟㉍হ叱㉍ฺव 㖇㠜㘧㏠ㆠ㏬䭢݄喑Ꭳᄳݣิ⮱㖇㠜㘧㏠ㆠ㏬䭢݄
㯸⮪⮱ܳ⇹喑෋ᑧγ EET ߌ㘪ȡ 喍PANI-NA喎࠲㺳⮱ Au ⩢Ხ喍PANI-NA/Au喎⩕҉
ጒ҉⩢Ხȡౕ̺ह⮱Ꮑ⩕⩢Ѻ̸喑㖇㠜㘧⮱็䛺⅔
ࡃⅡᎠᄩ㜡γϸᄩ EET ⮱็䛺㘪߈喑㔹ᢿ݄⮱㏠ㆠ
㐀ᲱᲮ๔ౝ෋ᑧγ PANI-NA ㏠ㆠহ㏳㘋㏱У͸䬡
⮱ᅭ䘕᠀᝾Ⱕο҉⩕喑ϻ㔹Ӱ䔈⩢ၽ䒙⼨ȡHUANG
ぶ [91] 䔶᠖ᄳ PANI ̻ⴠ෕☜㐀व喑Ռߖι⁎䩛߈喍ຯ
ള⼜߈Ƞ⅏䩛߈হ䲆⩢߈喎࣌Ѻᩦᕔ⅔ࡃⷠጰ҉ͧ
䭠Ხ喑MFC 䓀ܧߌ⢴ჳᏓ̻䓀ܧ⩢ࢸ䒰㏜ⷠጰ䭠Ხ
MFC ܳݘ᣽倅γ 1.9 Ժহ 1.3 ԺȡQIAO ぶ [92] व᜽
γ̭⻺➦₷⮱㏠ㆠ㐀Ჱ PANI/ϸႁ TiO 2 ฺवᱽ᫆喑
Ꭳᄳڣ⩕҉ MFC ⮱䭠Ხȡ㐀᳉㶕ᬻ喑ฺवᱽ᫆҉ͧ
䭠Ხᬣ⮱䓀ܧߌ⢴䒰᱗ᩦᕔ᣽倅γ 2 Ժȡ
2.3.2 㖇ॎড়
㖇ॎড়喍PPy喎఍ڣФᵩѻ᏶Ƞᄩ⩢ᕔ㘪倅Ƞ⣜
ධ⽠Ⴧᕔສহ⩌➖Ⱕღᕔສ㔹㷘䃑ͧ᭜̭⻺⠙➦⮱

ఫ 3 MIL-Fe 3 O 4 /CC Ӱ䔈㘋ใ⩢ၽэ䔿⮱ᱧ⤳⹧ᘼఫ [80] 㖇व➖ȡ♣㔹喑㖇ॎড়⮱Ӕ䨫͚ႅౕ๔䛼⮱ Į-ȕƍ֣
Fig. 3 Schematic diagram of mechanism of MIL-Fe 3 O 4 /CC 㖁喑ज㘪ᑂ䊤㐀Ჱ㈷Ξ喑Ҭڣڤᰶ䒰ጛ⮱⽠Ⴧᕔহ䔌
promoting extracellular electron transfer [80] [85,93]
㑀⮱⩢ၽ䒙⼨ᕔ喑䭽ݣγ MFC ⮱㔽Ͳᕔᕔ㘪 ȡ
XU ぶ [81] В Fe-MOF ͧݺ䏘喑ᣧᱯΆι㘧व᜽ 䞡λₑ喑ڣౕ MFC ͚⮱Ꮑ⩕ͨ㺮᭜Вฺवᱽ᫆⮱ᒏ
NH 2 -MIL-53(Fe)Ꭳ҉ͧ䭠Ხᱽ᫆Ꮑ⩕λ MFCȡВ ᐼႅౕȡZOU ぶ [94] 䛴⩕ॎড়ౕⷠ㏠ㆠノ̷࣌Ѻ㖇व